Development and validation of a method for analysis of "dioxin-like" PCBs in environmental samples from the steel industry

A method, previously used for determination of 2,3,7,8-substituted polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), has been modified for quantitative analysis of "dioxin-like" polychlorobiphenyls (PCBs) in environmental samples from the steel industry. The existing sample clean-up procedure, involving liquid chromatography on multi-layered silica and Florisil columns, has been extended to include a third chromatography stage on a basic alumina stationary phase. The additional clean-up stage is required for PCB analysis in order to eliminate interferences from relatively large concentrations of saturated cyclic and aliphatic hydrocarbons. Samples were analysed for WHO-12 congeners using high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) and standard solutions of the method US EPA 1668A. Replicate analysis of method blanks revealed background contamination for PCBs 118, 105 and 77, which are generally abundant in ambient air. These contaminants were taken into account using a subtraction method. The entire procedure was validated by replicate analysis (N = 3) of a certified reference sediment. The RSD for each WHO-12 congener was below 15%, 13C12-labelled PCB internal standard recoveries were in the range 70-95%. A waste dust sample collected in the electrostatic precipitator of a UK sinter plant was analysed for determination of PCDD/Fs and WHO-12 PCBs and exhibited a PCDD/F I-TEQ of 148.5 +/- 21.2 ngkg(-1) and a WHO-TEQ of 7.2 +/- 1.5 ngkg(-1). WHO-12 congeners contributed only 4.6% to the overall TEQ and PCB 126 was the major congener contributing to the WHO-TEQ (96%). The contribution to the overall TEQ of the waste dust sample was mainly attributed to PCDF followed by PCDD, which accounted for 86.6% and 8.7% to the overall TEQ, respectively.     

COMPARISON OF ALTERNATIVE ENGINEERING DESIGNS1

ABSTRACT: Procedures are presented for comparing and evaluating alternative engineering designs for a particular water resources project. By using certain aspects of fuzzy set theory, it is possible to introduce both quantitative and qualitative considerations into the decisionmaking process. In addition, the viewpoints of the various interest groups involved with the water resources development can be realistically incorporated by the evaluation techniques for the alternative designs. Methods are given for eliminating undesirable alternatives and thereby obtaining a reduced set of possible feasible solutions to the problem. Because of the flexibility of the evaluation methods, the viable alternatives should not only satisfy economical, technical. environmental and other types of constraints, but these possible solutions should be politically feasible as well. A method is formulated for checking the sensitivity of the feasible results with respect to the factors that are considered in the analysis.     

RIVER RECREATION: PUBLIC ACCESS VS. RIPARIAN RIGHTS1

ABSTRACT: The issues involved in the conflict between the rights of the public and those of riparian landowners are examined by reviewing the public access situation with regard to inland streams in the State of Virginia. Consideration is given to the legal framework defining access rights and to the attitudes of riparian landowners regarding the access question. Existing provisions of law suggest only limited recognition of public rights, but this law is incompletely developed. A considerably broader concept of public rights could be developed within the existing framework due to the existence of unresolved questions. The analysis of landowner attitudes is based on a survey of a sample of riparian owners chosen from throughout the state. The questionnaire used in the survey contained 123 questions in a variety of areas, including landowners' perceptions of public rights, problems encountered as the result of recreational water use, attitudes toward state designation and protection of scenic rivers, and the acceptability of alternatives for increasing public access. Although the survey results indicate substantial acceptance of the concept of public use, the landowners expressed concern over governmental control of land use and did not indicate a generally acceptable means for increasing public use.     

New Technology for Conducting Radiation Hazard Assessments: The Application of the Underwater Radiation Spectral Identification System (URSIS) at the Massachusetts Bay Industrial Waste (U.S.A.)

The Underwater Radiation Spectral Identification System (URSIS) is a portable spectrometer used for the in situ detection of radioactivity in the marine environment. This paper reports on the first time application of this technology to assess, in a preliminary manner, the potential radiation threat to the public and environment at an aquatic disposal site – the Massachusetts Bay Industrial Waste Site (IWS). Utilizing the meneuvering capabilities of ROV and manned submersible vehicles, the URSIS was successfully positioned close (5–10 cm) to waste containers for a period sufficient to detect, in real time, the presence of radioactive materials. Spectral data from 45 individual targets indicated that the radionuclides present in sediments which draped or partially buried waste containers were consistent with natural background concentrations. No man-made radionuclides were detected at any of the target or background measurement locations. These data support the conclusion that low-level radiation does not pose an imminent and widespread human health or ecological threat in Massachusetts Bay.     

Reducing Fertilizer‐Nitrogen Losses from Rowcrop Landscapes: Insights and Implications from a Spatially Explicit Watershed Model

We present conceptual and quantitative models that predict changes in fertilizer‐derived nitrogen delivery from rowcrop landscapes caused by agricultural conservation efforts implemented to reduce nutrient inputs and transport and increase nutrient retention in the landscape. To evaluate the relative importance of changes in the sources, transport, and sinks of fertilizer‐derived nitrogen across a region, we use the spatially explicit SPAtially Referenced Regression On Watershed attributes watershed model to map the distribution, at the small watershed scale within the Upper Mississippi‐Ohio River Basin (UMORB), of: (1) fertilizer inputs; (2) nutrient attenuation during delivery of those inputs to the UMORB outlet; and (3) nitrogen export from the UMORB outlet. Comparing these spatial distributions suggests that the amount of fertilizer input and degree of nutrient attenuation are both important in determining the extent of nitrogen export. From a management perspective, this means that agricultural conservation efforts to reduce nitrogen export would benefit by: (1) expanding their focus to include activities that restore and enhance nutrient processing in these highly altered landscapes; and (2) targeting specific types of best management practices to watersheds where they will be most valuable. Doing so successfully may result in a shift in current approaches to conservation planning, outreach, and funding.     

A feasibility and cost comparison of perchloroethylene dry cleaning to professional wet cleaning: case study of Silver Hanger Cleaners, Bellingham, Massachusetts

The Toxics Use Reduction Institute (TURI) has been working with the dry cleaning sector for over 10 years - focusing on the ultimate goal of eliminating the use of perchloroethylene in this sector due to the availability of less toxic, feasible alternatives. Professional wet cleaning has been identified as one of these alternatives and has been a focus of the Institute in recent years. In 2008, the Institute provided a matching grant to Silver Hanger Cleaners in Bellingham, Massachusetts to convert their operations from perchloroethylene-based to water-based processes. Two years of data have been collected from the facility, reflecting one year of solvent use and one year of dedicated professional wet cleaning. The analysis of that data is presented here, including capital costs, performance data and associated costs, operational costs, and resource use and associated costs.     

Homesickness,health and efficiency in first year students

The investigation is concerned with the reported incidence and frequency of homesickness following an environmental transition to university in a group of 101 first year university students. Definitions provided by students indicated that homesickness is a collective term for a number of cognitive and emotional/motivational experiences primarily associated with missing home and wanting to visit it. 60% reported homesickness. Geographical distance of the move and relative lack of satisfaction with features of the psychosocial and physical environment in the new place were found to be associated with homesickness reporting. Personality and circumstantial factors such as decisional control over the move and cognitive failure levels were also associated with homesickness reporting. A two-stage risk model is proposed in which an environmental relocation is a necessary but not a sufficient condition for homesickness; features of the new place combine with personality factors to precipitate the experience.