电导和直流安培双检测器离子色谱法测定清洁水样中的碘化物

选用配备了2种不同检测器(电导检测器和直流安培检测器)的离子色谱仪对稀释后过0.22μm滤膜的水样进行分析。配备有直流安培检测器的离子色谱仪测定水中碘化物的方法在0.100~20.0μg/L范围内线性关系良好,相关系数(r)=0.9999,方法检出限为0.030μg/L,测定下限为0.120μg/L,样品加标回收率为95.0%~104%,相对标准偏差为1.06%~1.64%;配备有电导检测器的离子色谱仪测定水中碘化物的方法在20.0~2.00×105μg/L范围内线性关系良好,相关系数(r)=0.9995,方法检出限为2.00μg/L,测定下限为8.00μg/L,样品加标回收率为99.0%~110%,相对标准偏差为0.71%~3.12%。离子色谱-直流安培检测器法测定水中碘化物的方法准确度高、灵敏度高、精密度好,检出限相对较低,适用于测定ρ(碘化物)≤20.0μg/L的清洁水样;离子色谱-电导检测器法主要适用于测定ρ(碘化物)≥20.0μg/L的水样。     

白洋淀水环境容量核算及上游容量分配

根据多年的水质监测资料、设计水文条件及水质目标等参数,在划分容量分配控制单元的基础上,运用浅水湖泊污染物水环境容量计算方法计算了COD_Cr和NH₃-N的环境容量,并给出了体现社会性、经济性的水环境容量分配方案,采用基尼系数法对分配方案进行公平性评估。结果表明,白洋淀南刘庄、烧车淀、采蒲台各区域的COD_Cr容量分别为2 526.8,328.5和1 430.8 t/a;NH₃-N容量为155.0,73.0和255.5 t/a。白洋淀上游各控制单元指标的基尼系数值均小于0.4,分配结果较为合理。     

路堤荷载下带桩帽刚性桩复合地基桩土应力比分析

路堤一般由填土、碎石等散体材料组成,刚性桩复合地基中,桩土刚度差异较大引起的桩土间沉降差异,会导致路堤内部出现相对竖向位移。通过路堤填土的受力平衡分析,根据桩土差异沉降,求解出桩帽和桩帽间土体的应力分配,并结合桩帽下应力分配得出桩身应力,最终求解出桩土应力比及桩的荷载分担比例。工程实例监测结果验证了文中计算公式的适用性和可靠性。通过分析计算结果和实测结果,得出了一些路堤荷载下刚性桩复合地基的承载规律,可供理论研究和工程设计参考。     

Effects of productivity on biodiversity in forest ecosystems across the United States and China

In the global campaign against biodiversity loss in forest ecosystems, land managers need to know the status of forest biodiversity, but practical guidelines for conserving biodiversity in forest management are lacking. A major obstacle is the incomplete understanding of the relationship between site primary productivity and plant diversity, due to insufficient ecosystem‐wide data, especially for taxonomically and structurally diverse forest ecosystems. We investigated the effects of site productivity (the site's inherent capacity to grow timber) on tree species richness across 19 types of forest ecosystems in North America and China through 3 ground‐sourced forest inventory data sets (U.S. Forest Inventory and Analysis, Cooperative Alaska Forest Inventory, and Chinese Forest Management Planning Inventory). All forest types conformed to a consistent and highly significant (P < 0.001) hump‐shaped unimodal relationship, of which the generalized coefficients of determination averaged 20.5% over all the forest types. That is, tree species richness first increased as productivity increased at a progressively slower rate, and, after reaching a maximum, richness started to decline. Our consistent findings suggest that forests of high productivity would sustain few species because they consist mostly of flat homogeneous areas lacking an environmental gradient along which a diversity of species with different habitats can coexist. The consistency of the productivity–biodiversity relationship among the 3 data sets we examined makes it possible to quantify the expected tree species richness that a forest stand is capable of sustaining, and a comparison between the actual species richness and the sustainable values can be useful in prioritizing conservation efforts.     

城市电力供应系统公共安全风险评估体系及应用

城市电力供应系统与城市公共安全关系紧密，文章分析了导致城市电力供应系统故障或事故的主要风险因素、事故类型及其风险程度，建立了城市电力供应系统公共安全风险评估体系。利用建立的风险评估体系，对某市电力供应系统的安全性进行了风险评估，同时验证了该体系在城市电力供应系统风险评估中的良好适用性。     

Polycyclic aromatic hydrocarbon and n-alkane pollution characteristics and structural and functional perturbations to the microbial community: a case-study of historically petroleum-contaminated soil

Characterization of the typical petroleum pollutants, polycyclic aromatic hydrocarbons (PAHs) and n-alkanes, and indigenous microbial community structure and function in historically contaminated soil at petrol stations is critical. Five soil samples were collected from a petrol station in Beijing, China. The concentrations of 16 PAHs and 31 n-alkanes were measured by gas chromatography-mass spectrometry. The total concentrations of PAHs and n-alkanes ranged from 973 ± 55 to 2667 ± 183 μg/kg and 6.40 ± 0.38 to 8.65 ± 0.59 mg/kg (dry weight), respectively, which increased with depth. According to the observed molecular indices, PAHs and n-alkanes originated mostly from petroleum-related sources. The levels of ΣPAHs and the total toxic benzo[a]pyrene equivalent (ranging from 6.41 to 72.54 μg/kg) might exert adverse biological effects. Shotgun metagenomic sequencing was employed to investigate the indigenous microbial community structure and function. The results revealed that Proteobacteria and Actinobacteria were the most abundant phyla, and Nocardioides and Microbacterium were the important genera. Based on COG and KEGG annotations, the highly abundant functional classes were identified, and these functions were involved in allowing microorganisms to adapt to the pressure from contaminants. Five petroleum hydrocarbon degradation-related genes were annotated, revealing the distribution of degrading microorganisms. This work facilitates the understanding of the composition, source, and potential ecological impacts of residual PAHs and n-alkanes in historically contaminated soil.

     

A review on fabricating functional materials by heavy metal–containing sludges

Environmental Science and Pollution Research - With the development of industry, sustainable use of natural resources has become a worldwide hot topic. Heavy metal–containing sludge (HMS) is...     

Removal of SO2 from smelting flue gas by using copper tailings with MnSO4: factors optimization by response surface methodology

Environmental Science and Pollution Research - The abatement of SO2 and the utilization of copper tailings are identified as two attention-attracting environmental issues in the copper smelter. In...     

The permeability of dredged material-bentonite backfills

Environmental Science and Pollution Research - Extensive attention has been paid to the treatment and disposal of dredged material, and there is a need to clarify the feasibility of recycling...