河流型水源地源水有机物种类分布特性及其与消毒副产物关系

研究了不同水文期条件下长三角某典型河流型水源地源水有机物种类分布特性及其与消毒副产物关系。结果表明，该水源地源水有机污染特性呈现出丰水期>平水期>枯水期的特点，水体腐殖化程度依次降低。经树脂富集分离后水样溶解性有机物(DOM)各组分占总有机碳(DOC)的比例有所不同。丰水期：疏水性有机酸(HPO A,38%)>亲水性有机物(HPI,26%)>过渡亲水性有机酸(TPI A,16%)>疏水性有机中性物质(HPO N,12%)>过渡亲水性中性物质(TPI N,8%)；平水期：HPO A(32%)>HPO N(22%)>TPI A(20%)>HPI(18%)>TPI N(8%)；枯水期：HPO A(28%)>TPI A(24%)>HPO N(20%)>HPI(19%)>TPI N(9%)。DOM中仅HPI组分比紫外吸光度值(SUVA)低于原水，其余均高于原水，其中HPO A组分SUVA值最高，是原水的177倍。各水文期条件下，疏水性有机物（疏水性有机酸和疏水性中性物质）对三卤甲烷和卤乙酸生成的贡献，分别超过全部有机物氯化后消毒副产物生成量的60%和65%，表明疏水性有机物是最主要的消毒副产物前体物，应当作为水处理工艺重点去除的有机物组分。各水文期源水有机物特性与消毒副产物生成潜能的关系变化不大，三卤甲烷生成潜能(STHMFP)与SUVA的线性相关度较高，卤乙酸生成潜能(SHAAFP)与SUVA的线性相关度一般。因此，可用水样SUVA值间接反映三卤甲烷生成潜能，以利于在实际生产中快速监控水中消毒副产物前体物的变化趋势     

Two-Compartment Sorption of Phenanthrene on Eight Soils with Various Organic Carbon Contents

Sorption characteristics of phenanthrene (PHE) were studied on eight soils with organic carbon contents spanning over an order of magnitude using phase distribution relationships (PDRs) at 1 h, 48 h, and 720 h contact times. A new algebraic method was employed to describe the sorption characteristics at different time intervals (between 1 h and 48 h, and 1 h and 720 h). It was found that nonlinearity increased with increasing contact time and sorption that occurred in the subsequent time interval following the initial 1 h exhibited stronger isotherm nonlinearity. Sorption coefficients were positively correlated with the organic carbon contents of the soils. Detailed sorption dynamics were also examined on these soils. A two-compartment, first-order model was used to describe the sorption dynamics. The rate constants of the two compartments differed 18–170 times, suggesting the dissimilar sorption behaviors of the mathematically separated compartments. These two compartments were labeled fast and slow sorption compartment according to the rate constants. Calculation showed that the fast compartment accounted for over 80% of the overall sorption at the initial 1 h, while the slow compartment predominated the total sorption in the following 47 h. By combining the discussion of PDRs and sorption dynamics, the contributions of the two compartments to linear and nonlinear sorption were differentiated. The slow sorption compartment made a major contribution to nonlinear sorption and possibly to sequestration of organic pollutants by these soils.     

Production of the monoclonal antibody against tylosin for immunoassay of macrolide antibiotics in milk

The objective of the present study was to develop an immunoassay for multi-determination of the residues of four macrolide antibiotics in milk. Tylosin was derivatized with 6-aminohexanoic acid to synthesize a hapten that was used to produce the monoclonal antibody. The obtained monoclonal antibody simultaneously recognized tylosin, acetylisovaleryltylosin, tilmicosin and desmycosin with crossreactivities of 100%, 91%, 49% and 76%, respectively. Then an indirect competitive immunoassay was developed to determine the four analytes in milk simultaneously. The limits of detection for the four analytes were in the range of 5.5–11.7 ng/mL depending on the compound. The recoveries of the four analytes from fortified blank milk were in the range of 78%–96% with coefficients of variation lower than 11.4%. The developed immunoassay could be used as a practical tool for rapid screening the residues of the four anlytes in milk.     

Investigation of the positive artifact formation during sampling semi-volatile aerosol using wet denuders

Wet denuders are used in several steam-based semi-continuous aerosol monitors to avoid gaseous absorption artifacts and pre-humidify the air stream, while simultaneously allowing measurements of water-soluble gaseous species. Unlike dry denuders, wet denuders saturate the sample air stream with water vapor, which can lead to re-partitioning of water-soluble volatile species to the aerosol phase, thereby causing a positive artifact in aerosol measurements. This paper investigates the magnitude of the positive artifact formation occurring in wet denuders using modeling techniques. Gaseous nitric acid was used as an example of volatile water-soluble gas in both flat and annular wet denuders. We have also verified the occurrence of the positive artifact in a flat wet denuder through a laboratory experiment. The model results indicate that the magnitude of the artifact is rather limited under typical conditions being less than 2.5% of ambient nitric acid concentration for the flat denuder and less than 0.6% for the annular denuder. The magnitude of the artifact increases with condensational sink of the aerosol (i.e. with the mean aerosol size and number concentration) and aerosol water solubility. While the artifact is relatively small in the absolute sense, it could be substantial for aerosol nitrate measurements, especially in ammonia limited conditions, when the concentration of the nitric acid is high and the concentration of nitrate is low. Therefore, we recommend that the artifact is assessed regularly by replacing the wet denuder with a dry denuder.     

厦门海岸带湿地变化的研究

通过“压力-状态-响应”分析模型，对厦门海岸带湿地变化的主要原因（压力）、成分退化和结构改变（状态）以及对厦门海岸带生态系统的主要影响（响应力）之间的作用机制进行了探讨。提出厦门海岸带湿地面临的主要压力来自海岸带围垦造地、近海滩涂养殖和九龙江河口输入；状态变化突出表现在浅海海域面积的减少。红树林的面积减少。近岸泥沙淤积。沉积物类型改变和沉积物污染；主要影响是造成厦门海域水质下降、近海底橙生物类型改变、航道泥沙淤积、水产养殖产量下降和珍稀海洋物种分布和数量改变。     

我国矿山生态环境保护法律制度完善问题研究

在资源主导型的经济发展模式下,矿产资源无疑是我国经济社会发展的重要支柱.但矿业是高污染行业,特别是近年来我国矿产资源持续大规模的勘探开采,引起了一系列严重的矿山环境问题,矿山生态环境急剧恶化,其影响已涉及经济社会发展的方方面面,因此加强和完善我国矿山生态环境制度建设至关重要.文章首先介绍了我国矿山环境恢复机制的现行制度框架,在此框架的基础上,对我国矿山环境状况恶化的现实进行了深层次的原因分析,剖析了目前我国针对矿山环境问题的意识、立法执法、资金技术的现实状况.接下来,对我国矿山生态环境恢复治理机制进行了宏观构建.笔者认为,要从三个方面对我国的矿山生态环境恢复机制进行构建.首先是调整矿山生态环境保护法律制度;第二,完善矿山环境保护机制;第三,建立矿山企业自身环保机制.     

滑行车类游乐设施动力学建模与仿真

根据滑行车类游乐设施运行速度高、加速度大、载荷工况复杂,发生事故后果非常严重的现状,认为深入的动力学分析、结构强度校核和寿命分析预测对保证其安全性尤为必要。因而分析滑行车的结构原理,提出其多体系统拓扑构型,包括轮轨关系模型、各零部件之间约束模型。运用图形学方法研究了滑行车轨道建模参数提取和坐标变换技术。通过仿真分析,在设计阶段就可获得滑行车在不同工况下运行时各部件的速度、加速度及载荷时间历程,为结构设计、安全性评估提供可靠依据。实例表明,分析结果与实测数据非常接近,所提出的建模方法是可行的。     

贫困地区可持续发展指标体系及其综合评估--以湖南湘西贫困地区为例

本文依据贫困地区可持续发展固有的制约因素，特殊的内涵与目标，首次利用压力（Pressure)——状态（State)——响应（Respons)模型，构建了贫困地区可持续发展指标体系，并采用专家咨询与定量模型相结合的方法，对湖南湘西贫困地区可持续发展水平作了实证评估与分析。     

福建太姥山龙潭洞地质环境与景观资源特征

本文系统论述了福建太姥山龙潭洞所在地域的自然地理、区域地质及环境地质条件，并对龙潭洞的规模形态、形成机制及景观资源特点进行讨论，为龙潭洞旅游资源的开发利用及总体规划设计提供参考依据。