Use of mass spectrometry for determining microbial toxins in indoor environments

We know little about the health consequences of human exposure to microorganisms in the environment. This may largely be due to the lack of universally accepted, sensitive, reproducible, non-discriminatory, and health relevant methods for characterizing the exposure. In this review, some of the different mass spectrometry methods that have been developed for measuring endotoxin and peptidoglycan from bacteria and mycotoxins from moulds in samples from-mainly damp-indoor environments are discussed.     

Recent advances in mercury speciation analysis with focus on spectrometric methods and enriched stable isotope applications

This paper discusses some recent advances in spectrometric methods and approaches for mercury speciation analysis of environmental samples with focus on isotope dilution techniques for determination of mercury species' concentrations in gaseous samples and reaction rates in soils and sediments. Such analytical data is important inter alia in fundamental research on mercury biogeochemistry and for risk assessments of mercury-contaminated soils and sediments and for designing effective remedial actions. The paper describes how the use of enriched stable isotope tracers in mercury speciation analysis can improve the traceability and accuracy of results, facilitate rational method developments, and be useful for studying biogeochemical processes, i.e. rate of reactions and fluxes, of mercury species. In particular the possibilities to study and correct for unwanted species transformation reactions during sample treatment and to study "natural" transformations of species in environmental samples, or micro- and mesocosm ecosystems, during incubations are highlighted. Important considerations to generate relevant data in isotope tracer experiments as well as reliability and quality assurance of mercury speciation analysis in general are also discussed.     

Dielectric properties of MSWI bottom ash for non-invasive monitoring of moisture

The dielectric procperties of MSWI bottom ash as a function of volumetric water content (VWC) are reported in this paper. The objective was to aid the development of microwave based non-invasive emission monitoring and control system for various bottom ash applications. The dielectric measurements were made, on a 1.5-year-old bottom ash, with an electrical network analyzer in microwave range (300 MHz–1.5 GHz). The VWC of the samples ranged between 0.05 and 0.40 m³?m^?3. The relationship between the dielectric permittivity and the VWC was modeled with an empirical model and a physically based Birchak model (BM). The results showed that a linear relationship existed between the permittivity and the VWC at higher water contents (>0.25 m³?m^?3). However, at lower water contents (<0.25 m³?m^?3), the relationship between the permittivity and the WVC was affected by the composition of the bottom ash. The permittivity measurement, with the current method, was not affected by high salt concentrations (10 and 20 dS/m). The empirical model, as compared to BM, provided the best fit between the actual and the predicted water content. The root mean square error (RMSE) values were 0.008–0.010 and 0.06–0.09 m³?m^?3 for the empirical and the Birchak model, respectively.     

An economic-environmental analysis of selected barrier-coating materials used in packaging food products: a Swedish case study

The purpose of a barrier coating in food packaging is primarily to increase the shelf life of the foodstuff contained within the packaging, preserve its colour, odour, taste and quality, and thereby reduce food wastage (both at retail outlets and households). While most publications hitherto have compared packaging and barrier-coating materials on the basis of their environmental impacts alone, this paper adopts a more holistic approach by factoring in the economic aspect as well. Four barrier material alternatives—starch, polyethylene, EVOH + kaolin and latex + kaolin are analysed. Two well-defined end-of-life handling scenarios, relevant to Sweden, are: one in which everything except starch is recycled, with starch being composted, and the other in which everything is incinerated. Among the several environmental impact categories which can be analysed, this paper considers only global warming. Two approaches are tested to combine the economic and environmental aspects—normalisation, weighting and aggregating on the one hand, and using the carbon tax to internalise the externality caused by GHG emissions on the other. For the set of weighting factors obtained thanks to a survey conducted by the authors (40.6% for environmental and 59.4% for economic), starch emerges as the most sustainable alternative, followed by polyethylene for both the end-of-life handling scenarios. This tallies with the result obtained by using the carbon tax for internalisation of the externality. The case study, methodology and results presented in this paper, will hopefully be a springboard for more detailed studies of this nature, under the umbrella of sustainability.     

Transforming systems of consumption and production for achieving the sustainable development goals: moving beyond efficiency

The United Nations formulated the sustainable development goals (SDGs) in 2015 as a comprehensive global policy framework for addressing the most pressing social and environmental challenges currently facing humanity. In this paper, we analyse SDG 12, which aims to “ensure sustainable consumption and production patterns.” Despite long-standing political recognition of this objective, and ample scientific evidence both on its importance and on the efficacy of various ways of promoting it, the SDGs do not provide clear goals or effective guidance on how to accomplish this urgently needed transformation. Drawing from the growing body of research on sustainable consumption and production (SCP), the paper identifies two dominant vantage points—one focused on promoting more efficient production methods and products (mainly through technological improvement and informed consumer choice) and the other stressing the need to consider also overall volumes of consumption, distributional issues, and related social and institutional changes. We label these two approaches efficiency and systemic. Research shows that while the efficiency approach contains essential elements of a transition to sustainability, it is by itself highly unlikely to bring about sustainable outcomes. Concomitantly, research also finds that volumes of consumption and production are closely associated with environmental impacts, indicating a need to curtail these volumes in ways that safeguard social sustainability, which is unlikely to be possible without a restructuring of existing socioeconomic arrangements. Analysing how these two perspectives are reflected in the SDGs framework, we find that in its current conception, it mainly relies on the efficiency approach. On the basis of this assessment, we conclude that the SDGs represent a partial and inadequate conceptualisation of SCP which will hamper implementation. Based on this determination, this paper provides some suggestions on how governments and other actors involved in SDGs operationalisation could more effectively pursue SCP from a systemic standpoint and use the transformation of systems of consumption and production as a lever for achieving multiple sustainability objectives.     

Larval outbreaks in West Greenland: Instant and subsequent effects on tundra ecosystem productivity and CO<Subscript>2</Subscript> exchange

Insect outbreaks can have important consequences for tundra ecosystems. In this study, we synthesise available information on outbreaks of larvae of the noctuid moth Eurois occulta in Greenland. Based on an extensive dataset from a monitoring programme in Kobbefjord, West Greenland, we demonstrate effects of a larval outbreak in 2011 on vegetation productivity and CO₂ exchange. We estimate a decreased carbon (C) sink strength in the order of 118–143 g C m^?2, corresponding to 1210–1470 tonnes C at the Kobbefjord catchment scale. The decreased C sink was, however, counteracted the following years by increased primary production, probably facilitated by the larval outbreak increasing nutrient turnover rates. Furthermore, we demonstrate for the first time in tundra ecosystems, the potential for using remote sensing to detect and map insect outbreak events.     

Towards quantifying the glacial runoff signal in the freshwater input to Tyrolerfjord–Young Sound,NE Greenland

Terrestrial freshwater runoff strongly influences physical and biogeochemical processes at the fjord scale and can have global impacts when considered at the Greenland scale. We investigate the performance of the HIRHAM5 regional climate model over the catchments delivering freshwater to Tyrolerfjord and Young Sound by comparing to the unique Greenland Ecological Monitoring database of in situ observations from this region. Based on these findings, we estimate and discuss the fraction of runoff originating from glacierized and non-glacierized land delivered at the daily scale between 1996 and 2008. We find that glaciers contributed on average 50–80% of annual terrestrial runoff when considering different sections of Tyrolerfjord–Young Sound, but snowpack depletion on land and consequently runoff happens about one month earlier in the model than observed in the field. The temporal shift in the model is a likely explanation why summer surface salinity in the inner fjord did not correlate to modelled runoff.     

Nitrogen fixation by cyanobacteria stimulates production in Baltic food webs

Filamentous, nitrogen-fixing cyanobacteria form extensive summer blooms in the Baltic Sea. Their ability to fix dissolved N₂ allows cyanobacteria to circumvent the general summer nitrogen limitation, while also generating a supply of novel bioavailable nitrogen for the food web. However, the fate of the nitrogen fixed by cyanobacteria remains unresolved, as does its importance for secondary production in the Baltic Sea. Here, we synthesize recent experimental and field studies providing strong empirical evidence that cyanobacterial nitrogen is efficiently assimilated and transferred in Baltic food webs via two major pathways: directly by grazing on fresh or decaying cyanobacteria and indirectly through the uptake by other phytoplankton and microbes of bioavailable nitrogen exuded from cyanobacterial cells. This information is an essential step toward guiding nutrient management to minimize noxious blooms without overly reducing secondary production, and ultimately most probably fish production in the Baltic Sea.     

Baltic Sea ecosystem-based management under climate change: Synthesis and future challenges

Ecosystem-based management (EBM) has emerged as the generally agreed strategy for managing ecosystems, with humans as integral parts of the managed system. Human activities have substantial effects on marine ecosystems, through overfishing, eutrophication, toxic pollution, habitat destruction, and climate change. It is important to advance the scientific knowledge of the cumulative, integrative, and interacting effects of these diverse activities, to support effective implementation of EBM. Based on contributions to this special issue of AMBIO, we synthesize the scientific findings into four components: pollution and legal frameworks, ecosystem processes, scale-dependent effects, and innovative tools and methods. We conclude with challenges for the future, and identify the next steps needed for successful implementation of EBM in general and specifically for the Baltic Sea.     

Interannual variability of phyto-bacterioplankton biomass and production in coastal and offshore waters of the Baltic Sea

The microbial part of the pelagic food web is seldom characterized in models despite its major contribution to biogeochemical cycles. In the Baltic Sea, spatial and temporal high frequency sampling over three years revealed changes in heterotrophic bacteria and phytoplankton coupling (biomass and production) related to hydrographic properties of the ecosystem. Phyto- and bacterioplankton were bottom-up driven in both coastal and offshore areas. Cold winter temperature was essential for phytoplankton to conform to the successional sequence in temperate waters. In terms of annual carbon production, the loss of the spring bloom (diatoms and dinoflagellates) after mild winters tended not to be compensated for by other taxa, not even summer cyanobacteria. These results improve our ability to project Baltic Sea ecosystem response to short- and long-term environmental changes.