Structural and Thermal Properties of Starch Plasticized with Glycerol/Urea Mixture

Journal of Polymers and the Environment - The paper presents the results of research on the influence of used plasticizing system on the structural and thermal properties of thermoplastic starch...     

Arsenic,cadmium, lead and thallium in coal ash from individual household furnaces

52 coal ash samples from individual households were analyzed to determine the pH and the concentrations of four toxic elements: arsenic, cadmium, lead and thallium. The method used was atomic absorption spectrometry with graphite-furnace atomization. The ash samples originated from various coal grades and statistical analysis showed existing correlations between the concentrations of studied elements, pH and the coal grades. The maximum concentrations of arsenic, cadmium, lead and thallium were 50,900, 43,500, 128,900, and 6660 µg/kg, respectively. The results were compared with the published data for the ash of industrial origin.

     

Assessment of the pollution and ecological risk of lead and cadmium in soils

The aim of the study was to assess the content, distribution, soil binding capacity, and ecological risk of cadmium and lead in the soils of Malopolska (South Poland). The investigation of 320 soil samples from differently used land (grassland, arable land, forest, wasteland) revealed a very high variation in the metal content in the soils. The pollution of soils with cadmium and lead is moderate. Generally, a point source of lead and cadmium pollution was noted in the study area. The highest content of cadmium and lead was found in the northwestern part of the area—the industrial zones (mining and metallurgical activity). These findings are confirmed by the arrangement of semivariogram surfaces and bivariate Moran’s correlation coefficients. Among the different types of land use, forest soils had by far the highest mean content of bioavailable forms of both metals. The results showed a higher soil binding capacity for lead than for cadmium. However, for both metals, extremely high (class 5) accumulation capacities were dominant. Based on the results, the investigated soils had a low (Pb) and moderate (Cd) ecological risk on living components. Soil properties, such as organic C, pH, sand, silt, and clay content, correlated with the content of total and bioavailable forms of metals in the soils. The correlations, despite being statistically significant, were characterized by very low values of correlation coefficient (r?=?0.12–0.20, at p?≤?0.05). Therefore, the obtained data do not allow to define any conclusions as to the relationships between these soil properties. However, it must be highlighted that there was a very strong positive correlation between the total content of cadmium and lead and their bioavailable forms in the soils.     

A roadmap for the conservation of freshwater mussels in Europe

Europe has a long history of human pressure on freshwater ecosystems. As pressure continues to grow and new threats emerge, there is an urgent need for conservation of freshwater biodiversity and its ecosystem services. However, whilst some taxonomic groups, mainly vertebrates, have received a disproportionate amount of attention and funds, other groups remain largely off the public and scientific radar. Freshwater mussels (Bivalvia, Unionida) are an alarming example of this conservation bias and here we point out six conceptual areas that need immediate and long-term attention: knowledge, threats, socioeconomics, conservation, governance and education. The proposed roadmap aims to advance research, policy and education by identifying the most pressing priorities for the short- and long-term conservation of freshwater mussels across Europe.     

Ranking ecosystem services delivered by trees in urban and rural areas

Policies and strategies for tree management and protection on a national, regional, and local level have not sufficiently considered differences between rural and urban areas. We used expert knowledge to compare rural and urban areas in a case study evaluating the relative importance of ecosystem services (ES) in policy development. The Analytic Hierarchy Process (AHP) and focus group discussions were used to rank 17 ES, representing four classes of services: provisioning, regulating, habitat, and cultural. The results indicated that effective protection strategies, beyond simply increasing general tree cover, should consider specific benefits trees provide to local communities. We discuss the role of objective prioritization of ES delivered by trees in urban and rural areas and their consequences for decision-making processes.Supplementary InformationThe online version contains supplementary material available at 10.1007/s13280-022-01722-2.     

Principal component analysis of indicator PCB profiles in breast milk from Poland

Principal component analysis (PCA) was applied to a data set containing the levels of indicator polychlorinated biphenyls (PCBs) in human milk of mothers living in the Wielkopolska region, Poland, in order to investigate the information captured in the PCB patterns and to elucidate the relationship between PCB concentrations in milk and donor characteristics. According to the obtained PCA results milk fat content was the most influential factor affecting the PCB levels in milk of the Wielkopolska cohort. The lifestyle data collected from the questionnaire completed by the donors appeared to have no influence on PCB concentrations in breast milk. The score plots revealed the PCB contents of milk were quite low and uniform with a few outliers, without discrimination observed either between the primipareous and secundipareous females or between donors from the urban and rural areas. Comparison of the PCB levels and profiles of human milk from the Wielkopolska region and from various European and Asian locations made by PCA reflected a generally low background exposure and indicated the possible reasons for the outlying of some samples. In order to enhance the chances of observing the relationship between donor habits and PCB levels in breast milk it was suggested that the questionnaire be redesigned to gather information about vegetable product consumption and indoor air exposure.     

Environmental impact of flood: the study of arsenic speciation in exchangeable fraction of flood deposits of Warta river (Poland) in determination of "finger prints" of the pollutants origin and the ways of the migration

The paper presents the application of the hyphenated technique - high-performance liquid chromatography with atomic absorption spectrometry detection with hydride generation (HPLC-HG-AAS) - in the determinations of inorganic forms of arsenic: As(III) and As(V) in the exchangeable fraction of flood deposits. The separation of analytical signals of the determined arsenic forms was obtained using an ion-exchange column in a chromatographic system with the atomic absorption spectrometer as a detector, at the determination limits of 5 ng g⁻¹ for As(III) and 10 ng g⁻¹ for As(V). Flood deposits were collected after big flood event in valley of the Warta river which took place in summer 2010. Samples of overbank deposits were taken in Poznań agglomeration and vicinity (NW Poland). The results of determinations of arsenic forms in the exchangeable fraction of flood deposits allowed indication of a hypothetical path of deposits migration transported by a river during flood and environmental threats posed by their deposition by flood.     

Mean annual (222)Rn concentration in homes located in different geological regions of Poland: first approach to whole country area

The paper presents the results of year-long measurements of radon (²²²Rn) concentration inside 129 buildings in Poland in relation to the geological conditions of their foundation. The authors took into account the division of the country into tectonic units, as well as the lithology of the rocks forming the bedrock of these buildings. As expected, the highest value of mean annual ²²²Rn concentration (845 Bq/m³) was recorded in a building situated in the area of the Sudetes, while the highest geometric mean (characteristic of the expected log-normal data distribution) was calculated based on measurements from buildings located within the East-European craton, in the area of Mazury-Podlasie monocline, where it reached 231 Bq/m³. Such results reflect geological conditions - the occurrence of crystalline rocks (especially U- and Ra-enriched granites and orthogneisses) on the surface in the Sudetes, and of young post-glacial sediments containing fragments of Scandinavian crystalline rocks, also enriched with U and Ra, in the area of Mazury-Podlasie monocline. However, the least expected result of the investigations was finding out that, contrary to the hitherto widespread belief, none of the major tectonic units of Poland can be excluded from the list of those containing buildings with mean annual ²²²Rn concentration exceeding 200 Bq/m³. The mean annual concentration of radon for all the buildings were much higher than the mean concentration value (49.1 Bq/m³) of indoor radon in Poland quoted so far. These results cast a completely new light on the necessity to perform measurements of radon concentration in residential buildings in Poland, no more with reference to small areas with outcrops of crystalline rocks (especially the Sudetes, being the Polish fragment of the European Variscan belt), but for all the major tectonic units within Poland.