Anaerobic co-digestion of dairy cow manure and high concentrated food processing waste

Anaerobic co-digestion of dairy manure (DM) and concentrated food processing wastes (FPW) under thermophilic (55 °C) and mesophilic (35 °C) temperatures, and fertilizer value of the effluent were investigated in this study. Two types of influent feedstock were utilized: 100 % DM and a 7:3 mixture (wet weight basis) of DM and FPW. The contents of the FPW, as feedstock were 3:3:3:1 mixture of cheese whey, animal blood, used cooking oil and residue of fried potato. Four continuous digestion experiments were carried out in 10 L digesters. Co-digestion under thermophilic temperature increased methane production per digester volume. However, co-digestion at 35 °C was inhibited. Total Kjeldahl nitrogen (N) recovered after digestion ranged from 73.1 to 91.9 %, while recoveries of ammonium nitrogen (NH₄-N) exceeded 100 %. The high recovery of NH₄-N was attributed to mineralization of influent organic N. The mixture of DM and FPW showed greater recoveries of NH₄-N after digestion compared to DM only, reflecting its greater organic N degradability. The ratios of extractable to total calcium, phosphorus and magnesium were slightly reduced after digestion. These results indicate that co-digestion of DM and FPW under thermophilic temperature enhances methane production and offers additional benefit of organic fertilizer creation.     

Characterization and optimization of an online system for the simultaneous measurement of atmospheric water-soluble constituents in the gas and particle phases

In this work we present the results of extensive characterization and optimization of the Ambient Ion Monitor-Ion Chromatograph (AIM-IC) system, an instrument developed by URG Corp. and Dionex Inc. for simultaneous hourly measurements of the water-soluble chemical composition of atmospheric fine particulate matter (PM(2.5)) and associated precursor gases. The sampling assembly of the AIM-IC consists of an inertial particle size-selection assembly, a parallel-plate wet denuder (PPWD) for the collection of soluble gases, and a particle supersaturation chamber (PSSC) for collection of particles, in series. The analytical assembly of the AIM-IC consists of anion and cation IC units. The system detection limits were determined to be 41 ppt, 5 ppt, and 65 ppt for gas phase NH(3(g)), SO(2(g)), and HNO(3(g)) and 29 ng m(-3), 3 ng m(-3), and 45 ng m(-3) for particle phase NH(4)(+), SO(4)(2-), and NO(3)(-) respectively. From external trace gas calibrations with permeation sources, we determined that the AIM-IC is biased low for NH(3(g)) (11%), SO(2(g)) (19%), and HNO(3(g)) (12%). The collection efficiency of SO(2(g)) was found to strongly depend on the composition of the denuder solution and was found to be the most quantitative with 5 mM H(2)O(2) solution for mixing ratios as high as 107 ppb. Using a cellulose membrane in the PPWD, the system responded to changes in SO(2(g)) and HNO(3(g)) within an hour, however for NH(3(g)), the timescale can be closer to 20 h. With a nylon membrane, the instrument response time for NH(3(g)) was significantly improved, becoming comparable to the responses for SO(2(g)) and HNO(3(g)). Performance of the AIM-IC for collection and analysis of PM(2.5) was evaluated by generating known number concentrations of ammonium sulfate and ammonium nitrate particles (with an aerodynamic diameter of 300 nm) under laboratory conditions and by comparing AIM-IC measurements to measurements from a collocated Aerosol Mass Spectrometer (AMS) during a field-sampling campaign. On average, the AIM-IC and AMS measurements agreed well and captured rapid ambient concentration changes at the same time. In this work we also present a novel inlet configuration and plumbing for the AIM-IC which minimizes sampling inlet losses, reduces peak smearing due to sample carryover, and allows for tower-height sampling from the base of a research tower.     

Reducing fall risk by improving balance control: development, evaluation and knowledge-translation of new approaches

Problem

Falling is a leading cause of serious injury, loss of independence, and nursing-home admission in older adults. Impaired balance control is a major contributing factor.

Methods

Results from our balance-control studies have been applied in the development of new and improved interventions and assessment tools. Initiatives to facilitate knowledge-translation of this work include setting up a new network of balance clinics, a research-user network and a research-user advisory board.

Results

Our findings support the efficacy of the developed balance-training methods, balance-enhancing footwear, neuro-prosthesis, walker design, handrail-cueing system, and handrail-design recommendations in improving specific aspects of balance control.

Impact on Knowledge Users

A new balance-assessment tool has been implemented in the first new balance clinic, a new balance-enhancing insole is available through pharmacies and other commercial outlets, and handrail design recommendations have been incorporated into 10 Canadian and American building codes. Work in progress is expected to have further impact.     

What can be learned from incidents in chemistry labs

Students of chemistry should achieve certain safety competencies. Among other things they should be able to learn from undesirable events that happen during their work. In order to facilitate this we decided to analyze, together with our students, the specific causes of a few undesirable events which have happened in our school laboratories. We applied an approach based on root cause analysis and on the classification of four levels of safety assurance. Our examples showed the effectiveness of this approach, leading us at once not only to the identification of errors committed by students, but to those of teachers as well. This enabled us to compile a set of recommendations for the possible prevention of such incidents. Above all, our analysis strongly reinforced the conviction that this approach – learning from actual incidents – is more than just a cause analysis technique. It is a pattern of behavior, a cultural pattern. A technique may be analyzed and taught, but the most effective way to pass on a behavioral pattern is to set an example. The best way to show students how to learn from their own errors is for teachers to demonstrate how they have learned from their own experiences. Work in chemistry labs provides ample opportunities for this.     

Toxicity of tributyltin to willow trees

BACKGROUND: Tributyltin is an organotin compound, used as an antifouling agent in ship paint, with heavy impact on the marine environment. Contaminated dredged harbor sludge is now dumped on land. The toxicity of tributyltin (TBT) to trees has not yet been quantified. Eventually, a vegetation cover on the dumped sludge could be established for the purpose of non-food cash crop production and phytoremediation. METHODS: The phytotoxicity of tributyltin chloride (TBTCl) and tributyltin hydride (TBTH) was measured at pH 4 and at pH 7 using the willow tree transpiration test. Different pH levels of the nutrient solutions were achieved by adding ammonium salt (low pH) or nitrate (high pH) as nitrogen source. RESULTS AND DISCUSSION: At low pH (pH 4), all trees showed symptoms of poor health. Transpiration decreased at concentrations above or equal to 0.1 mg TBTCl/l and 1 mg TBTH/L. The TBT toxicity was more pronounced at pH 7. The trees survived even the highest dose of 10 mg/l TBTCl or TBTH, although their growth and transpiration was strongly reduced. CONCLUSION: In contrast to other organisms, TBTCl and TBTH were less toxic to higher plants. RECOMMENDATIONS AND OUTLOOK: The toxicity of TBT is no hindrance for establishing vegetation on TBT-contaminated sludge. Phytoremediation and cash crop production could be possible with suitable plants.     

捷克共和国的APELL计划

捷克共和国APELL计划试实施的一个试验项目是在科林县组织的,之所以选择这个地方,是由于该地区有化工厂和炼油厂存在.为科林市及其周围地区设计的IZIS信息系统的试运行始于1996年12月.IZIS把一个应急指挥中心与国家、市和地区的机构和组织以及私人公司连接在一起.     

Greenhouse gas Emissions projections and mitigation options for the Czech Republic, 1990–2010

The models used to assess greenhouse gas mitigation options for the Czech Republic are discussed and compared with respect to their capabilities and ease of use. The input data and preliminary results are described. According to the projections, Czech CO₂ emissions will not exceed their 1990 level until 2010. Assessment of several mitigation options shows that a 6% reduction in CO₂ emissions can be achieved using cost-effective technologies. Key areas for mitigation measures are fuel switching from brown coal to natural gas through replacement of boilers, efficiency improvements in household heating, and use of compact fluorescent lamps.     

Totalitarian loss of responsibility in an explosives production plant

One of the largest accidents of communist era in former Czechoslovakia occurred in an explosion production plant in Semtín 26 years ago. Original analysis of the accident concentrated on technical causes and did not look for root causes. Additional root cause analysis showed that the plant’s safety management had been decaying and that other layers of causes had lain under the root causes. According to deeper analysis in this article, the event represents an accident that shows the decay of safety management after decades of dispersed ownership in a totalitarian society. We attempt to understand the mechanisms which led the plant into such a state. Their substantial aspects are identified and a model of the development of managers’ attitude to safety is constructed. The analysis points at the replacement of ideal managers’ behavior in safety management by distorted behavior which is here termed the totalitarian loss of responsibility. Presumably, more accidents with similar backgrounds can be identified in totalitarian surroundings. The analysis shows that the Chernobyl disaster can be considered one of them. Tools that helped deepen the analysis are based on the STAMP model and on the archetypes of safety. The analysis integrates various ideas and models into a single procedure based on the original representation of assumptions about the structure of safety management.