Source apportionment of PM2.5 for supporting control strategies in the Monterrey Metropolitan Area,Mexico

The Monterrey Metropolitan Area (MMA) in Northeast Mexico has shown high PM_2.5 concentrations since 2003. The data shows that the annual average concentration exceeds from 2 to 3 times the Mexican PM_2.5 annual air quality standard of 12 µg/m³. In a previous work we studied the chemical characterization of PM_2.5 in two sites of the MMA during the winter season. Among the most important components we found ammonium sulfate and nitrate, elemental and organic carbon, and crustal matter. In this work we present the results of a second chemical characterization study performed during the summer time and the application of the chemical mass balance (CMB) model to determine the source apportionment of air pollutants in the region. The chemical analysis results show that the chemical composition of PM_2.5 is similar in both sites and periods of the year. The results of the chemical analysis and the CMB model show that industrial, traffic, and combustion activities in the area are the major sources of primary PM_2.5 and precursor gases of secondary inorganic and organic aerosol (SO₂, NOx, NH₃, and volatile organic compounds [VOCs]). We also found that black carbon and organic carbon are important components of PM_2.5 in the MMA. These results are consistent with the MMA emission inventory that reports as major sources of particles and SO₂ a refinery and fuel combustion, as well as nitrogen oxides and ammonium from transportation and industrial activities in the MMA and ammonium form agricultural activities in the state. The results of this work are important to identify and support effective actions to reduce direct emissions of PM_2.5 and its precursor gases to improve air quality in the MMA. Implications: The Monterrey Metropolitan Area (MMA) has been classified as the most air-polluted area in Mexico by the World Health Organization (WHO). Effective actions need to be taken to control primary sources of PM_2.5 and its precursors, reducing health risks on the population exposed and their associated costs. The results of this study identify the main sources and their estimated contribution to PM_2.5 mass concentration, providing valuable information to the local environmental authorities to take decisions on PM_2.5 control strategies in the MMA.     

Sediment distribution on the continental shelf in relation to stream inputs and contamination: hydrodynamic,chemical, mineralogical,and sedimentological characteristics (Ligurian Sea,Italy)

River estuaries, continental shelf, and sediment contamination are closely linked from the point of view of sediment transport and diffusion that is governed by different factors such as sea waves and currents, river flows and floods, and sediment characteristics. Taking these factors into consideration, we have examined marine environmental and marine bottom sediments off the mouth of a stream to highlight the main ways of sediment and contaminant transport and diffusion on the continental shelf. For this purpose, we followed a multidisciplinary approach, studying circulation of water masses, hydrological characteristics of water column, distribution and main characteristics of sediment grain size, sediment mineralogical composition, and metal concentrations of bottom sediments. Our results allowed identifying the presence of preferential ways of sediment deposition and areas of sediment spread for the Entella Stream, as well as the origin of some metals.

     

Modeling the decline of labor-sharing in the semi-desert region of Chile

Regional Environmental Change - The rapid environmental changes currently underway in many dry regions of the world, and the deep uncertainty about their consequences, underscore a critical...     

From vineyards to feedlots: a fund-flow scanning of sociometabolic transition in the Vallès County (Catalonia) 1860–1956–1999

Regional Environmental Change - We analyse the changes to agricultural metabolism in four municipalities of Vallès County (Catalonia, Iberia) by accounting for their agroecosystem funds and...     

Electrochemical advanced oxidation processes: today and tomorrow. A review

In recent years, new advanced oxidation processes based on the electrochemical technology, the so-called electrochemical advanced oxidation processes (EAOPs), have been developed for the prevention and remediation of environmental pollution, especially focusing on water streams. These methods are based on the electrochemical generation of a very powerful oxidizing agent, such as the hydroxyl radical (^?OH) in solution, which is then able to destroy organics up to their mineralization. EAOPs include heterogeneous processes like anodic oxidation and photoelectrocatalysis methods, in which ^?OH are generated at the anode surface either electrochemically or photochemically, and homogeneous processes like electro-Fenton, photoelectro-Fenton, and sonoelectrolysis, in which ^?OH are produced in the bulk solution. This paper presents a general overview of the application of EAOPs on the removal of aqueous organic pollutants, first reviewing the most recent works and then looking to the future. A global perspective on the fundamentals and experimental setups is offered, and laboratory-scale and pilot-scale experiments are examined and discussed.     

TXRF analysis of soils and sediments to assess environmental contamination

Total reflection x-ray fluorescence spectroscopy (TXRF) is proposed for the elemental chemical analysis of crustal environmental samples, such as sediments and soils. A comparative study of TXRF with respect to flame atomic absorption spectroscopy and inductively coupled plasma optical emission spectroscopy was performed. Microwave acid digestion and suspension preparation methods are evaluated. A good agreement was found among the results obtained with different spectroscopic techniques and sample preparation methods for Cr, Mn, Fe, Ni, Cu, and Zn. We demonstrated that TXRF is suitable for the assessment of environmental contamination phenomena, even if the errors for Pb, As, V, and Ba are ingent.     

Synoptic patterns associated with extreme dust events in the Mediterranean Basin

Extreme dust events over the western, central and eastern Mediterranean are identified analysing the aerosol optical depth remote-sensed by the Moderate Resolution Imaging Spectroradiometer (MODIS) in 2001–2010 and simulated by the Goddard Chemistry Aerosol Radiation and Transport (GOCART) model in 2000–2007. The seasonal variability of the dust events and the evolution of the synoptic circulation patterns before and during the events are studied. Results show that the highest occurrence of short events (1–3 days) is in the eastern Mediterranean, while long events (more than 4 days) are more frequent in the western Mediterranean. Short events are concentrated in spring, while long events do not show a clear seasonality. The synoptic circulation patterns accompanying short and long events are similar, and the occurrence across the Mediterranean Basin is related to westerly low-pressure systems. Dust events in the western Mediterranean are associated with high-pressure conditions limiting the development of lows to the western North Africa, while the eastward evolution of cyclones over the central Mediterranean and Northern Africa accompanies dust events in the central and eastern Mediterranean.     

台风灾害气象指数保险相关技术方法初探

气象指数灾害保险是目前全球范围内广泛研究的一种风险转移工具,它可以克服传统的自然灾害保险的局限性,在农业保险领域应用前景广阔。以福建省连江县为例,依据连江县台风灾害及台风活动特征,将能够对连江县造成一定损失的台风分成分别以大风、大雨和大风雨为主导的3类。结合连江站相关气象数据及概率分布建立了广义的台风灾害气象指数,最后构建了保险赔付路线图,以供有关部门参考。     

Attitudes of rural population in emergency exposure situations

People growing crops in kitchen gardens eat locally self-produced food and are the subject of growing attention as the potential for a more sustainable development. A survey was carried out in two provinces in northern Italy to gather information on the consumption of local horticultural products, peoples’ expectations of authorities in the case of a nuclear accident and peoples’ behaviour in the absence of official information. Results show that up to 70% of the owners of kitchen gardens possess diets comprised of more than 60% of self-produced vegetables and can be regarded as particular groups of population. In the case of a dispersion of radioactive material, the local population would take advantage of official information on preventive measures to protect farms and local crops from contamination. Results of the survey show differences in the attitude of the population due to age, gender and past experience.     

Spatial distribution of soil radon as a tool to recognize active faulting on an active volcano: the example of Mt. Etna (Italy)

This study concerns measurements of radon and thoron emissions from soil carried out in 2004 on the eastern flank of Mt. Etna, in a zone characterized by the presence of numerous seismogenic and aseismic faults. The statistical treatment of the geochemical data allowed recognizing anomaly thresholds for both parameters and producing distribution maps that highlighted a significant spatial correlation between soil gas anomalies and tectonic lineaments. The seismic activity occurring in and around the study area during 2004 was analyzed, producing maps of hypocentral depth and released seismic energy. Both radon and thoron anomalies were located in areas affected by relatively deep (5-10 km depth) seismic activity, while less evident correlation was found between soil gas anomalies and the released seismic energy. This study confirms that mapping the distribution of radon and thoron in soil gas can reveal hidden faults buried by recent soil cover or faults that are not clearly visible at the surface. The correlation between soil gas data and earthquakes depth and intensity can give some hints on the source of gas and/or on fault dynamics.