A new policy‐related measure of population dispersal and sparsity using GIS

Policy indicators applied at a national scale can have considerable financial impact for resource allocations to individual counties, especially if there are extreme local factors. This article develops arid explores a new measure of population dispersal and sparsity and discusses the impact of this indicator in a variety of locations, by using GIS techniques.     

The Scottish economy: the development of underdevelopment?

This paper describes the recent economic history of the Scottish economy and uses a synthesised theory of labour market segmentation and the dual economy to identify the origins of the relative decline of Scottish industry and labour over the period, critically evaluating the role of the SDA and of government policy in general. Incorporating the impacts of takeover and merger of indigenous companies, the promotion of the branch plant economy, the selective effects of emigration and training schemes, and the reliance on small and medium sized companies to regenerate the economies of city‐regions, an analysis based on the importance of the centre‐periphery relations of monopoly capitalism for the Scottish economy is undertaken.     

Renewable energy projects

The promotion of renewable energy during the last decade did not result in widescale application of the technology. In many cases, technologies were promoted before they were commercially viable or were inappropriately selected for the particular end-use application. In other cases, a lack of local technical expertise and support infrastructure was absent to sustain the technology once it had been placed in the field. There was also a loss of donor interest and funding for renewables concomitant with the decline in oil prices. This paper attempts to summarize lessons learned from this decade of experience with renewable energy and to offer criteria and suggestions for future activities in transferring renewable energy technology.     

Excimer laser fragmentation-fluorescence spectroscopy as a method for monitoring ammonium nitrate and ammonium sulfate particles

Excimer laser fragmentation-fluorescence spectroscopy (ELFFS) is shown to be an effective detection strategy for ammonium nitrate and ammonium sulfate particles at atmospheric pressure and room temperature. Following photofragmentation of the ammonium salt particle, fluorescence of the NH fragment is observed at 336 nm. The fluorescence signal is shown to depend linearly on particle surface area for laser intensities varying from 1.2 x 10(8) to 6 x 10(8) W/cm2. The 100 shot (1 s) detection limits for ammonium nitrate range from 20 ppb for 0.2 microm particles to 125 ppb for 0.8 microm particles, where these concentrations are expressed as moles of ammonium ion per mole of air. For ammonium sulfate, the 100 shot (1 s) detection limits vary from 60 ppb for 0.2 microm particles to 500 ppb for 1 microm particles. These detection limits are low enough to measure ammonium salt particles that form in the exhaust of combustion processes utilizing ammonia injection as a nitric oxide control strategy.     

Assessment of the effluent quality from a gold mining industry in Ghana

The physical and chemical qualities of the process effluent and the tailings dam wastewater of AngloGold-Ashanti Limited, a gold mining company in Ghana, were studied from June to September, 2010. The process effluent from the gold extraction plant contains high amounts of suspended solids and is therefore highly turbid. Arsenic, copper and cyanide were identified as the major pollutants in the process effluent with average concentrations of 10.0, 3.1 and 21.6 mg?L^?1, respectively. Arsenic, copper, iron and free cyanide (CN^?) concentrations in the process effluent exceeded the Ghana EPA discharge limits; therefore, it is necessary to treat the process effluent before it can be discharged into the environment. Principal component analysis of the data indicated that the process effluent characteristics were influenced by the gold extraction process as well as the nature of the gold-bearing ore processed. No significant correlation was observed between the wastewater characteristics themselves, except for the dissolved oxygen and the biochemical oxygen demand. The process effluent is fed to the Sansu tailings dam, which removes 99.9 % of the total suspended solids and 99.7 % of the turbidity; but copper, arsenic and cyanide concentrations were still high. The effluent produced can be classified as inorganic with a high load of non-biodegradable compounds. It was noted that, though the Sansu tailings dam stores the polluted effluent from the gold extraction plant, there will still be serious environmental problems in the event of failure of the dam.     

Strength Development of Solidified/Stabilized Organic Waste and Optimum Treatment Design

Abstract

Artificially contaminated (spiked) natural soils were solidified/stabilized using various combinations of commonly used additives, such as lime, cement, fly ash, activated carbon, and silica fume. The effectiveness of the solidification/stabilization (S/S) processes was evaluated based on experimental findings from compaction testing, unconfined compressive shear strength, and X-ray diffraction (XRD). Correlations of limited reliability between unconfined compressive strength and penetrometer and torvane measurements were derived. Results from XRD experiments indicated that certain organic contaminants (i.e., naphthalene and pyrene) might impact the S/S processes for a given combination of additives. The type and amount of organic contaminants also affected the pozzolanic reactions. Specifically, the absence or small peak intensity of pozzolanic product XRD patterns for a given combination of additives was a good indication that the type and the amount of organic contaminant present inhibited pozzolanic reactions. This phenomenon was tested and confirmed for actual field-contaminated samples.     

Building a better methane generation model: Validating models with methane recovery rates from 35 Canadian landfills

The German EPER, TNO, Belgium, LandGEM, and Scholl Canyon models for estimating methane production were compared to methane recovery rates for 35 Canadian landfills, assuming that 20% of emissions were not recovered. Two different fractions of degradable organic carbon (DOC_f) were applied in all models. Most models performed better when the DOC_f was 0.5 compared to 0.77. The Belgium, Scholl Canyon, and LandGEM version 2.01 models produced the best results of the existing models with respective mean absolute errors compared to methane generation rates (recovery rates + 20%) of 91%, 71%, and 89% at 0.50 DOC_f and 171%, 115%, and 81% at 0.77 DOC_f. The Scholl Canyon model typically overestimated methane recovery rates and the LandGEM version 2.01 model, which modifies the Scholl Canyon model by dividing waste by 10, consistently underestimated methane recovery rates; this comparison suggested that modifying the divisor for waste in the Scholl Canyon model between one and ten could improve its accuracy. At 0.50 DOC_f and 0.77 DOC_f the modified model had the lowest absolute mean error when divided by 1.5 yielding 63 ± 45% and 2.3 yielding 57 ± 47%, respectively. These modified models reduced error and variability substantially and both have a strong correlation of r = 0.92.     

Cost-Effective Mitigation of Diffuse Pollution: Setting Criteria for River Basin Management at Multiple Locations

A case study of the Yorkshire Derwent (UK) catchment is used to illustrate an integrated approach for assessing the viability of policy options for reducing diffuse nitrate losses to waterbodies. For a range of options, modeling methods for simulating river nitrate levels are combined with techniques for estimating the economic costs to agriculture of modifying those levels. By incorporating spatially explicit data and information on catchment residence times (which may span many decades particularly in areas of groundwater discharge) a method is developed for efficient spatial targeting of measures, for example, to the most at-risk freshwater environments. Combining hydrological and economic findings, the analysis reveals that, in terms of cost-effectiveness, the ranking of options is highly sensitive to both (i) whether or not specific stretches of river within a catchment are regarded as a priority for protection, and (ii) the criterion of nitrate concentration deemed most appropriate as an indicator of the health of the environment. Therefore, given the focus under European legislation upon ecological status of freshwaters, these conclusions highlight the need to improve understanding of mechanistic linkages between the chemical and biological dynamics of aquatic systems.