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101.
Hursthouse AS Matthews JM Figures JE Iqbal-Zahid P Davies IM Vaughan DH 《Environmental geochemistry and health》2003,25(2):171-203
Detailed surveys of intertidal sediments have been performed along the north and south shores of the Inner Clyde estuary, UK. Surface sediment data reveal significant spatial variation in Cr content and an association with major sediment characteristics and location within the estuary. Depth variation for Cr and other heavy metals cannot be explained by variation in major geochemical controls such as grain size and organic matter and highlights the impact of historical contamination on sediment quality. These elevated levels at depth may still have environmental impact through redox-reactivity, in association with iron and manganese. Sequential extraction of sediments and pore water analysis of Cr(VI) and Cr(III) provide detailed information on release potential from the sediments. The implication of Cr mobility for biota in the estuary has been assessed by the analysis of a common marine bivalve, Mytilus edulis (Blue Mussel) and a burrowing polychaete, Nereis diversicolor (rag worm) from a number of survey sites. Bioconcentration factors for Mytilus indicate that the weakly held portion of sediment Cr is available for uptake and in the case of Nereis, bioaccumulation appears to be inhibited by sediment organic matter. 相似文献
102.
Juliette Richetin Marco Perugini Mark Conner Iqbal Adjali Robert Hurling Abhijit Sengupta Danica Greetham 《Journal of environmental psychology》2012
Recent research shows that because they rely on separate goals, cognitions about not performing a behaviour are not simple opposites of cognitions about performing the same behaviour. Using this perspective, two studies (N = 758 & N = 104) examined the psycho-social determinants of reduction in resource consumption. Results showed that goals associated with reducing versus not reducing resource consumption were not simple opposites (Study 1). Additionally, the discriminant validity of the Theory of Planned Behaviour constructs associated with reducing versus not reducing resource consumption was demonstrated (Study 1 & 2). Moreover, results revealed the incremental validity of both Intentions (to reduce and to not reduce resource consumption) for predicting a series of behaviours (Study 1 & 2). Finally, results indicated a mediation role for the importance of ecological dimensions on the effect of both Intentions on a mock TV choice and a mediation role for the importance of non ecological dimensions on the effect of Intention of not reducing on the same TV choice. Discussion is organized around the consequences, at both theoretical and applied levels, of considering separate motivational systems for reducing and not reducing resource consumption. 相似文献
103.
Samsul Alam Dwaipayan Sengupta Ramen Kumar Kole Anjan Bhattacharyya 《Environmental monitoring and assessment》2013,185(12):9819-9824
Laboratory experiment was conducted to understand the persistence behavior of tetraconazole in three soils of West Bengal (alluvial, red lateritic, and coastal saline) and also in water maintained at three different pH (4.0, 7.0, and 9.2) conditions. Processed soil samples (100 g) were spiked at two treatment doses: 2.5 μg/g (T1) and 5.0 μg/g (T2). Double distilled buffered water (200 ml) was spiked at two treatment doses: 1.0 μg/ml (T1) and 2.00 μg/ml (T2). The tetraconazole dissipation followed first-order reaction kinetics and the residual half-life (T 1/2) values in soil were found to be in the range of 66.9–77.2 days for T1 and 73.4–86.0 days for T2. The persistence increased in the order red lateritic > new alluvial > coastal saline. Interestingly, the red lateritic soil exhibited the lowest pH (5.56) and organic carbon (0.52 %) content as compared to other two soils. However, the dissipation of tetraconazole in case of water was not pH dependant. The T 1/2 values in water were in the range of 94 to 125 days. The study indicated the persistent nature of tetraconazole in soil and water. 相似文献
104.
Increasingly, many youth are disconnected from the natural world; rather, they inhabit a technological world. Although experiences in nature have long been a source of fascination, little is known about how youth independently access and make sense of nature. We focus on the experiences of youth who chose to use marijuana in nature. A substance such as marijuana is often viewed as a “gateway” leading to “harder” drug use; rarely do we consider how marijuana might be a gateway to positive experiences. Narrative analysis was used to explore how young people, aged 14–18, describe their marijuana use in nature, an important aspect of the culture and context of marijuana use. Youth's constructions of nature are revealed in four narratives in which they situate themselves: freedom in nature, the pleasure of leisure, in awe of the natural world and making meaning of the world. One subnarrative, flowing through space, was also uncovered. The findings point to the importance of these nature experiences for youth who expressed how they were able to be in nature in new ways. Participants articulated their yearning for and ability to establish a connection within their natural world. 相似文献
105.
Bian Liu Gerald J. Keeler J. Timothy Dvonch James A. Barres Mary M. Lynam Frank J. Marsik Joy Taylor Morgan 《Atmospheric environment (Oxford, England : 1994)》2010,44(16):2013-2023
Measurements of gaseous elemental mercury (GEM), particulate mercury (Hgp), and reactive gaseous mercury (RGM) were concurrently recorded at an urban site in Detroit and a rural site in Dexter, both in Michigan for the calendar year 2004. Their average concentrations (±standard deviation) for the urban area were 2.5 ± 1.4 ng m?3, 18.1 ± 61.0 pg m?3, and 15.5 ± 54.9 pg m?3, respectively, while their rural counterparts were 1.6 ± 0.6 ng m?3, 6.1 ± 5.5 pg m?3, and 3.8 ± 6.6 pg m?3, respectively. The medians of urban-to-rural ratios of Hg concentrations indicate approximately 1-fold, 2-fold, and 3-fold gradients between Detroit and Dexter for GEM, Hgp, and RGM, respectively. The urban–rural differences in Hg also varied considerably on different temporal scales and with wind flow patterns, which was most evident in RGM. Our results show that while Hg at both sites was impacted by regional sources, meteorological conditions, and photochemical transformations, the extent of variations in the observed urban-to-rural gradients, particularly in RGM, cannot be fully accounted for by these processes. Both analyses of the annual data and case studies indicate that the more variable and episodic nature of Hg, particularly RGM, seen in Detroit compared with Dexter, was the result of direct impact from local anthropogenic sources. 相似文献
106.
Sotiriou M Ferguson SF Davey M Wolfson JM Demokritou P Lawrence J Sax SN Koutrakis P 《Environmental monitoring and assessment》2008,137(1-3):351-361
Particles in a dental office can be generated by a number of instruments, such as air-turbine handpieces, low-speed handpieces,
ultrasonic scalers, bicarbonate polishers, polishing cups, as well as drilling and air sprays inside the oral cavity. This
study examined the generation of particles during dental drilling and measured particle size, mass, and trace elements. The
air sampling techniques included both continuous and integrated methods. The following particle continuous measurements were
taken every minute: (1) size-selective particle number concentration (Climet); (2) total particle number concentration (PTRAK),
and; (3) particle mass concentration (DustTrak). Integrated particle samples were collected for about 5 h on each of five
sampling days, using a PM2.5 sampler (ChemComb) for elemental/organic carbon analysis, and a PM10 sampler (Harvard Impactor) for mass and elemental analyses. There was strong evidence that these procedures result in particle
concentrations above background. The dental procedures produced number concentrations of relatively small particles (<0.5 μm)
that were much higher than concentrations produced for the relatively larger particles (>0.5 μm). Also, these dental procedures
caused significant elevation above background of certain trace elements (measured by X-ray fluorescence) but did not cause
any elevation of elemental carbon (measured by thermal optical reflectance). Dental drilling procedures aerosolize saliva
and products of drilling, producing particles small enough to penetrate deep into the lungs. The potential health impacts
of the exposure of dental personnel to such particles need to be evaluated. Increased ventilation and personal breathing protection
could be used to minimize harmful effects. 相似文献
107.
Assessment and occurrence of various heavy metals in surface water of Ganga river around Kolkata: a study for toxicity and ecological impact 总被引:2,自引:0,他引:2
Md. Wasim Aktar M. Paramasivam M. Ganguly S. Purkait Daipayan Sengupta 《Environmental monitoring and assessment》2010,160(1-4):207-213
A study was conducted during November, 2005–October, 2006 to evaluate the surface water quality of river Ganga around Kolkata. The samples were analyzed for a number of physico-chemical parameters using standard laboratory procedures and giving prime thrust to determine the heavy metal concentrations (Fe, Mn, Cu, Zn, Pb, Cd, Cr, and Ni) of surface water at four different locations of the river Ganga around Kolkata from two points (middle of the river stream and a discharge point) at each location. Out of 96 samples analyzed, Fe, Mn, Cu, Zn, and Ni were detected in 71, 47, 38, 60, and 45 samples in the concentrations ranging from 0.013 to 5.49, 0.022 to 1.78, 0.003 to 0.033, 0.005 to 0.293, and 0.045 to 0.24 mg L???1, respectively. Cd and Pb were detected in six and 21 samples in the range of 0.005 to 0.006 and 0.05 to 0.53 mg L???1, respectively. But Cr was not detected in any of the samples analyzed. The metals exhibited no significant variation with respect to sampling locations as well as discharge points. However, the concentration of those metals varied with season, being higher in rainy and lower in winter season. 相似文献
108.
Edward J. M. Joy E. Louise Ander Martin R. Broadley Scott D. Young Allan D. C. Chilimba Elliott M. Hamilton Michael J. Watts 《Environmental geochemistry and health》2017,39(4):835-845
Widespread potential dietary deficiencies of calcium (Ca), iron (Fe), iodine (I), selenium (Se) and zinc (Zn) have been identified in Malawi. Several deficiencies are likely to be compounded by high phytic acid (PA) consumption. Rice (Oryza sativa) is commonly consumed in some Malawian populations, and its mineral micronutrient content is important for food security. The considerable irrigation requirements and flooded conditions of paddy soils can also introduce or mobilise potentially toxic elements including arsenic (As), cadmium (Cd) and lead (Pb). The aim of this study was to determine the mineral composition of rice sampled from farmers’ fields and markets in Malawi. Rice was sampled from 18 extension planning areas across Malawi with 21 white (i.e. polished) and 33 brown samples collected. Elemental composition was determined by inductively coupled plasma-mass spectrometry (ICP-MS). Arsenic speciation was performed using high-performance liquid chromatography (HPLC)-ICP-MS. Concentration of PA was determined using a PA-total phosphorus assay. Median total concentrations (mg kg?1, dry weight) of elements important for human nutrition in brown and white rice, respectively, were: Ca = 66.5 and 37.8; Cu = 3.65 and 2.49; Fe = 22.1 and 7.2; I = 0.006 and <0.005; Mg = 1130 and 265; Mn = 18.2 and 9.6; Se = 0.025 and 0.028; and Zn = 17.0 and 14.4. In brown and white rice samples, respectively, median PA concentrations were 5438 and 1906 mg kg?1, and median PA:Zn molar ratios were 29 and 13. Concentrations of potentially toxic elements (mg kg?1, dry weight) in brown and white rice samples, respectively, were: As = 0.030 and 0.006; Cd ≤ 0.002 and 0.006; Pb = 0.008 and 0.008. Approximately 95 % of As was found to be inorganic As, where this could be quantified. Malawian rice, like the more widely consumed staple grain maize, contains inadequate Ca, I, Se or Zn to meet dietary requirements. Biofortification strategies could significantly increase Se and Zn concentrations and require further investigation. Concentrations of Fe in rice grain varied greatly, and this was likely due to contamination of rice samples with soil. Risk of As, Cd or Pb toxicity due to rice consumption in Malawi appears to be minimal. 相似文献
109.
Long-term storage of carbon dioxide (CO2) and other forms of carbon in non-atmospheric reservoirs is called carbon sequestration. Selective anthropogenic enrichment of the atmospheric carbon pool is causing dire environmental problems, thereby necessitating remediation by mitigation. Algae possess efficient carbon concentrating mechanisms and consequently high photosynthetic rates which make them suitable candidates for biosequestration of CO2. Globally, nearly half of the atmospheric oxygen is generated by algal photosynthesis despite the fact that algae account for less than 1% of photosynthetic biomass. In water bodies, algae are responsible for creating the ‘biological pump’ that transports carbon from the upper sunlit waters to the depth below. A diverse array of photoautotrophs ranging from prokaryotic cyanobacteria to eukaryotic algae such as Chlorophytes, and even protists like euglenoids, contribute to this ‘biological pump’. It operates in a variety of aquatic ecosystems ranging from small freshwater ponds to the oceans where it has been most extensively studied. Two separate but intricately linked processes constitute this ‘biological pump’, viz. the ‘organic carbon pump’ and the ‘calcium carbonate pump’. The present review discusses the natural CO2 sequestration processes carried out by algae and cyanobacteria in their native ecosystems. 相似文献
110.
This paper reports on a life‐cycle analysis (LCA) of Taiwan's “agriculture and forestry”, “crude petroleum, coal and natural gas extraction” and “electricity generation” sectors, revealing for the first time Taiwan's CO2 and CH4 emissions inventories and matching Taiwan's input‐output sectors. Integrated hybrid input‐output life cycle analysis is used to disaggregate the electricity generation sector into nuclear, hydro, gas, oil and coal, and cogeneration. Results show that the fossil‐fuel‐related electricity sub‐sectors have higher CO2 emissions intensity than the remaining sectors in the economy and that the “paddy rice” sector is Taiwan's most CH4‐intensive sector, making rice cultivation an important source of CH4 emissions. This work is vital to sound policy decisions concerning power generation, coal, and agriculture and forestry at the national level. 相似文献