Acid Blue 25 adsorption on base treated Shorea dasyphylla sawdust: Kinetic, isotherm, thermodynamic and spectroscopic analysis

The potential of base treated Shorea dasyphylla (BTSD) sawdust for Acid Blue 25 (AB 25) adsorption was investigated in a batch adsorption process. Various physiochemical parameters such as pH, stirring rate, dosage, concentration, contact time and temperature were studied. The adsorbent was characterized with Fourier transform infrared spectrophotometer, scanning electron microscope and Brunauer, Emmett and Teller analysis. The optimum conditions for AB 25 adsorption were pH 2, stirring rate 500 r/min, adsorbent dosage 0.10 g and contact time 60 min. The pseudo second-order model showed the best conformity to the kinetic data. The equilibrium adsorption of AB 25 was described by Freundlich and Langmuir, with the latter found to agree well with the isotherm model. The maximum monolayer adsorption capacity of BTSD was 24.39 mg/g at 300 K, estimated from the Langmuir model. Thermodynamic parameters such as Gibbs free energy, enthalpy and entropy were determined. It was found that AB 25 adsorption was spontaneous and exothermic.     

Options for sustainable development planning based on “GHGs emissions reduction allocation (GERA)” from a national perspective

Climate change phenomenon can be seen as a simple but daunting problem. The lack of equity in emission reduction burden sharing regime, will cause a need for a greater sacrifice for poor or less developed countries. Thus, the evaluation of different aspects of equity at a national scale and presenting a top–down model of equity for allocation of GHGs emission (such as GERA) in line with sustainable development is the main objective of this study. In this study, the five equity principles proposed in the literature namely (1) population distribution, (2) GHGs emissions, (3) GDP, (4) trend of economic growth and (5) per capita of carbon productivity as appropriate criteria of equity estimation. Due to the different decision makers' preferences, different weights are allocated to indicators and analyzed. Iran has been considered as a case study, and these criteria were applied at national level to propose an allowance allocation scheme. The result of applying GERA for Iran, at provincial level and under the five equity criteria, determines which provinces have to shoulder higher reduction burdens, and makes a room for less developed provinces for growth. Based on these results, this model demonstrated to be more sensitive to criteria selection rather than to the weight factors. In addition, shifting to low carbon technologies or renewables, careful evaluation of current emission–income pattern, improving of energy intensity and finally, adjustment of secondary industries (manufacturing) based on ecological and natural resources of each region are suggested as the most efficient approaches toward sustainability and green development for the case study.     

Environmental and economic evaluation of bioenergy in Ontario, Canada

We examined life cycle environmental and economic implications of two near-term scenarios for converting cellulosic biomass to energy, generating electricity from cofiring biomass in existing coal power plants, and producing ethanol from biomass in stand-alone facilities in Ontario, Canada. The study inventories near-term biomass supply in the province, quantifies environmental metrics associated with the use of agricultural residues for producing electricity and ethanol, determines the incremental costs of switching from fossil fuels to biomass, and compares the cost-effectiveness of greenhouse gas (GHG) and air pollutant emissions abatement achieved through the use of the bioenergy. Implementing a biomass cofiring rate of 10% in existing coal-fired power plants would reduce annual GHG emissions by 2.3 million metric tons (t) of CO2 equivalent (7% of the province's coal power plant emissions). The substitution of gasoline with ethanol/gasoline blends would reduce annual provincial lightduty vehicle fleet emissions between 1.3 and 2.5 million t of CO2 equivalent (3.5-7% of fleet emissions). If biomass sources other than agricultural residues were used, additional emissions reductions could be realized. At current crude oil prices ($70/barrel) and levels of technology development of the bioenergy alternatives, the biomass electricity cofiring scenario analyzed is more cost-effective for mitigating GHG emissions ($22/t of CO2 equivalent for a 10% cofiring rate) than the stand-alone ethanol production scenario ($92/t of CO2 equivalent). The economics of biomass cofiring benefits from existing capital, whereas the cellulosic ethanol scenario does not. Notwithstanding this result, there are several factors that increase the attractiveness of ethanol. These include uncertainty in crude oil prices, potential for marked improvements in cellulosic ethanol technology and economics, the province's commitment to 5% ethanol content in gasoline, the possibility of ethanol production benefiting from existing capital, and there being few alternatives for moderate-to-large-scale GHG emissions reductions in the transportation sector.     

Coupling of solvent-based de-emulsification dispersive liquid–liquid microextraction with high performance liquid chromatography for simultaneous simple and rapid trace monitoring of 2,4-dichlorophenoxyacetic acid and 2-methyl-4-chlorophenoxyacetic acid

A simple, rapid, and efficient sample pretreatment technique, based on solvent-based de-emulsification dispersive liquid–liquid microextraction (SD-DLLME), followed by high performance liquid chromatography (HPLC) has been developed for simultaneous preconcentration and trace detection of 2,4-dichlorophenoxyacetic acid (2,4-D) and 2-methyl-4-chlorophenoxyacetic acid (MCPA) in water and urine samples. Some parameters such as acidity of solution, the amount of salt, type, and volume of extraction solvents, type of disperser/de-emulsifier solvent, and its volume were investigated and optimized. Under optimum extraction conditions, the limits of detections (LODs) of this method for MCPA and 2,4-D were 0.2 and 0.6 μg L^?1 (based on 3S_b/m) in water and 0.4 and 1.6 μg L^?1 in urine, respectively. Furthermore, dynamic linear range of this method for MCPA and 2,4-D was 1–300 and 2–400 μg L^?1, repectively. Finally, the applicability of the proposed method was evaluated by extraction and determination of the herbicides in urine and different water samples.     

Quantification of ultra-trace amounts of copper by using off-line solid phase extraction-flame atomic absorption spectrometric determination through the octadecyl silica-bonded phase membrane (OSPM) C18 disks impregnated with 2,2'-[ethane-1,2-diylbis(thio)]dianiline

This study reports a very selective, easy, and precise method for rapid separation of trace amounts of copper in aqueous samples using octadecyl silica-bonded phase membrane disks modified by 2,2'-[ethane-1,2-diylbis(thio)]dianiline (EDTD) combined with flame atomic absorption spectrometric determination. In addition, the synthesis and spectral characterization of EDTD have been described in detail. All the affecting experimental variables such as pH, amount of modifier, eluent type, sample and eluent flow rate, interfering ions, and disk capacity were also investigated. The target analyte (trace copper) was quantitatively retained at pH?=?4 and eluted with 6.0 mL of 0.5 M HNO₃ at flow rates of 40 and 10 mL min^?1 for analyte passage and elution steps, respectively, through the disks modified with 17.0 mg of EDTD. The proposed method also allows an enrichment factor of about 500 and has a detection limit of 0.005 ng mL^?1. The method has been successfully applied for isolation and determination of copper in different water samples, peppers, and standard alloys.     

VALIDATION OF AN ENZYME LINKED IMMUNOSORBENT ASSAY (ELISA) FOR CYPRINUS CARPIO L. VITELLOGENIN, AS A BIOMARKER OF REPRODUCTIVE DISORDERS

Vitellogenin is a female sex-specific protein, and a validated and suitable method for its assay can be applied as a biomarker of reproductive disorders in male and female aquatic animals. Therefore, the present study was designed to validate an ELISA for measuring plasma vitellogenin in wild carp ( Cyprinus carpio L.) living in the Lake of Trasimeno (Umbria, Italy); plasma samples were taken during pre-spawning, spawning, and post-spawning periods; in addition to vitellogenin, in both male and female carps, plasma changes of estradiol-17 βwere monitored together with those of estrogen receptor density in the liver.

In females, VTG showed high seasonality, reaching the highest levels in March during the pre-spawning period; the VTG levels correlated with those of estradiol-17 β( E 2 ), and with the changes of gonadosomatic index (GSI), while a non parallel trend was found in the liver estrogen receptor (ER) density. In forty percent of males, VTG was found to be present in the plasma and changes of ER density in the liver were observed.

The data here reported suggest that the common carp can be a useful sentinel species for biomonitoring studies of environmental estrogens, and of their effects on its reproductive biology.     

Combined Effects of Physical Demands and Shift Working on Low Back Disorders Among Nursing Personnel

The aim of this study was to investigate the synergistic effects of physical demands and shift working on low back disorders (LBDs) among nursing personnel. The study used 2 questionnaires: a self-administered questionnaire composed of parts of Nordic musculoskeletal questionnaire to assess LBDs and job content questionnaire to assess physical demands. The participants were divided into 4 groups: from group 1 (low physical demands day workers) to group 4 (high physical demands shift workers). In regression analysis, high physical demands were associated with the prevalence of LBDs independently (OR 4.4, 95% CI [2.40, 8.00] and p < .05), but there was no association between shift working and LBDs (p > .05). Odds ratio in high physical demands shift workers was 9.33 compared to the reference group (p < .001). Calculated synergistic index was 7.37. Simultaneous impacts of shift working and high physical demands may increase the prevalence of LBDs among nursing personnel.     

Physical and chemical separation of Ti,rare earth elements,Fe, and Al from red mud by carbothermal reduction,magnetic separation,and leaching

Environmental Science and Pollution Research - In this study, a combination of physical and chemical separation processes was used to recover the metallic components of red mud. At first, the...     

Evaluating the impact of GDP per capita on environmental degradation for G-20 economies: Does N-shaped environmental Kuznets curve exist?

Environment, Development and Sustainability - The extant literature reveals that scholars and policy makers are highly concerned about exploring the validity of the environmental Kuznets curve...