全文获取类型
收费全文 | 754篇 |
免费 | 9篇 |
国内免费 | 24篇 |
专业分类
安全科学 | 34篇 |
废物处理 | 86篇 |
环保管理 | 68篇 |
综合类 | 54篇 |
基础理论 | 130篇 |
环境理论 | 1篇 |
污染及防治 | 253篇 |
评价与监测 | 120篇 |
社会与环境 | 36篇 |
灾害及防治 | 5篇 |
出版年
2023年 | 11篇 |
2022年 | 91篇 |
2021年 | 76篇 |
2020年 | 16篇 |
2019年 | 31篇 |
2018年 | 37篇 |
2017年 | 46篇 |
2016年 | 49篇 |
2015年 | 33篇 |
2014年 | 43篇 |
2013年 | 99篇 |
2012年 | 41篇 |
2011年 | 50篇 |
2010年 | 23篇 |
2009年 | 34篇 |
2008年 | 17篇 |
2007年 | 17篇 |
2006年 | 10篇 |
2005年 | 9篇 |
2004年 | 9篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1996年 | 1篇 |
1995年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1982年 | 2篇 |
1981年 | 4篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1977年 | 1篇 |
1976年 | 2篇 |
1973年 | 1篇 |
1969年 | 1篇 |
排序方式: 共有787条查询结果,搜索用时 15 毫秒
41.
Seyed Mohammad Majedi Barry C. Kelly Hian Kee Lee 《Environmental science and pollution research international》2014,21(20):11811-11822
Cloud point extraction (CPE) factors, namely Triton X-114 (TX-114) concentration, pH, ionic strength, incubation time, and temperature, were optimized for the separation of nano-sized copper(II) oxide (nCuO) in aqueous matrices. The kinetics of phase transfer was studied using UV–visible spectroscopy. From the highest separation rate, the most favorable conditions were observed with 0.2 %?w/v of TX-114, pH?=?9.0, ionic strength of 10 mM NaCl, and incubation at 40 °C for 60 min, yielding an extraction efficiency of 89.2?±?3.9 % and a preconcentration factor of 86. The aggregate size distribution confirmed the formation of very large nCuO–micelle assemblies (11.9 μm) under these conditions. The surface charge of nCuO was also diminished effectively. An extraction efficiency of 91 % was achieved with a mixture of TX-100 and TX-114 containing 30 wt.% of TX-100. Natural organic and particulate matters, represented by humic acid (30 mg/L) and micron-sized silica particles (50 mg/L), respectively, did not significantly reduce the CPE efficiency (<10 %). The recovery of copper(II) ions (20 mg/L) in the presence of humic acid was low (3–10 %). The spiked natural water samples were analyzed either directly or after CPE by inductively coupled plasma mass spectrometry following acid digestion/microwave irradiation. The results indicated the influence of matrix effects and their reduction by CPE. A delay between spiking nCuO and CPE may also influence the recovery of nCuO due to aggregation and dissolution. A detection limit of 0.04 μg Cu/L was achieved for nCuO. 相似文献
42.
43.
Khani MH 《Environmental science and pollution research international》2011,18(5):790-799
Introduction
The application of response surface methodology is presented for optimizing the removal of U ions from aqueous solutions using Padina sp., a brown marine algal biomass. 相似文献44.
Farideh Golbabaei Monireh Khadem Asghar Ghahri Mohammad Babai Mostafa Hosseini Mirghani SeyedSomea 《International journal of occupational safety and ergonomics》2013,19(4):647-655
This study evaluated the influence of welding on pulmonary functions in welders. Spirometry tests were performed before and after work shift in 91 welders and 25 clerks (control group). We examined forced vital capacity (FVC), forced expiratory volume in 1 s (FEV1), FEV1/FVC ratio and forced expiratory flow 25%-75% (FEF 25–75). Significant differences were found for FVC and FEV1/FVC between welders and the control group in pre- and post-shift measurements (p < .001). In welders, smoking and nonsmoking habit had no significant effects on any pulmonary indices before or after shift. Work experience and fume concentrations also had no significant effects on the majority of spirometric indices (p > .05). Most welders had at least 1 of the respiratory symptoms. Significant differences were found between pre- and post-shift indices (as percentage of predicted values calculated with spirometer) and between the welders engaged in some welding tasks and the control group before work shift. This study documented work-related changes in pulmonary functions in the welders and marked drops in these functions without symptoms in some welders. 相似文献
45.
46.
Mohammad M. Hossain Franco Berruti Cedric Briens 《Journal of environmental science and health. Part. B》2016,51(12):860-867
Valuable chemicals can be separated from agricultural residues by chemical or thermochemical processes. The application of pyrolysis has already been demonstrated as an efficient means to produce a liquid with a high concentration of desired product. The objective of this study was to apply an insect and microorganism bioassay-guided approach to separate and isolate pesticidal compounds from bio-oil produced through biomass pyrolysis. Tobacco leaf (Nicotianata bacum), tomato plant (Solanum lycopersicum), and spent coffee (Coffea arabica) grounds were pyrolyzed at 10°C/min from ambient to 565°C using the mechanically fluidized reactor (MFR). With one-dimensional (1D) MFR pyrolysis, the composition of the product vapors varied as the reactor temperature was raised allowing for the selection of the temperature range that corresponds to vapors with a high concentration of pesticidal properties. Further product separation was performed in a fractional condensation train, or 2D MFR pyrolysis, thus allowing for the separation of vapor components according to their condensation temperature. The 300–400°C tobacco and tomato bio-oil cuts from the 1D MFR showed the highest insecticidal and anti-microbial activity compared to the other bio-oil cuts. The 300–350 and 350–400°C bio-oil cuts produced by 2D MFR had the highest insecticidal activity when the bio-oil was collected from the 210°C condenser. The tobacco and tomato bio-oil had similar insecticidal activity (LC50 of 2.1 and 2.2 mg/mL) when the bio-oil was collected in the 210°C condenser from the 300–350°C reactor temperature gases. The 2D MFR does concentrate the pesticidal products compared to the 1D MFR and thus can reduce the need for further separation steps such as solvent extraction. 相似文献
47.
The field of oil spill cost modelling is not as well explored as desirable. Generally speaking, the existing models have either low accuracy, in that their predictions are far from the real cost, or low applicability, in that they are only valid under very specific conditions; such as in one particular country. This work strives to construct a model that is functional in a global scope and still possess a high level of accuracy. The resulting attempt is in many ways superior to the publicly available competitors, not only because of its predictive capacity but also because the model is quick to use, and its input variables should be readily available to any informed user. The model is more accurate comparing with similar available models. However, further study is needed to modify it to obtain more realistic results. 相似文献
48.
Hosein Kamani Mohammad Hoseini Mahdi Seyedsalehi Yousef Mahdavi Jalil Jaafari Gholam Hosein Safari 《Environmental science and pollution research international》2014,21(12):7319-7328
Particulate matter is an important air pollutant, especially in closed environments like underground subway stations. In this study, a total of 13 elements were determined from PM10 and PM2.5 samples collected at two subway stations (Imam Khomeini and Sadeghiye) in Tehran’s subway system. Sampling was conducted in April to August 2011 to measure PM concentrations in platform and adjacent outdoor air of the stations. In the Imam Khomeini station, the average concentrations of PM10 and PM2.5 were 94.4?±?26.3 and 52.3?±?16.5 μg m?3 in the platform and 81.8?±?22.2 and 35?±?17.6 μg m?3 in the outdoor air, respectively. In the Sadeghiye station, mean concentrations of PM10 and PM2.5 were 87.6?±?23 and 41.3?±?20.4 μg m?3 in the platform and 73.9?±?17.3 and 30?±?15 μg m?3, in the outdoor air, respectively. The relative contribution of elemental components in each particle fraction were accounted for 43 % (PM10) and 47.7 % (PM2.5) in platform of Imam Khomeini station and 15.9 % (PM10) and 18.5 % (PM2.5) in the outdoor air of this station. Also, at the Sadeghiye station, each fraction accounted for 31.6 % (PM10) and 39.8 % (PM2.5) in platform and was 11.7 % (PM10) and 14.3 % (PM2.5) in the outdoor. At the Imam Khomeini station, Fe was the predominant element to represent 32.4 and 36 % of the total mass of PM10 and PM2.5 in the platform and 11.5 and 13.3 % in the outdoor, respectively. At the Sadeghiye station, this element represented 22.7 and 29.8 % of total mass of PM10 and PM2.5 in the platform and 8.7 and 10.5 % in the outdoor air, respectively. Other major crustal elements were 5.8 % (PM10) and 5.3 % (PM2.5) in the Imam Khomeini station platform and 2.3 and 2.4 % in the outdoor air, respectively. The proportion of other minor elements was significantly lower, actually less than 7 % in total samples, and V was the minor concentration in total mass of PM10 and PM2.5 in both platform stations. 相似文献
49.
Hamed Gharibi Mohammad Hossein Sowlat Amir Hossein Mahvi Morteza Keshavarz Mohammad Hossein Safari Saeedeh Lotfi Mahnaz Bahram Abadi Azim Alijanzadeh 《Chemosphere》2013,90(4):1487-1494
The present study aimed to evaluate the performance of a bipolar electrolysis/electrocoagulation reactor designed to enhance the sludge dewaterability. The reactor was 15 L in volume, with two series of plates used in it; Ti/RuO2 plates for the electrolysis of the sludge, and also aluminum and iron plates for electrocoagulation process. The dewaterability of the sludge was determined in terms of its capillary suction time (CST) and specific resistance to filtration (SRF), while the degree of sludge disintegration was determined based on the value of degree of sludge disintegration (DDSCOD). The maximum reduction in CST and SRF was observed at a detention time of 20 min and a voltage of 30 V. However, increasing of both detention time and voltage significantly increased the values of CST and SRF even to an extent that they both exceeded those of the untreated sludge. The optimal degree of sludge disintegration achieved by the present study was 2.5%, which was also achieved at a detention time of 20 min and a voltage of 30 V. As reported previously, increased DDSCOD values led to increasing CST and SRF values, due primarily to the disruption of the sludge flocs. According to the results from the present study, it can be concluded that simultaneous application of electrocoagulation and electrolysis is effective in enhancing the sludge dewaterability, because electrocoagulation helps to achieve a higher degree of sludge disintegration while maintaining the desired sludge dewaterability. 相似文献
50.
Santanu K. Ray Gautam Chattopadhyay Asim K. Ray 《Journal of the Air & Waste Management Association (1995)》2013,63(6):716-721
Abstract A detailed characterization has been made of the dust generated during steel making in basic oxygen furnaces (BOF). Chemical composition and particle size distribution have been analyzed. X-ray diffraction, scanning electron microscopy, and electron probe micro-analysis techniques have been used to identify the morphology and the nature of the major iron-bearing phases as well as the gangue constituents. The dust characteristics have been found to be widely different, depending on the type of process used in BOF steel making, namely, suppressed combustion or total combustion. The type of dust abatement system (dry or wet) additionally influences the nature of the gangue constituents. The possibility of utilizing the iron-bearing major phases has been examined. 相似文献