Catalytic effect of soil colloids on the reaction between CrVI and p-methoxyphenol

Adsorption of CrVI and p-methoxyphenol (PMP) on soil colloids at different pH media was studied. The resulting k1 and n of 1.89 x 10(2) and 0.53 (r2 = 0.99) and k2 and b of 0.13 and 1.25 x 10(3) (r2 = 0.96) were obtained from Freundlich (Q = k1Caqn) and Langmuir [Q = k2bCaq/(1 + k2Caq)] simulation equations, respectively, for CrVI adsorption on soil colloids (pH 4.20). The adsorption of PMP on soil colloids in pH 5.72 media was simulated by five different equations and the results indicated that the Fritz-Schluender one (r2 = 1.00) was the most suitable among them. Adsorption quantity of CrVI and PMP on colloids increased with increasing acidity in the pH range of 3.5-9.0. Study of CrVI adsorption kinetics indicated that the adsorption equilibrium of CrVI was reached rapidly within 2 h. In pure aqueous solution, CrVI reduction by PMP was observed only when the media's pH was lower than 4.0. Oxidation and reduction reaction between CrVI and p-methoxyphenol obviously occurred when soil colloids were involved in this system, even at pH > or = 7.0, which strongly suggested that minerals in soil colloids acted as catalysts to speed the reaction of CrVI and PMP. The oxidized product of PMP by CrVI, extracted by chloroform in acid media and analyzed by gas chromatography-mass spectrometry, was identified as benzoquinone. The reaction included two steps of one electron process.     

印染废水脱色技术与理论述评

文章介绍了印染废水典型脱色技术的现状和进展,并着重分析了各种脱色技术的脱色机制,突出了典型脱色技术中的理论因素,介绍并阐明了一些脱色理论新观点,如吸附剂改性增效原理、分子结构与絮凝效果的联系、小剂量氧化剂偶合絮凝、脱色菌的质粒对脱色率的影响等,并从工艺角度分析了各种脱色方法的应用.     

电化学法生成Fenton试剂及其在工业染料废水降解脱色中的应用

以多孔石墨电极为阴极 ,电解时在阴极通以氧气或空气 ,电解生成的过氧化氢与阳极溶解的Fe2 +进行随后化学反应 ,现场生成羟基自由基 (Fenton试剂 ) ,进而对有机染整工业废水进行降解脱色反应。以可见光吸收谱图表征了工业染料废水经电解槽处理后吸光度的变化 ,以重铬酸钾法测试染料处理后的COD。实验结果表明 ,COD的去除率大于 80 % ,染料的脱色率达 1 0 0 % ,若将电解电流密度控制在 1 0mA/cm2 以下 ,槽电压可控制在 5V以内。实验结果表明 ,向阴极多孔石墨电极中通入空气与通入氧气的效果一致。     

覆膜滤料对特殊烟尘处理的优越性

覆膜滤料是新型的过滤材料 ,弥补了普通滤料在烟尘处理过程中的不足。特别是对含油雾、粘结性强的粉尘以及高湿等特殊烟尘治理具有良好的效果     

A comparison of mussels (Perna viridis) and semi-permeable membrane devices (SPMDs) for monitoring chlorinated trace organic contaminants in Hong Kong coastal waters

A comparison of mussels (Perna viridis) and semi-permeable membrane devices (SPMDs) was carried out at five sites, representing a gradient of contaminant concentrations, in Hong Kong coastal waters. Mussels, originally collected from a “clean” location, were deployed along with SPMDs at each site for 30 days. Analyses for chlorinated pesticides and polychlorinated biphenyls (PCBs) indicated that SPMDs have potential as monitoring tools, and to some extent can overcome the problems associated with mussels, such as natural variability, differing age, sex, and physical condition. However, in most cases, SPMDs failed to rank the sites in the same order as mussels in terms of contaminant concentrations. Nonetheless, in localities where mussels cannot survive – as shown at Kwun Tong in the present experiment – SPMDs may be valuable in providing an indication of potentially bio-available lipophilic pollutants.     

基于健康风险的危险废物智能化分级分类研究

在分析国内外危险废物分级管理经验的基础上,结合健康风险的评估步骤,提出了基于全过程危险废物污染物释放情景的精细化-动态健康风险评价方法。充分考虑处理利用工艺、企业管理水平等因素对于危险废物中污染物释放概率和能力的影响,并基于污染物向环境介质的迁移转化,定量评估危险废物的健康风险。基于危险废物污染特性数据库和事故情景数据库,结合全过程信息采集技术,构建危险废物分级分类管理平台,进行涉废企业的风险级别划分,实施差异化管理,形成更加科学有效的危险废物全过程精细化管理体系。     

SO2-4/TiO2表面的酸性对其光催化性能的影响

采用Na2CO3溶液将SO2-4/TiO2表面的SO2-4洗脱下来,用热重(TG)、NH3程序升温脱附(NH3-TPD)和吡啶吸附的红外光谱等手段,分析洗脱前后SO2-4/TiO2表面的酸量和酸类型的变化;在相同晶型、结晶度和吸光特性条件下,考察了SO2-4/TiO2表面的酸性对Cr(Ⅵ)光催化还原效率的影响.结果表明:SO2-4/TiO2表面同时存在Lewis酸位和Bronsted酸位,通过Na2CO3溶液降低SO2-4/TiO2表面的酸量并去除Bronsted酸位后,其对Cr(Ⅵ)的光催化活性显著降低.     

有机废水制取氢气及COD的去除

针对当前能源紧缺以及有机废水治理和回收再利用的需求,采用驯化的河底污泥发酵模拟有机废水,研究了不同有机废水制取氢气和去除有机物的效果.结果表明:在相同条件下,糖源质量浓度均为1.67 g·L-1、废水体积为300 mL、pH=5.5、θ=40℃时,糖源为葡萄糖、蔗糖和淀粉的三种有机废水总产氢气量分别是309.36 mL,318.18 mL,8.20 mL,含蔗糖的废水总产氢气量最高.含蔗糖和葡萄糖的废水COD去除率分别是78.00%和76.92%,而含淀粉的废水COD去除率仅为55%.此外,废水产氢规律与从污泥里筛选出的产氢菌生长曲线有密切的关系.厌氧发酵产氢是一个复杂的过程,它受底物种类、底物浓度、pH值和温度等因素的影响.用驯化的污泥来发酵含糖浓度较高的有机废水,不仅可以收集到大量的生物质能氢气,而且一定程度上缓解了有机废水污染环境的问题.     

红树林生态系统微生物学研究进展

红树林生态系统是复杂而独特的生态系统,是目前环境科学和生态学研究的热点领域,而对红树林生态系统微生物学的研究也越来越受到重视,目前研究的热点主要集中在红树林生态系统微生物的物种多样性、生理活性物质多样性以及环境修复功能上.未来的研究,除了现有的研究基础要加强,研究手段与方法要采用新技术外,还应该在探索红树林生态系统微生物与物质和能量平衡、微生物与其它生物及其与气候的关系等方面进一步深入研究.     

珠江三角洲城市群大气微生物与环境相关性

运用生态学的方法,结合实地调查与数理统计分析,对珠江三角洲城市群的大气微生物与环境的相关性问题进行探讨,拟为珠江三角洲城市环境污染的综合防治和卫生防疫工作提供依据,研究结果表明.(1)珠江三角洲城市群中广州和东莞的大气微生物含量较高,其中细菌比真菌含量高;室内较室外,无绿化地较有绿化地的大气微生物含量高,在全年中,春、夏季节的大气微生物含量相对较高.(2)大气风速、湿度、气温、可吸入颗粒、总悬浮颗粒、人口流动,绿化状况等环境因子与大气微生物真菌、细菌的平均含量有较明显的相关关系,大气微生物含量与气象因子多数呈正或负的线性关系.相关分析的计算结果为:真菌、细菌平均含量在春、夏、秋、冬四个季度中与大气温度、湿度、风速大多数地区相关程度比较高,其值R在0.583～0.988之间,真菌、细菌与可吸人颗粒数和总悬浮颗粒数,R值分别为为0.525,0.388和0.081,-0.044.一元线性回归分析和多元线性回归分析计算结果为:大气微生物含量与气象因子有明显的正或负的线性关系.真菌、细菌的平均含量与温度、湿度、风速一元线性回归模型的置信水平较高,其p值大多在0.019～0.483之间,T值在0.001～0.246之间;多元线性回归模型的置信水平也较高,其P值大多数在0.083～0.220之间,T值在0.026～0.132之间;排序值显示:温度、风速变化是大气微生物含量高低影响重要性最大的环境因子.(3)统计数据比较分析表明:大气微生物含量与人口密集状况、人口流动大小和绿化状况好坏也有较明显的相关性,火车站,汽车客运站售票厅,人口流量大,绿化无,大气微生物(真菌细菌)平均含量高;而人口流量相对较少,但车流量大,有一定的绿化带的道路大气微生物平均含量较低;环境条件、绿化较好的公园绿地大气微生物含量低,车流、人流多,绿化少的地段、商业中心大气微生物含量较高.