Sequentielle Schwermetallextraktion aus Staubniederschlägen und Stra\ensedimenten

For the application of our method for the sequential extraction of heavy metals from microsamples presented in part 1 (“Sequentielle Schwermetallextraktion von Mikroproben” — “Sequential Extraction of Heavy Metals from Micro Samples”) an investigation was carried out to evaluate airborne dust fallout and street sediments at two urban sites where different heavy metal immission rates occur due to traffic influence. In the street sediments the total concentrations of zinc, copper and lead was three to fivefold higher in the silt and clay fraction (< 63 μm) than in the particle size fraction (< 1,12 mm), but showed nearly the same mobilisation behaviour. The dust samples showed equal mobilisation behaviour as the street sediments for copper and lead, while zinc was considerably more mobile in the dust samples: In extraction steps I–IV (I: mobile fraction; II: easily deliverable fraction; III: fraction bound to manganese oxides; IV: fraction bound organic to matter) zinc, copper and lead in street sediments, as well as copper and lead in dust samples, were dissolved to 40–70%, whereas about 80% of zinc in the dust samples was already dissolved in extraction step I.     

Objectively best or most acceptable? Expert and lay knowledge in Swedish wind power permit processes

This article analyses legal aspects of the Swedish wind power development, theoretically based on how different types of knowledge are represented in legal contexts, mainly in the courts. A sample of appealed wind power permits is analysed, a handful of relevant informants are interviewed – including two judges in the Land and Environment Court and the appeal court – and the legal setting is analysed. Of key interest here is the interplay between expert and lay statements in the court cases, which here is related to the concepts of calculating and communicative rationalities that are developed in the planning literature. The results indicate that the juridification – which takes place as a permit issue is appealed in the judiciary system – supports the calculating rationality more than the communicative, and that the plaintiffs often attempt to adapt in how they shape their argumentation.     

Hotspots and key periods of Greenland climate change during the past six decades

We investigated air temperature and pressure gradients and their trends for the period 1996–2014 in Greenland and compared these to other periods since 1958. Both latitudinal temperature and pressure gradients were strongest during winter. An overall temperature increase up to 0.15 °C year^?1 was observed for 1996–2014. The strongest warming happened during February at the West coast (up to 0.6 °C year^?1), weaker but consistent and significant warming occurred during summer months (up to 0.3 °C year^?1) both in West and East Greenland. Pressure trends on a monthly basis were mainly negative, but largely statistically non-significant. Compared with other time windows in the past six decades, the period 1996–2014 yielded an above-average warming trend. Northeast Greenland and the area around Zackenberg follow the general pattern but are on the lower boundary of observed significant trends in Greenland. We conclude that temperature-driven ecosystem changes as observed in Zackenberg may well be exceeded in other areas of Greenland.     

Vegetation phenology gradients along the west and east coasts of Greenland from 2001 to 2015

The objective of this paper is to characterize the spatiotemporal variations of vegetation phenology along latitudinal and altitudinal gradients in Greenland, and to examine local and regional climatic drivers. Time-series from the Moderate Resolution Imaging Spectroradiometer (MODIS) were analyzed to obtain various phenological metrics for the period 2001–2015. MODIS-derived land surface temperatures were corrected for the sampling biases caused by cloud cover. Results indicate significant differences between West and East Greenland, in terms of both observed phenology during the study period, as well as the climatic response. The date of the start of season (SOS) was significantly earlier (24 days), length of season longer (25 days), and time-integrated NDVI higher in West Greenland. The sea ice concentration during May was found to have a significant effect on the date of the SOS only in West Greenland, with the strongest linkage detected in mid-western parts of Greenland.     

Citizens’ perception of the resilience of Australian cities

How well does the general public understand the concept of urban resilience? We address this question via an online survey of 500+ citizens living in three large Australian cities (Sydney, Melbourne and Perth). The majority of respondents claim not to know what urban resilience means. Of the remaining respondents, understanding ranges from poor to sophisticated. To circumvent this stated lack of understanding, we cast the concept of urban resilience into a more familiar framework consisting of risk and ability to cope with threats. This allows us to assess perceptions about what may challenge the resilience of Australian cities. Two concerns clearly emerge: (1) violence and social unrest and (2) environmental threats. Analysing a number of constructs from the social psychology literature reveals that these two concerns hold different cognitive signatures, whose understanding may facilitate discussion and communication within a public engagement process.     

Fractionated phytoplankton primary production,exudate release and bacterial production in a Baltic eutrophication gradient

The distribution of phytoplankton primary production into four size fractions (>10 m, 10-3 m, 3-0.2 m and <0.2 m), the utilization of algal exudates by bacteria and the bacterial production were studied in a eutrophication gradient in the northern Baltic proper. The polluted area exhibits substantially increased nutrient, especially nitrogen, levels while only minor differences occur in salinity and temperature regimes. Total primary production was 160 g C · m^-2 · yr^-1 at the control station and about 275 g C · m^-2 · yr^-1 at the eutrophicated stations. The estimated total exudate release was 16% of the totally fixed ¹⁴CO₂ in the control area and 12% in the eutrophicated area (including the estimated bacterial uptake of exudates). The difference in¹⁴CO₂ uptake rates between incubation of previously filtered water (<3, <2, <1 m) and unfiltered water was used to estimate bacterial uptake of phytoplankton exudates which were found to contribute about half of the estimated bacterial carbon requirement in both areas. Bacterial production was estimated by the frequency of dividing cells (FDC) method as being 38 g C · m^-2 · yr^-1 at the control station and 50 g C · m^-2 · yr^-1 at the eutrophicated stations. To estimate the mean in situ bacterial cell volume a correlation between FDC and cell volume was used. The increased annual primary production in the eutrophicated area was due mainly to higher production during spring and autumn, largely by phytoplankton cells (mainly diatoms) retained by a 10 m filter. Primary production duringsummer was similarin the two areas, as was the distribution on different size fractions. This could possibly explain the similar bacterial production in the trophic layers at all stations since the bulk of bacterial production occurs during summer. It was demonstrated that selective filtration does not quantitatively separate photoautotrophs and bacteria. A substantial fraction of the primary production occurs in the size fraction <3 m. The primary production encountered in the 3-0.2 m fraction was due to abundant picoplankton (0.5 to 8 · 10⁷ ind · l^-1), easily passing a 3 m filter. The picoplankton was estimated to constitute up to 25% of the total phytoplankton biomass in the control area and up to 10% in the eutrophicated area.     

Plasma PBDE and thyroxine levels in rats exposed to Bromkal or BDE-47

In experimental models, polybrominated diphenyl ethers (PBDEs), a group of brominated flame retardants, have caused effects in a number of biological end-points, including neurobehavioural effects, disturbances in thyroid and steroid hormone homeostasis, and other steroid-related effects. Almost exclusively, only external dose metrics (dose per body weight basis) have been studied in connection to the observed effects. In this study we report on new analyses of plasma PBDE levels in surplus samples from earlier studies on thyroid hormones (TH) in exposed rodents. Female, 7-week old Sprague-Dawley rats were given either Bromkal 70-5 DE (Study I; 18 or 36 mg/kg bw/day) or BDE-47 (Study II; 1, 6 or 18 mg/kg bw/day) daily by gavage for two weeks. At an external dose of 18 mg/kg bw/day significant TH effects (decreased plasma free thyroxin levels) were observed in both studies, corresponding to an internal (plasma) dose of 463 microg sumPBDE/g lipid (Study I) or 421 microg BDE-47/g lipid (Study II). If we compare the contribution of different BDE congeners to the total BDE level in rat plasma after Bromkal exposure (Study II), and in the Bromkal mixture itself, the most important congener in the Bromkal mixture were also found in plasma. However, the relative concentration of BDE-99 was lower, and that of BDE-153 was higher, than that of the mixture, indicating selectivity in uptake, metabolism and/or excretion of the individual BDE congeners. Explicitly, the possible in vivo conversion of BDE-99 to BDE-47, and of BDE-154 to BDE-153 could not be excluded. The internal dose in the present rat study could be compared to reported human serum doses of PBDE. Human serum/blood levels have a wide range, from 3 to 6 ng sumPBDE/g lipid in background samples from Europe, about 10 times higher in US sample, and up to 100 times higher (300-600 ng/g lipid) in upper-end levels in collected samples from USA. As a consequence, the margin between effects levels in the rat and exposure levels in man varies widely, with a quotient roughly from 1000 to 100,000. Generally, it could be expected that this margin is lower than if external dose metrics would be used. An even lower margin could be expected as recent studies have shown effects in offspring at lower doses than those giving effects in our studies. Lastly, it should be noted that humans are already exposed to a mixture of chemicals in daily life, a fact that complicates this kind of comparison.     

Designing cost efficient buffer zone programs: An application of the FyrisSKZ tool in a Swedish catchment

Riparian buffer zones are the only measure which has been used extensively in Sweden to reduce phosphorus losses from agricultural land. This paper describes how the FyrisSKZ web tool can be used to evaluate allocation scenarios using data from the Svärta River, an agricultural catchment located in central Sweden. Three scenarios are evaluated: a baseline, a uniform 6-m-wide buffer zone in each sub-catchment, and an allocation of areas of buffer zones to sub-catchments based on the average cost of reduction. The total P reduction increases by 30 % in the second scenario compared to the baseline scenario, and the average reduction per hectare increases by 90 % while total costs of the program fall by 32 %. In the third scenario, the average cost per unit of reduction (€163 kg P^?1) is the lowest of the three scenarios (58 % lower than the baseline) and has the lowest total program costs.     

欧洲地表酸化水体恢复--未来展望

到目前为止,有关欧洲地表酸化水体大范围化学恢复的文献层出不穷,而有关生物恢复的报道并不多见.建立在现今欧洲排放减少计划之上的模型研究表明,化学恢复仍将继续.而影响恢复进程的诸多不确定性因素主要包括:未来生态系统内氮的可能行为和气候变化的影响.下列4个与气候变化相关的因子可能对未来恢复进程产生影响:①海水盐分入侵事件爆发频率和强度增加;②干旱发生频率和强度上升;③有机碳交换周期加快;④硝化作用增强.目前降低水体酸化程度的国际性协作是成功的,但是未来还有大量问题需要解决,也会遇到许多困难.对未来硫、氮排放减少后以及气候变化背景下酸化地表水体的水化学和水生生物变化需要继续监测.