IMPACT OF WATERSHED URBANIZATION ON STREAM INSECT COMMUNITIES1

ABSTRACT: The impact of urbanization on stream insect communities was determined by sampling 22 sites in northern Virginia representing a range of human population densities. Watershed development had little effect on the total insect numbers (no./m²), but shifted the taxonomic composition markedly. Relative abundance of Diptera (mainly chironomids) increased at more highly urbanized sites, while most other insect orders including Ephemeroptera (mayflies), Coleoptera (bettles), Megaloptera (dobsonflies), and Plecoptera (stone-flies) decreased. Trichoptera (caddisfiles) exhibited a variable response. Genus diversity and richness (number of genera) were significantly higher in less urbanized streams. Two genera of chironomids were positively correlated with increased urbanization, while 14 other genera (scattered through several orders) were negatively related to human population density. Principal components analysis demonstrated a gradient from more urbanized to less urbanized stations based on generic and order level biological data. Results of this study indicate that watershed urbanization has a major impact on benthic insect communities even in the absence of point source discharges.     

A refutation of Karasek's demand – discretion model of occupational stress with a range of dependent measures

Karasek's (1979) demand–discretion model of occupational stress has been highly influential but has been criticized as confounding social class variables (Payne and Fletcher, 1983), ignoring the curvilinearity of relationships (Warr, 1991), and because it has inconsistently predicted heart disease (Ganster and Fusilier, 1989). The present study examines the ability of the model to predict raised blood pressure (a risk factor in the development of CHD), anxiety, depression, job and life satisfaction, in a large heterogeneous sample of over 3000 people. It examines the predictability of the model for men and women, taking occupational classification (manual and non-manual workers) into account, to allow some control over social class confounding. It also examines nonlinear relationships in the data. The study showed that demands and discretion do separately predict psychological strain, job and life satisfaction, though they account for a very small percentage of the variance. There was no evidence of interactive effects which are central to the model. Where the model was able to predict blood pressure, relationships were consistently in the opposite direction to that hypothesized. There was also little evidence of curvilinear relationships. Interpersonal support was found to add significantly to the predictability of the dependent variables. The findings cast doubt on Karasek's model and suggest that emphasis should be shifted to those models which are more encompassing of support factors.     

PCBs and other organochlorines in human tissue samples from the Welsh population: I--Adipose

The general exposure of humans to polychlorinated biphenyls (PCBs) and SigmaDDT (i.e., p,p'-DDT + p,p'DDE = p,p'-DDD) in Wales (UK) was determined through the analysis of adipose tissue samples collected from 75 individuals during post-mortem examinations in 1990-1991. Fifty PCB congeners were screened, of which 29 were identified in most of the samples. Congener IUPAC numbers 138, 153 and 180 were the most abundant compounds, accounting for an average of 55% of the SigmaPCB congeners analysed. SigmaPCB concentrations varied between 0.2 and 1.8 microg g(-1) of adipose tissue and were positively correlated with the donors age and negatively associated with the percentage of lipid in the adipose tissue. A progressive change in the congener pattern was noted with increasing subject age. Tissue from older individuals generally contained a relatively high proportion of the more persistent and higher chlorinated congeners. SigmaDDT concentrations ranged from 0.11 to 5.6 microg g(-1) adipose tissue, with p,p'-DDE contributing 96% towards the SigmaDDT concentration. SigmaDDT levels were also positively correlated with age. No significant differences in the SigmaPCB and SigmaDDT concentrations were noted between males and females, between people living in rural and urban locations or with the subjects' body weight at the time of their death.     

Dynamics of PAH deposition, cycling and storage in a mixed-deciduous (Quercus-Fraxinus) woodland ecosystem

Estimates of standing biomass and fluxes of biomass in a mixed-deciduous woodland were derived, and used with results for concentrations of seven polycyclic aromatic hydrocarbons (PAHs) in different compartments of the woodland system to quantitatively assess some of the key fluxes and burdens of PAHs in this complex system. We quantified PAH burdens in air, in leaves of three deciduous tree species, in leaf litter and in soil, and uptake of PAHs by the tree leaves; PAH fluxes in litterfall, and deposition to the litter layer on the woodland floor during winter were calculated from these data. Air burdens exhibited marked seasonal variations for all compounds, with lowest values in summer when combustion-related emissions were low. Leaves did not accumulate large burdens of PAHs while on the trees and consequently, litterfall-associated fluxes of PAHs were small, representing only a fraction of the burdens in the litter layer to which they were deposited. Higher PAH burdens in air in winter, combined with the organic-matter-rich nature of the litter layer, are thought to be responsible for fluxes of PAHs to the litter layer in winter being 20-170 times the peak litterfall fluxes. The soil compartment was calculated to contain 25 years' worth of deposition of benzo[ghi]perylene, the most recalcitrant PAH in this study. Storage quotients for fluoranthene, pyrene, benzo[k]fluoranthene and benzo[a]pyrene burdens in soil represented 7-10 years' worth of deposition, while fluorene and phenanthrene storage in soil approached unity with inputs (1 and 3 years' worth of deposition, respectively). The relative importance of storage and loss processes was therefore closely related to the physico-chemical properties of the PAH, and is discussed in relation to the cycling of carbon in the woodland.     

Integrated biological treatment and biogas production in a small-scale slaughterhouse in rural Ghana.

A small-scale anaerobic slaughter waste treatment plant in rural Ghana was tested for the production of energy and a microbiologically clean effluent suitable for use in irrigation. A typical day's slaughter, comprising 4 cattle, 12 sheep, and 12 goats, produced 8.5 m3 of biogas. Annually, this is equivalent to the energy from 17 metric tons of fuel wood, which is the annual productivity of 2 ha of savanna vegetation. Fecal indicator bacteria were reduced by 2 to 3 logs, nitrates by 86 to 90%, phosphates by 23%, biochemical oxygen demand by 42 to 92%, and suspended solids and dissolved solids by 73 to 86% and 19 to 37%, respectively. The effluent is used for irrigation, and the organic biomass from the digester is used as a biofertilizer. Besides energy and a cleaner effluent, the community benefited from a lessening dependency on fuel wood and reductions in unpleasant smells and nuisance animals, such as flies, dogs, and vultures.     

Reducing global NOx emissions: developing advanced energy and transportation technologies

Globally, energy demand is projected to continue to increase well into the future. As a result, global NOx emissions are projected to continue on an upward trend for the foreseeable future as developing countries increase their standards of living. While the US has experienced improvements in reducing NOx emissions from stationary and mobile sources to reduce ozone, further progress is needed to reduce the health and ecosystem impacts associated with NOx emissions. In other parts of the world, (in developing countries in particular) NOx emissions have been increasing steadily with the growth in demand for electricity and transportation. Advancements in energy and transportation technologies may help avoid this increase in emissions if appropriate policies are implemented. This paper evaluates commercially available power generation and transportation technologies that produce fewer NOx emissions than conventional technologies, and advanced technologies that are on the 10-year commercialization horizon. Various policy approaches will be evaluated which can be implemented on the regional, national and international levels to promote these advanced technologies and ultimately reduce NOx emissions. The concept of the technology leap is offered as a possibility for the developing world to avoid the projected increases in NOx emissions.     

The effects of particle size, organic matter content, crop residues and dissolved organic matter on the sorption kinetics of atrazine and isoproturon by clay soil

Reliable predictions of the fate and behaviour of pesticides in soils is dependent on the use of accurate ‘equilibrium’ sorption constants and/or rate coefficients. However, the sensitivity of these parameters to changes in the physicochemical characteristics of soil solids and interstitial solutions remains poorly understood. Here, we investigate the effects of soil organic matter content, particle size distribution, dissolved organic matter and the presence of crop residues (wheat straw and ash) on the sorption of the herbicides atrazine and isoproturon by a clay soil. Sorption K_d's derived from batch ‘equilibrium’ studies for both atrazine and isoproturon by <2 mm clay soil were approximately 3.5 L/kg. The similarity of K_oc's for isoproturon sorption by the <2 mm clay soil and <2 mm clay soil oxidised with hydrogen peroxide suggested that the sorption of this herbicide was strongly influenced by soil organic matter. By contrast, K_oc's for atrazine sorption by oxidised soil were three times greater than those for <2 mm soil, indicating that the soil mineral components might have affected sorption of this herbicide. No significant differences between the sorption of either herbicide by <2 mm clay soil and (i) <250 μm clay soil, (ii) clay soil mixed with wheat straw or ash at ratios similar to those observed under field conditions, (iii) <2 mm clay soil in the presence of dissolved organic matter as opposed to organic free water, were observed.     

A study into the parameters affecting selected reaction monitoring of 2,3,7,8-TCDD

The use of high resolution (10,000 resolving power) coupled gas chromatography - mass spectrometry is a well established technique in the analysis of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) but in the case of heavily contaminated stack samples interferences can still occur. A complementary technique that offers high specificity is selected reaction monitoring (SRM).A study has been made into the effects that affect the metastable dissociation of 2,3,7,8-TCDD in the first field free region (FFR1) of a magnetic sector mass spectrometer, and monitored using SRM.Monatomic, diatomic and polyatomic gases have been investigated in the collision chamber of the mass spectrometer, as have the effects of electron energy, source temperature and trap current on the dissociation, and optima conditions determined for them.     

The Rossby Centre Regional Atmospheric Climate Model part I: model climatology and performance for the present climate over Europe

The Rossby Centre Atmospheric Regional Climate Model (RCA2) is described and simulation results, for the present climate over Europe, are evaluated against available observations. Systematic biases in the models mean climate and climate variability are documented and key parameterization weaknesses identified. The quality of near-surface parameters is investigated in some detail, particularly temperature, precipitation, the surface energy budget and cloud cover. The model simulates the recent, observed climate and variability with a high degree of realism. Compensating errors in the components of the surface radiation budget are highlighted and the fundamental causes of these biases are traced to the relevant aspects of the cloud, precipitation and radiation parameterizations. The model has a tendency to precipitate too frequently at small rates, this has a direct impact on the simulation of cloud-radiation interaction and surface temperatures. Great care must be taken in the use of observations to evaluate high resolution RCMs, when they are forced by analyzed boundary conditions. This is particularly true with respect to precipitation and cloudiness, where observational uncertainty is often larger than the RCM bias.