Assessing Ecological Resources for Remediation and Future Land Uses on Contaminated Lands

Increasingly, the public and governmental agencies are concerned about remediating and reclaiming contaminated sites. Understanding the ecological resources on-site and valuing those resources in terms of future uses is important for determining suitable future land uses. In this article, we suggest the major categories of natural resource information required by managers, policy makers, and the general public for making initial future land-use determinations. We then use a dataset of 25 Department of Energy (DOE) sites slated for remediation to explore whether such data are readily available and whether the data can be used to assess natural resource value. Although information is available for almost all sites on federally endangered and threatened species, this information is less available for state-listed species. Biodiversity information is available only for some sites for birds (N = 17), mammals (N = 15), reptiles (N = 14), amphibians (N = 13), and plants (N = 11) and is almost nonexistent for invertebrates (N = 2). Some information is available for invasive species (N = 9). The number of available habitats is directly related to total acres and nonindustrial acres. Biodiversity of birds, mammals, and reptiles (but not amphibians) is directly related to both total acres and total nonindustrial acres of sites. These data suggest that even over a wide geographical area (from eastern to western United States), biodiversity relates to habitat size and number of habitats available. This information will be useful not only to DOE managers but also to natural resource trustees, ecologists, state and federal regulators, and the general public in the discourse over future uses of these lands.*Published online Author to whom correspondence should be addressed; Joanna Burger     

Modified Fenton's processes for effective in‐situ chemical oxidation—Laboratory and field evaluation

Fenton's reagent in its conventional form, although effective for contaminant treatment, is impractical from an in‐situ field application perspective due to low pH requirements (i.e., pH 3‐4), and limited reagent mobility when introduced into the subsurface. Modified Fenton's processes that use chelated‐iron catalysts and stabilized hydrogen peroxide have been developed with the goal of promoting effective in‐situ field application under native pH conditions (i.e., pH 5‐7), while extending the longevity of hydrogen peroxide. Laboratory experiments conducted in soil columns packed with organic soil to compare modified Fenton's catalysts with conventional catalysts (acidified iron [II]) indicated superior mobility and sorption characteristics for modified Fenton's catalysts. Furthermore, the acidic pH of a conventional catalyst was buffered to the native soil range, leading to increased iron precipitation/adsorption following permeation through the soil column. The chelates present within the modified Fenton's catalyst showed greater affinity toward iron compared with the native soil and, hence, minimized iron loss through adsorption during the permeation process even at pH 5‐7. Field effectiveness of the modified Fenton's process was demonstrated at a former dry‐cleaning facility located in northeast Florida. Preliminary laboratory‐scale experiments were conducted on soil‐slurry and groundwater samples to test the process efficacy for remediation of chlorinated solvents. Based on successful experimental results that indicated a 94 percent (soil slurry) to 99 percent (groundwater) reduction of cis‐1,2‐DCE, PCE, and TCE, a field‐scale treatment program was initiated utilizing a plurality of dual‐zone direct push injection points installed in a grid fashion throughout the site. Results of treatment indicated a 72 percent reduction in total chlorinated contamination detected in the site groundwater following the first injection event; the reduction increased to 90 percent following the second injection event. © 2002 Wiley Periodicals Inc.     

Predicting employee aggression against coworkers,subordinates and supervisors: the roles of person behaviors and perceived workplace factors

Predictors of employee aggression against coworkers, subordinates, and supervisors were studied in a sample of 136 men employed full‐time. Person behaviors (history of aggression, amount of alcohol consumed) predicted aggression against a coworker. In contrast, aggression against a supervisor was predicted by two perceived workplace factors (procedural justice, workplace surveillance). However, neither person behaviors nor perceived workplace factors predicted aggression against a subordinate. In addition, person behaviors and perceived workplace factors interacted to predict aggression. First, procedural justice interacted with amount of alcohol consumed in predicting both aggression against a coworker and aggression against a subordinate. Secondly, both job security and procedural justice interacted with history of aggression in predicting aggression against a subordinate. Finally, job security and amount of alcohol consumed interacted to predict aggression against a subordinate. Results suggest that both the understanding and prediction of employee aggression will be enhanced by taking into account the target of employee aggression, and by including both perceived workplace factors and person behaviors as predictor variables. Copyright © 1999 John Wiley & Sons, Ltd.     

Public preferences for environmental management practices at DOE's nuclear waste sites

Residents who lived within 50 miles of one of six major US Department of Energy nuclear waste sites were asked in 2005 and again in 2010 to rate environmental management options. Respondents expressed strong preference for continuously sampling the air and water, monitoring worker health, and providing training and equipment to local responders. They strongly supported some site restrictions, such as making sure that the federal government owns the site until no more hazards are present, keeping visitors and recreational users off the site, and requiring government officials to report information to community representatives. The public was much more equivocal about other options, such as restricting new nuclear‐related activities and requiring site managers to live near sites. The authors summarize factors that lead to these public preferences and discuss five population types encountered at these and perhaps other waste management sites. © 2011 Wiley Periodicals, Inc.     

Citizen board issues and local newspaper coverage of risk,remediation, and environmental management: Six U.S. nuclear weapons facilities

We examined site‐specific advisory board (SSAB) minutes and local newspaper coverage of the Fernald, Hanford, Idaho, Oak Ridge, Rocky Flats, and Savannah River sites of the U.S. Department of Energy (US DOE) in order to determine the importance of risk‐related issues related to remediation and other forms of environmental management. About one‐third of SSAB issues were risk‐related, and these were disproportionately major issues at meetings. The media focused on risks associated with remediation and other forms of waste management. The analysis implies that contractors and government officials need to establish and maintain communications with advisory panels and accentuate these contacts well in advance of contemplated new actions. © 2008 Wiley Periodicals, Inc.     

Brownfield redevelopment as a smart growth option in the United States

An evaluation is made of brownfields redevelopment as a smart growth policy compared to purchase of land, restrictive growth policies, changing transportation patterns, promoting compact development designs on the metropolitan fringe, and regional government. In the US brownfields redevelopment has clear advantages with regard to environmental protection, moral imperative, and government and special interest reactions. Its rank with regard to economic feasibility, ability to respond to changes in technology, and public reaction are not clear. A great deal more research is needed, especially about the costs of brownfield redevelopment and public preferences for housing type and location to be certain about brownfields redevelopment as a viable smart growth option.     

An experimental study of habitat selection by birds in a coffee plantation

Unique components of tropical habitats, such as abundant vascular epiphytes, influence the distribution of species and can contribute to the high diversity of many animal groups in the tropics. However, the role of such features in habitat selection and demography of individual species has not been established. Understanding the mechanisms of habitat selection requires both experimental manipulation of habitat structure and detailed estimation of the behavioral and demographic response of animals, e.g., changes in movement patterns and survival probabilities. Such studies have not been conducted in natural tropical forest, perhaps because of high habitat heterogeneity, high species diversity, and low abundances of potential target species. Agroforestry systems support a less diverse flora, with greater spatial homogeneity which, in turn, harbors lower overall species diversity with greater numerical dominance of common species, than natural forests. Furthermore, agroforestry systems are already extensively managed and lend themselves easily to larger scale habitat manipulations than protected natural forest. Thus, agroforestry systems provide a good model environment for beginning to understand processes underlying habitat selection in tropical forest animals. Here, we use multistate, capture-recapture models to investigate how the experimental removal of epiphytes affected monthly movement and survival probabilities of two resident bird species (Common Bush-Tanager [Chlorospingus ophthalmicus] and Golden-crowned Warbler [Basileuterus culicivorus]) in a Mexican shade coffee plantation. We established two paired plots of epiphyte removal and control. We found that Bush-Tanagers were at least five times more likely to emigrate from plots where epiphytes were removed compared to control plots. Habitat-specific movement patterns were not detected in the warbler. However, unlike the Golden-crowned Warbler, Common Bush-Tanagers depend upon epiphytes for nest sites and (seasonally) for foraging. These dispersal patterns imply that active habitat selection based on the presence or absence of epiphytes occurs in C. ophthalmicus on our study area. Survival rates did not vary with habitat in either species. Interestingly, in both species, survival was higher in the nonbreeding season, when birds were in mixed-species flocks. Movement by Common Bush-Tanagers into areas with epiphytes occurred mostly during the breeding season, when mortality-driven opportunity was greatest.