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11.
Gennari M Abbate C Baglieri A Negre M 《Journal of environmental science and health. Part. B》2008,43(6):498-505
The behavior and fate of triasulfuron (TRS) in water and soil systems were examined in laboratory studies. The degradation of TRS in both buffer solution and soil was highly pH-sensitive. The rate of degradation could be described with a pseudo first-order kinetic and was much faster at pH 4 than at pH 7 and 9. Aqueous hydrolysis occurred by cleavage of the sulfonylurea bridge to form 2-(2-chloroethoxy) benzenesulfonamide (CBSA) and [(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] (AMMT). AMMT was unstable in aqueous solutions in any pH condition but it degraded more quickly at pH 4 and 9. CBSA did not degrade in aqueous solutions or in enriched cultures but it underwent a quick degradation in the soil. The rates of TRS degradation in sterile and non-sterile soils were similar, suggesting that microorganisms played a minimal role in the breakdown process. This hypothesis is supported by the results of studies on the degradation of TRS by enriched cultures during which the molecule underwent a prevalently chemical degradation. 相似文献
12.
A solid phase extraction procedure (SPE) is described for the quantitative analysis of polycyclic aromatic hydrocarbons (PAHs) in atmospheric particulate matter (PM), as ubiquitous environmental pollutants routinely measured in air quality monitoring. A SPE cartridge was used based on a molecular imprinted polymer (MIP-SPE) properly tailored for selective retention of PAHs with 4 and more benzene fused rings. The performance of the clean-up procedure was evaluated with the specific concern of selective purification towards saturated hydrocarbons, which are the PM components mostly interfering GC analysis of target PAHs. Under optimized operative conditions, the MIP-SPE provided analyte recovery close to 95% for heavier PAHs, from benzo(α)pyrene to benzo(ghi)perylene, and close to 90% for four benzene rings PAHs, with good reproducibility (RSDs: 2.5%-5.9%). Otherwise, C17-C32 n-alkanes were nearly completely removed. The proposed method was critically compared with Solid Phase Micro Extraction (SPME) using a polyacrylate fiber. Both methods were successfully applied to the analysis of ambient PM2.5 samples collected at an urban polluted site. Between the two procedures, the MIP-SPE provided the highest recovery (R% ≥ 93%) for PAHs with 5 and more benzene rings, but lower for lighter PAHs. In contrast, SPME showed a mean acceptable R% value (∼ 80%) for all the investigated PAHs, except for the heaviest PAHs in the most polluted samples (R%: 110%-138%), suggesting an incomplete purification from the interfering n-hydrocarbons. 相似文献
13.
The effluent from a facultative pond loaded at 80 kg BOD ha(-1) day(-1) was treated in a subsurface horizontal-flow aerated rock filter (RF) and a subsurface horizontal-flow constructed wetland (CW) planted with Typha latifolia. Over a 12-month monitoring period BOD and TSS removals were higher, and effluent ammonia concentrations lower, in the RF than in the CW (> 75% vs. 25-75%, and 3.6 mg N L(-1) vs. 6 mg N L(-1), respectively). However, the ammonia concentration was lower in the CW effluent than in the aerated RF effluent during mid-July to mid-September (1.1 mg N L(-1) vs. 2.2 mg N L(-1)), but in winter it was higher than the influent concentration. Overall the performance of the aerated RF was better and more consistent than that of the CW. 相似文献
14.
Finocchiaro R Meli S Gennari M 《Journal of environmental science and health. Part. B》2004,39(3):381-392
This research was carried out with the aim of obtaining information regarding the possible environmental impact of Chlorpyrifos-methyl, an organophosphoric insecticide used in agriculture for its phytoiatric action against Hemiptera, Lepidoptera, Coleoptera, and Diptera. Studies relating to the degradation kinetics of the insecticide in two soils and one sediment have shown a rapid degradation process in all three. The prevalent form of degradation would appear to be the chemical type, because the degradation kinetics in a sterile soil have not demonstrated that micro-organisms play a significant part. The adsorption isotherms showed that the insecticide has a greater affinity for the sediment (Kf=143) as opposed to the soils (Kf=65) and that the adsorption process is practically irreversible. Moreover, hydrolysis tests in buffered solutions at pH 4, 7, and 9 revealed that the molecule is particularly unstable with a basic pH. 相似文献
15.
Kouloukoui Daniel Marinho Marcia Mara de Oliveira Gomes Sônia Maria da Silva de Jong Pieter Kiperstok Asher Torres Ednildo Andrade 《Mitigation and Adaptation Strategies for Global Change》2020,25(1):127-147
Mitigation and Adaptation Strategies for Global Change - The corporate sector is one of the main emitters in the world due to the production process and therefore is identified as a major... 相似文献
16.
Mara Gennari Cristina Abbate Andrea Baglieri Michèle Nègre 《Journal of environmental science and health. Part. B》2013,48(6):498-505
The behavior and fate of triasulfuron (TRS) in water and soil systems were examined in laboratory studies. The degradation of TRS in both buffer solution and soil was highly pH-sensitive. The rate of degradation could be described with a pseudo first-order kinetic and was much faster at pH 4 than at pH 7 and 9. Aqueous hydrolysis occurred by cleavage of the sulfonylurea bridge to form 2-(2-chloroethoxy) benzenesulfonamide (CBSA) and [(4-methoxy-6-methyl-1,3,5-triazin-2-yl)amino] (AMMT). AMMT was unstable in aqueous solutions in any pH condition but it degraded more quickly at pH 4 and 9. CBSA did not degrade in aqueous solutions or in enriched cultures but it underwent a quick degradation in the soil. The rates of TRS degradation in sterile and non-sterile soils were similar, suggesting that microorganisms played a minimal role in the breakdown process. This hypothesis is supported by the results of studies on the degradation of TRS by enriched cultures during which the molecule underwent a prevalently chemical degradation. 相似文献
17.
The ecological burden of economic growth is a highly discussed issue. In this article, we focus on the set of European Union (EU) 15 countries in the period 1995–2014. We first decomposed emissions into six effects and afterward the decoupling-effort index was used to calculate the magnitude of impact that each factor has on it, considering the country group. For the group of the EU-15 in the pre-Kyoto period, CO2 changes are only negative in 1998 and 1999 considering the initial view (with respect to the base year of 1995), being positive for all the other years. This positive effect means increased emissions, for which many contributed the positive and significant effects of income per capita and the population effects. The most significant reductions in CO2 changes are verified in the years after the effective Kyoto commitment and observed mainly in the alternative view (year to year changes), for which many contributed the negative and significant effects of carbon intensity of petroleum products, energy intensity and conversion efficiency in the overall period. The effects elasticity decoupling and decoupling effort do not seem to be controlled by the internal drivers of CO2 emissions. Policy makers should bet in policy instruments pointed in the sense of strengthening energy efficiency, in reducing petroleum products consumption and therefore dependency and on the structure of added value generated by the economy. 相似文献
18.
Victor Moutinho Mara Madaleno Joo Paulo Bento 《Environmental and Ecological Statistics》2020,27(2):363-413
Few studies have attempted to study the environmental Kuznets curve (EKC) hypothesis at the individual sector level using more than one sector at once. This paper investigates the existence of the EKC hypothesis in the Iberian countries (Portugal and Spain) using thirteen economic activity sectors for each, analyzing each individual sector’s cointegration and causality relationships considering carbon dioxide (CO2) emissions, sector gross value added and energy consumption. The findings of this paper using the autoregressive distributed lag (ARDL) approach only validate cointegration in six Portuguese sectors and in five of the Spanish sectors. Results confirm both short- and long-run bi-directional and unidirectional causality between economic growth, energy consumption and CO2 emissions, using the error correction model (ECM) and Toda and Yamamoto’s causality approaches. Moreover, results for Portuguese and Spanish sectors indicate an inverted U-shaped relationship only for one sector each. In some sectors there was evidence of a U-shaped relationship and in others the EKC hypothesis could be verified but no statistical significance was obtained. The study has significant contributions for sector policy, including implications to curtail energy pollutants by implementing environmental friendly regulations to sustain economic development at the sector level in the Iberian market. It also allows inferences to be made about the existence of different behaviors in comparative terms for the same economic activity sectors of the individual countries. 相似文献
19.
Marcelo Fabiano Costella Tarcisio Abreu Saurin Lia Buarque de Macedo Guimarães 《Safety Science》2009,47(8):1056-1067
This article introduces a method for assessing health and safety management systems (MAHS) that has two innovative characteristics: (a) it brings together the three main auditing approaches to health and safety (HS) – the structural approach (which assesses the system prescribed), the operational approach (which assesses what is really happening on the shop-floor) and the performance approach (which assesses the results of performance indicators); (b) it emphasizes the resilience engineering perspective on HS, which takes into consideration four major principles (flexibility, learning, awareness, and top management commitment). Such principles underlie seven major assessment criteria, which in turn are divided into items (e.g. hazard identification from a resilience perspective is an item that belongs to the criteria of production processes). The items are sub-divided into statements, which are the requirements that should be assessed based on interviews, analysis of documents and direct observations. Within the 112 requirements proposed, 38 of them have clear links with at least one out of the four resilience engineering principles adopted. The remaining requirements are based on traditional assumptions underlying the so-called best practices of HS management. The results of the assessment for each item are expressed by a score on a scale of compliance with the established requirements, ranging from 0% to 100%. The specific score within that scale is obtained from tables used to assess applications for the Brazilian national quality award. The MAHS was tested in a case study that was carried out in a factory that manufactures automobile exhaust systems, located in Brazil. 相似文献
20.
Luke P. Shoo Julian O’Mara Karin Perhans Jonathan R. Rhodes Rebecca K. Runting Susanne Schmidt Lochran W. Traill Lui C. Weber Kerrie A. Wilson Catherine E. Lovelock 《Regional Environmental Change》2014,14(2):435-447
While many scientific assessments have been recommending general strategies for biodiversity conservation under climate change, translation of these recommendations into specific actions and practice has been limited. Focusing on two biomes, rainforest and wetlands in biodiverse South East Queensland, Australia, we demonstrate how general principles can be translated into specific actions for stakeholders and responsible agencies. We synthesize research that is contextualizing protection of refugia and habitat connectivity, establishing baseline data sets to detect change and developing strategic conservation planning scenarios to adjust reserve boundaries or situate new reserves. This has been achieved by coupling spatial information on biological assets (i.e. ecosystems and species) with future climate scenarios and process models to anticipate movement of critical habitats. Conservation planning software is also being used to prioritize investment to meet specific objectives. This approach is enabling us to identify at-risk biological assets, opportunities to ameliorate threats and obstacles to delivering regional adaptation actions. A larger total reserved area is needed, with proactive planning to capture areas further inland and along watercourses. Major obstacles include conflict between urbanization and priorities for habitat conservation and the need for greater levels of investment for monitoring programmes and to protect landward shifted wetlands on private land. 相似文献