A novel method for reducing acid mine drainage using green liquor dregs

When exposed to the weather, sulfidic minerals release sulfuric acid, metals and metalloids. This leachate can devastate nearby ecosystems for centuries. This article reports a novel barrier system based on green liquor dregs that reduces acid generation, is inexpensive, and is practical for implementation at operational mines. Two waste rock piles were constructed. One pile was left open to the atmosphere, and the other was sealed with green liquor dregs and partially capped with a polyethylene liner. This test was designed in collaboration with personnel from Boliden Mineral AB, a Swedish mining company in order to ensure that the results would be practical to implement at an operational mine. Leachate flow and chemistry were monitored in both piles over a period of 12 months. Effluent volume was 40 % lower in the test pile, while thirteen of the twenty elements assessed showed average concentrations that were 50 % lower in the test pile than in the control pile. For the most environmentally toxic elements As, Cd, Pb and Hg, reductions were even more significant, ranging between 67 and 87 %. These positive results are hypothesized to be primarily due to the chemical and physical characteristics of the green liquor dregs. The novelty of this result is that it is the first barrier system that fulfills the multiple needs of the Swedish mining industry: It is effective in reducing acid mine drainage while remaining both economical and practical. No other barrier system meets these requirements.     

Organophosphate and phthalate esters in indoor air: a comparison between multi-storey buildings with high and low prevalence of sick building symptoms

An extensive study has been conducted on the prevalence of organophosphorous flame retardants/plasticizers and phthalate ester plasticizers in indoor air. The targeted substances were measured in 45 multi-storey apartment buildings in Stockholm, Sweden. The apartment buildings were classified as high or low risk with regard to the reporting of sick building symptoms (SBS) within the project Healthy Sustainable Houses in Stockholm (3H). Air samples were taken from two to four apartments per building (in total 169 apartments) to facilitate comparison within and between buildings. Association with building characteristics has been examined as well as association with specific sources by combining chemical analysis and exploratory uni- and multivariate data analysis. The study contributes to the overall perspective of levels of organophosphate and phthalate ester in indoor air enabling comparison with other studies. The results indicated little or no difference in the concentrations of the target substances between the two risk classifications of the buildings. The differences between the apartments sampled within (intra) buildings were greater than the differences between (inter) buildings. The concentrations measured in air ranged up to 1200 ng m(-3) for organophosphate esters and up to 11?000 ng m(-3) for phthalate esters. Results in terms of sources were discerned e.g. PVC flooring is a major source of benzylbutyl phthalate in indoor air.     

Large variation in breast milk levels of organohalogenated compounds is dependent on mother's age, changes in body composition and exposures early in life

We identified factors that are important determinants of body burdens (breast milk levels) of polychlorinated biphenyls (PCBs), dioxins (polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs)) and polybrominated diphenyl ethers (PBDEs). PCBs, PCDD/Fs and PBDEs were analysed in breast milk from up to 325 first-time mothers in Uppsala, Sweden, who delivered between 1996 and 2006. Hierarchical clustering was used as a method for identification of groups of compounds with common sources of exposure and similar toxicokinetics. Based on correlations between levels of single compounds/congeners in breast milk, distinctly separated clusters were formed, strongly dependent on structural similarities of the organohalogen molecules. In a multiple regression model, levels of PCBs (except PCB 28), PCDD/Fs and BDE-153 were positively associated with age of the mother and weight loss after delivery and inversely associated with pre-pregnancy BMI (body mass index) and weight gain during pregnancy. Higher levels of mono-ortho PCB TEQ, non-ortho PCB TEQ and BDE-153 in milk were found among women with high physical activity. Women who were breastfed during infancy and grew up on the Baltic coast of Sweden, with high availability of contaminated fish from the Baltic sea, had higher levels of PCBs and PCDD/Fs in breast milk indicating that exposure early in life from breast milk and contaminated fish may still affect body burdens at the time of pregnancy. The importance of current consumption of fatty Baltic fish as a source of exposure was supported by the positive association with breast milk levels of mono-ortho PCB TEQ, PCDF TEQ and BDE-153. The results show that, in contrast to the lower brominated PBDE congeners, the hexa-brominated BDE-153 resembles the chlorinated compounds with regards to determinants in breast milk. This suggests that some of the PBDEs may have toxicokinetic properties and that are similar to the PCBs and PCDD/Fs. Our results show that a few simple advices to women regarding weight changes in connection with pregnancy and consumption of contaminated fatty fish during the whole lifetime may lower the levels of dioxins in breast milk by up to 60%.     

景观空间格局的定量化

根据栅格化数字图的数据,本文讨论景观信息理论指数:根据Shannon熵进行各种度量,如:度量多样性和聚集度;以及根据条件熵进行度量,如:一种新的指数,可以替代聚集度的度量,从而避免与多样性高度相关的缺点.另外,在这里还介绍一种测量方法,即在大尺度图中含多少小尺度图的信息.     

Chondrodysplasia punctata (CDP) with features of the tibia-metacarpal type and maternal phenytoin treatment during pregnancy

We describe a 2-year-old boy with chondrodysplasia punctata (CDP). The boy was exposed to phenytoin, in combination with carbamazepine, during pregnancy. There has been previous evidence for a connection between phenytoin exposure during pregnancy and chondrodysplasia punctata. The boy had clinical and some radiological characteristic features of CDP, of the tibia-metacarpal type. We know of no other report on a child exposed to phenytoin during pregnancy who developed CDP of this type. Copyright © 2002 John Wiley & Sons, Ltd.     

Comparison of Skimmed Milk and Lanthanum Flocculation for Concentration of Pathogenic Viruses in Water

Food and Environmental Virology - Concentration of viruses in water is necessary for detection and quantification of the viruses present, in order to evaluate microbiological barriers in water...