Screening of indicator pharmaceuticals and personal care products in landfill leachates: a case study in Shanghai,China

● A systematic framework was developed to identify i-PPCPs for landfill leachate. ● The wide-scope target analysis offered a basis for comprehensive i-PPCP screening. ● Source-specificity and representativeness analysis helped to refine i-PPCPs. ● Erythromycin, gemfibrozil and albendazole were identified as i-PPCPs for leachate. Identifying potential sources of pharmaceuticals and personal care products (PPCPs) in the environment is critical for the effective control of PPCP contamination. Landfill leachate is an important source of PPCPs in water; however, it has barely been involved in source apportionment due to the lack of indicator-PPCPs (i-PPCPs) in landfill leachates. This study provides the first systematic framework for identifying i-PPCPs for landfill leachates based on the wide-scope target monitoring of PPCPs. The number of target PPCPs increased from < 20 in previous studies to 68 in the present study. Fifty-nine PPCPs were detected, with median concentrations in leachate samples ranging from below the method quantification limit (MQL) to 41 μg/L, and 19 of them were rarely reported previously. A total of 29 target compounds were determined to be PPCPs of high concern by principal component analysis according to multiple criteria, including occurrence, exposure potential, and ecological effect. Coupled with source-specificity and representativeness analysis, erythromycin, gemfibrozil, and albendazole showed a significant difference in their occurrence in leachate compared to other potential sources (untreated and treated municipal wastewater and livestock wastewater) and correlated with total PPCP concentrations; these were recommended as i-PPCPs for leachates. Indicator screening procedure can be used to develop a sophisticated source apportionment method to identify sources of PPCPs from adjacent landfills.     

一种便携式荧光测油仪在海上溢油应急监测中的适用性研究

研究了一种便携式荧光测油仪在海上溢油应急监测中的适用性,并与现行仲裁标准方法进行比较分析。研究表明:该便携式荧光测油仪测定海水中油类样品仅需100 mL水样,平均每个样品所需的前处理时间约340 s,方法检出限为0.003 mg/L,测定下限为0.012 mg/L。测定用标准物质配制的不同浓度海水样品,相对标准偏差为0.08%~0.87%,测定标准样品的相对误差为0.49%~4.50%,实际样品加标回收率为90%~107%。对标准物质配制的海水样品进行检测,与现行仲裁标准方法在0.05水平下无显著性差异。在渤海中部海上监测中,连续6 d测定不同标准样品的相对标准偏差为0.26%~0.83%。研究结果表明,该便携式荧光测油仪适用于现场对油类的定量分析和水质评价。     

单通道方形海水养殖池基于流场均匀性的结构优化研究

由于海水循环养殖生产中常见的方形养殖池存在较大的低流速容积（死区容积）,本文提出以圆弧角代替直角的方式对方形养殖池结构进行优化,既保持较高空间利用率,又可以改善养殖池的流场均匀性。本文建立了不同圆弧角尺度养殖池的三维湍流数值计算模型,运用计算流体力学技术（computational fluid dynamics,CFD）对养殖池流场均匀性开展研究,重点分析了养殖池内流速分布,并提出研究流场均匀性的判别系数UC₅₀（均匀系数）。研究结果表明:相比方形养殖池,0.2≤R/B（相对弧宽比）<0.4时养殖池内的中流速区占比相对较高,流场均匀性显著改善。本文的研究成果为方形圆弧角养殖池的设计给予了理论依据,为方形养殖池的结构优化提供优选设计参数。     

GC/MS/MS法结合SPME进样测定饮用水中亚硝胺类化合物

本文利用岛津公司GCMS-TQ8050 NX三重四极杆气质联用仪以及AOC-6000自动进样器的SPME Arrow功能,建立了一种饮用水中亚硝胺类化合物的测定方法.水样经固相微萃取方式萃取后采用多反应监测模式(MRM)进行检测.11种亚硝胺类化合物在线性范围内线性关系良好,标准曲线相关系数(R) ＞0.999,检出限...     

上海沿海六区县自然灾害脆弱性评价

沿海城市在全球发展中具有重要的战略地位,然而特殊的地理位置和高度集中的人口及财富也决定了其面临灾害时具有较高的脆弱性,即同等灾害强度下,沿海城市遭遇自然灾害时的人口伤亡更多,经济损失更大。从灾害系统承灾体的角度,分析了影响灾害脆弱性的五个方面,顺应脆弱性评价定量化的趋势,依据一定的原则,不分灾种,面对区域和人群,选取代表性指标尝试构建了沿海城市自然灾害脆弱性的指标评价体系,利用AHP法对该区域相应指标的权重进行了确定,建立了脆弱性模型,并在收集和标准化数据的基础上,对上海沿海六区县进行了脆弱性评价,并对各个地区的区域脆弱性、人群脆弱性和整体脆弱性进行对比分析,为灾害管理提供理论依据。同时,通过评价结论,总结了沿海城市的自然灾害脆弱性特点,并为上海市降低脆弱性、减轻自然灾害影响提供对策建议。     

爆破地震波作用下尾矿坝的有限元动力分析

为了了解某钼矿进行爆破采矿是否会对近距离的尾矿坝产生破坏作用,结合实际勘探资料,在二维静力非线性有限元分析的基础上,进行爆破地震波作用下坝体的动力反应分析,综合研究了动位移、动应力和加速度时程等关键物理量变化的规律性,并在此基础上进一步结合试验资料对坝体进行了液化判断及稳定性分析。分析结果表明,该钼矿在规定的爆心距、药量范围内进行爆破采矿时,相邻的尾矿坝是安全稳定的。本文的研究结果对爆破设计、现场采矿及尾矿坝体运行维护均具有一定的指导意义。     

Succession of aquatic microbial communities as a result of the water quality variations in continuous water

The changes of structural and functional parameters of aquatic microbial communities in continuous water on campus of Tsinghua University, China are investigated by polyurethane foam unit(PFU) method. The measured compositions of the communities include alga, protozoa, and some metazoa (such as rotifers). The measured indicators of water quality include water temperature, pH value, dissolved oxygen (DO), potassium permanganate index(CODMn), total nitrogen(TN), total phosphorus(TP) and chlorophyll- a(Chla). The trophic level, expressed by the trophic level indices(TL/c), is assessed with analytic hierarchy process and principal component analysis (AHP-PCA) method. The changing trends of the structural and functional parameters of aquatic microbial communities, such as Margalef index of diversity(D), Shannon-weaver index of diversity (H), Heterotropy index (HI), number of species when the colonization gets equilibrium(Seq), colonizing speed constant(G) and time spent when 90 percent of Seq colonized in PFU ( T90% ), are also analyzed. The experimental results showed the succession of aquatic microbial communities along the water flow is consistent with the water quality changes, so the parameters of microbial community can reflect the changes of water quality from the ecological view.     

Using a zeolite medium biofilter to remove organic pollutant and ammonia simultaneously

IntroductionWatershortageproblemisquiteseriousinmanycitiesofChina .Thereuseofmunicipalwastewaterisoneofthekeymethodstoreleasethisproblem .Makeupwaterforrecirculatingcoolingsystemisthelargestwaterusageinmanyfactories .Thewaterqualitystandardsforreclaimedwa…     

受限空间煤尘爆炸毒害气体传播伤害研究

为减少煤矿煤尘爆炸后毒气对人的危害,为煤矿防爆、抑爆和安全评价,以及事故应急救援等提供理论依据,研究了煤尘爆炸后毒气的传播伤害规律。基于质量守恒定律与空气动力学理论,建立煤尘爆炸后风流作用下的毒害气体在受限空间内的数学传播模型,得到巷道内毒气传播的弥散系数,计算出沿爆炸传播方向毒气浓度随距离变化的关系,划分伤害三区并推导出相应的伤害范围计算公式。研究表明:毒气传播的峰值点随风流方向移动,其峰值点浓度逐渐变小。     

基于计划行为理论的自行车不安全行为模型研究

依托国家道路交通安全科技行动计划课题五"全民交通行为安全性提升综合技术及示范"专题,基于计划行为理论,从社会心理学的角度首次对自行车骑行者的不安全行为进行分析。在增加变量的基础上,通过调查问卷的方式,研究自行车骑行者对不安全行为的态度、主观规范、知觉行为控制、行为经验等心理因素,从而构建自行车不安全行为模型。从调查数据的结构方程模型分析和个人属性分析可知,在调查人群中存在对不安全行为没有正确认识、自觉守法能力较弱和普遍有不安全行为经验等问题,同时也确定了参与不安全行为的重点人群。最后,在揭示心理因素作用于行为的基础上提出家庭式安全教育、加强交警管理、提倡榜样学习、加强交通安全宣传等行为矫正手段。