Geographic information system–assisted site quality assessment for hazelnut cultivation using multi-criteria decision analysis in the Black Sea region,Turkey

Environmental Science and Pollution Research - Developing land suitability models for strategically critical agricultural products to expand sustainable agricultural policies and sensitive...     

Perspectives for pilot scale study of RDF in Istanbul,Turkey

Municipal solid waste (MSW) is one of the most important environmental problems arising from rapid urbanization and industrialization. The use of alternative fuels in rotary kilns of cement plants is very important for reducing cost, saving fossil fuels and also eliminating waste materials, accumulated during production or after using these materials. Cement industries has an important potential for supplying preferable solutions to the waste management. Energy recovery from waste is also important for the reduction of CO₂ emissions.This paper presents an investigation of the development of refuse derived fuel (RDF) materials from non-recycling wastes and the determination of its potential use as an alternative fuel in cement production in Istanbul, Turkey. RDF produced from MSW was analyzed and its effects on cement production process were examined. For this purpose, the produced RDF was mixed with the main fuel (LPG) in ratios of 0%, 5%, 10%, 15% and 20%. Then chemical and mineralogical analyses of the produced clinker were carried out. It is believed that successful results of this study will be a good example for municipalities and cement industries in order to achieve both economic and environmental benefits.     

Valorization of spent coffee grounds recycling as a potential alternative fuel resource in Turkey: An experimental study

In this study, recycling of spent coffee grounds (SCG) as a potential feedstock for alternative fuel production and compounds of added value in Turkey was assessed. The average oil content was found (≈ 13% w/w). All samples (before and after extraction) were tested for scanning electron microscopy (SEM), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), X-ray diffraction (XRD), calorific value, surface analysis and porosity, Fourier transform infrared (FT-IR), and elemental analysis to assess their potential towards fuel properties. Elemental analysis indicated that carbon represents the highest percentages (49.59% and 46.42%, respectively), followed by nitrogen (16.7% and 15.5%), hydrogen (6.74% and 6.04%), and sulfur (0.851% and 0.561%). These results indicate that SCG can be utilized as compost, as it is rich in nitrogen. Properties of the extracted oil were examined, followed by biodiesel production. The quality of biodiesel was compared with American Society for Testing and Materials (ASTM) D6751 standards, and all the properties complied with standard specifications. The fatty acid compositions were analyzed by gas chromatography. It was observed that coffee waste methyl ester (CWME) is mainly composed of palmitic (35.8%) and arachidic (44.6%) acids, which are saturated fatty acids. The low degree of unsaturation provides an excellent oxidation stability (10.4 hr). CWME has also excellent cetane number, higher heating value, and iodine value with poor cold flow properties. The studies also investigated blending of biodiesel with Euro diesel and butanol. Following this, a remarkable improvement in cloud and pour points of biodiesel was obtained. Spent coffee grounds after oil extraction is an ideal material for garden fertilizer, feedstock for ethanol, biogas production, and as fuel pellets. The outcome of such research work produces valuable insights on the recycling importance of SCG in Turkey.

Implications: Coffee is a huge industry, and coffee has been widely used due to its refreshing properties. This industry generates large quantities of waste. Therefore, recycling of spent coffee grounds for producing alternative fuels and compounds of added value is crucial. Elemental analysis indicated that coffee waste can be utilized as compost, as it is rich in nitrogen. Coffee waste after oil extraction is an ideal feedstock for ethanol and biogas production, garden fertilizer, and as fuel pellets. The low degree of unsaturation provides excellent oxidation stability. Its biodiesel has also excellent cetane number, higher heating value, and lower iodine value.     

Detection of fungal development in closed spaces through the determination of specific chemical targets

In addition to the biodegradation problems encountered in buildings, exposure of their occupants to moulds is responsible for numerous diseases: infections (invasive nosocomial aspergillosis), immediate or delayed allergies, food-borne infections and different types of irritation. In this context, the aim of our work has been to determine specific chemical tracers for fungal development on construction materials. More generally, by detecting a specific chemical fingerprint of fungal development, our objective was to propose a microbiological alert system which could control systems and/or procedures for the microbiological treatment of indoor areas.

We therefore characterized the chemical emissions from six types of construction material contaminated artificially by moulds. Chemical fingerprints were established for 19 compounds arising specifically from fungal metabolism: 2-ethylhexanoic acid methyl ester, 1-octen-3-ol, 3-heptanol, 3-methyl-1-butanol, 2-methyl-1-butanol, 1,3-octadiene, 2-(5H)-furanone, 2-heptene, -pinene, 2-methylisoborneol, 4-heptanone, 2-methylfuran, 3-methylfuran, dimethyldisulfide, methoxybenzene, a terpenoid and three sesquiterpenes.

Determining the origin of these compounds and their specific links with a growth substrate or fungal species made it possible to judge the pertinence of choosing these compounds as tracers.

Thus the detecting specific volatile organic compounds emitted as from the second day of fungal growth demonstrated that this approach had the advantage of detecting fungal development both reliably and rapidly before any visible signs of contamination could be detected.     

Medical waste management in Turkey: A case study of Istanbul

The objective of this study was to analyze the present status of medical waste management in the light of the Medical Waste Control Regulation (MWCR) in Istanbul, the largest city in Turkey. About 17% of the hospitals, 20% of bed capacity, and 54% of private hospitals in Turkey are located in Istanbul. The first regulation about medical waste management in Turkey was published in 1993, and as a candidate state, it was changed in 2005 in accordance with EU Environmental Directives. In this work, a survey of 14 questions about the amount, collection, and temporary storage of medical wastes was applied to 192 hospitals in Istanbul through face-to-face interviews. It was found that the estimated quantity of medical waste from the hospitals is about 22tons/day and the average generation rate is 0.63kg/bed-day. Recyclable materials are collected separately at a rate of 83%. Separate collection of different types of wastes is consistently practiced, but 25% of the hospitals still use inappropriate containers for medical waste collection. Almost 77% of the hospitals use appropriate equipment for the medical waste collection personnel. The percentage of the hospitals that have temporary storage depots is 63%. Medical waste management in Istanbul is carried out by applying the MWCR.     

Heterogeneous impact of agricultural support policies: evidence from Turkey

Agricultural support policies, which increase production to excessive levels, have been heavily criticized for their distortional effects on farmers’ decisions. High input consumption, which harms the environment, and the distribution of supports, which causes income inequality among farmers, are also the other factors that economists criticize these support policies. However, in recent years, the use and dependence on production and land have been increasing globally due to fears of food insecurity in several countries. In this article, the impact of a support policy on cotton farmers’ land in Turkey is evaluated using a detailed farm-level micro dataset. We use the dynamic panel model to consider the production dynamics, unobservable individual heterogeneity, and the endogeneity of the support variable. Our results show that considering the support variable as endogenous significantly increased its impact on farmers’ land. A farmer’s past land allocation decisions also affected their current lands holdings. However, the results varied considerably between regions and between different land sizes. Therefore, the findings show the importance of heterogeneity in the impact of support policies. We conclude that due to the heterogeneous impact of support policies, it might not be possible to discuss the effect of support policies using an average estimate applicable for all farmers. Therefore, a different support policy considering regional characteristics or farm size is necessary to obtain the desired policy outcomes.

     

Degradation of diuron by the electro-Fenton process

The degradation of the herbicide diuron has been undertaken by electrochemical advanced oxidation in aqueous solution. This process generates catalytically hydroxyl radicals that are strong oxidizing reagents for the oxidation of organic substances. Hydroxyl radicals degrade diuron in less than 10 min. Kinetic results evidence a pseudo-first-order degradation, with a rate constant of reaction between diuron and hydroxyl radicals of 4.8x10⁹ M^–1 s^–1. Several degradation products were identified by chromatography-mass spectrometry (LC-MS). The mineralization degree of a 1.7x10^–4 M diuron solution reached 93% at 1,000 coulombs.     

Valorization of leather industry waste in polyurethane composites for reduced flammability

Journal of Material Cycles and Waste Management - Industrial wastes are considered a major cause of environmental pollution, and studies on valorizing these wastes and converting them into...