Kinetic-spectrophotometric determination of free cyanide by stopped-flow reversed flow injection analysis

A stopped-flow reversed flow injection method for the determination of free cyanide is proposed. Pyridine-barbituric acid mixture is injected in the flow system as reagent to form the colour species with cyanide. The flow is stopped when the reagent zone comes in the flow cell, where absorbance-time data are collected at 580nm wavelength. The linear range of the determination is 0.1 -10μg/ml CN-. The sampling rate is 60h-1 and the relative standard deviation is 1.6% (n=16) at 5.0 μg/ml CN-1 level. With satisfactory results, the proposed method was applied to the determination of free cyanide in wastewater without sample pretreatment.     

氯氟烃及其替代物

近年来,臭氧衰竭比原先预料的更严重,对人类健康和环境构成了严重威胁。“蒙特利尔议定书”和“大气清洁法案”要求2000年要完全清除致臭氧衰竭物质——氯氟烃(CFCs)的生产和使用。目前,世界各地积极开发CFCs的替代物,以加速转换。虽然已开发的氧氯氟烃(HCFCs)、氢氟烃(HFCs)等替代物与CFCs相比还有一定缺点,但最终一定会实现替代转换。     

政府必须具备绿色控制能力——访内蒙古自治区人大常委会副主任陈瑞清

现任内蒙古自治区人大常委会副主任的陈瑞清，是一位地地道道的北京人。1965年8月，他从北京中央民族学院历史系毕业，却选择了在内蒙古西部生态环境最恶劣的阿拉善盟当教师，之后又当过副旗长和副盟长，这样一干就是30年!也许正是这样一段艰苦的岁月，历练出他对生态环境保护的执着信念。1998年1月，陈瑞清由呼和浩特市副市长当选为内蒙古自治区人大常委会副主任，分管环境与资源保护的法治工作。新世纪以来，他多次呼吁生态建设产业化、经济发展生态化，循环经济实质上是生态经济，发展循环经济势在必行。[编者按]     

催化技术在污染物治理应用的研究进展

对近年来催化技术在污染物治理应用的研究进展进行了综述,指出了现在研究中存在的主要问题,并对其前景进行了展望。     

摆辗机摆头运动学分析和运动轨迹的数值模拟

从摆动辗压机中摆头的结构出发．通过运动学分析给出摆头运动方程，采用数值方法对摆头运动轨迹进行数值模拟，为摆辗机结构设计和摆辗工艺的合理应用提供科学依据。     

杞麓湖主要污染物的动态变化特征研究

以１９９７年杞麓湖水质监测结果为基础，运用相关分析，双因子方差分析等方法，对杞麓湖主要污染物动态变化特征的研究结果表明，杞麓湖主要污染物的空间分布较为均匀；ＢＯＤ５和ＴＮ都有较为明显的季节变化。     

化学发光流动注射法测定雨水中过氧化氢

用化学发光流动注射分析装置,将16孔阀连接成异步双流路,以过氧化氢-鲁米诺-钴(Ⅱ)为化学发光体系,建立了快速测定雨水中过氧化氢的方法,最低检测限为0.1ng/ml,在0.1—400ppb范围内有良好的线性关系,相对标准差为0.78—3.03％,每小时可分析480个以上的样品.     

Status of air pollution in Beijing

A study has been made on elements organic constituents, TSP, SO2,NO2 of atmospheric pollutants in Beijing. 17 elements, and some PAHs, e. g. B(a)P, B(b, j, k)P, and B(g, h, i)P, in airborne particles by X-ray fluorescence spectroscopy and HPLC, GC/MS, have been determined respectively. It has been shown that the elements Pb, Zn, S and Cu were more enriched in fine particles and different valence states of sulfur at various sites. It was found that the concentrations of S6+ and S2-were more than 85% and less than 15% of the total sulfur respectively. Concentrations of major PAHs and sulfur-containing compounds increased in winter and in urban area. High values for Pb and Zn in city, Fe and Mn at industrial area and Cu, Al rural sites were obtained respectively. This implies the functions of different elemental sources of various sites. Thus, elements can be from distingushed anthropogenic and natural sources.The main contribution of SO2 was found of to have same seasonal variation as the anthropogenic el     

重庆南山马尾松林衰亡与大气污染关系的讨论

重庆市南郊的南山是一个风景区,有林地约二万七千余亩,主要是马尾松林(Pinusmassoniana Lamb.),自八十年代起明显出现衰亡现象,目前约有85％马尾松植株受到不同程度的伤害,死亡率达35％左右.马尾松出现的症状是针尖坏死,针叶提早脱落,针长变短,树冠稀疏,枝条枯死,径向生长变弱等.