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231.
Ehrich Dorothée Schmidt Niels M. Gauthier Gilles Alisauskas Ray Angerbjörn Anders Clark Karin Ecke Frauke Eide Nina E. Framstad Erik Frandsen Jay Franke Alastair Gilg Olivier Giroux Marie-Andrée Henttonen Heikki Hörnfeldt Birger Ims Rolf A. Kataev Gennadiy D. Kharitonov Sergey P. Killengreen Siw T. Krebs Charles J. Lanctot Richard B. Lecomte Nicolas Menyushina Irina E. Morris Douglas W. Morrisson Guy Oksanen Lauri Oksanen Tarja Olofsson Johan Pokrovsky Ivan G. Popov Igor Yu. Reid Donald Roth James D. Saalfeld Sarah T. Samelius Gustaf Sittler Benoit Sleptsov Sergey M. Smith Paul A. Sokolov Aleksandr A. Sokolova Natalya A. Soloviev Mikhail Y. Solovyeva Diana V. 《Ambio》2020,49(3):801-804
Ambio - In the original published article, some of the symbols in figure 1A were modified incorrectly during the typesetting and publication process. The correct version of the figure is provided... 相似文献
232.
Adeline Jondeau-Cabaton Amélie Soucasse Emilien L. Jamin Nicolas Creusot Marina Grimaldi Isabelle Jouanin Sélim Aït-Aïssa Patrick Balaguer Laurent Debrauwer Daniel Zalko 《Environmental science and pollution research international》2013,20(5):2705-2720
Complex mixtures of contaminants with potential adverse effects on human health and wildlife are found in the environment and in the food chain. These mixtures include numerous anthropogenic compounds of various origins and structures, which may behave as endocrine disruptors. Mixture’s complexity is further enhanced by biotic and abiotic transformations. It is therefore necessary to develop new strategies allowing the identification of the structure of known, as well as unknown, nuclear receptor (NR) ligands present in complex matrices. We explored the possibility to use NR-based affinity columns to characterize the presence of bioactive molecules in environmental complex mixtures. Estrogen receptor α (ERα)-based affinity columns were used to trap and purify estrogenic substances present in surface sediment samples collected in a French river under mixed anthropogenic pressure. We combined biological, biochemical and analytical approaches to characterize the structure of ligands retained on columns and demonstrate the presence of known active molecules such as bisphenol A and octylphenol, but also of unexpected ERα ligands (n-butylparaben, hydroxyl-methyl-benzofuranone). High resolution mass spectrometry results demonstrate that ERα affinity columns can be used for the isolation, purification and identification of known as well as unknown estrogenic contaminants present in complex matrices. 相似文献
233.
234.
Herve Plaisance Pierre Mocho Nicolas Sauvat Jane Vignau-Laulhere Katarzyna Raulin Valerie Desauziers 《Environmental science and pollution research international》2017,24(31):24156-24166
Basing on the material emission data obtained in a test chamber, chemical mass balance (CMB) was used to assess the source apportionment of volatile organic compound (VOC) concentrations in three newly built timber frame houses. CMB has been proven to be able to discriminate the source contributions for two contrasted environmental conditions (with and without ventilation). The shutdown of the ventilation system caused an increase in the VOC concentrations due to the increased contribution of indoor surface materials like the door material and furniture explaining together over 65% of total VOCs. While the increase in formaldehyde concentration is mainly due to furniture (contribution of 70%), the increase in α-pinene concentration is almost exclusively attributable to the emission of door material (up to 84%). The apportionment of VOC source contributions appears as highly dependent on the position of source materials in the building (surface materials or internal materials) and the ventilation conditions explaining that the concentrations of compounds after the shutdown of ventilation system do not increase in equivalent proportion. Knowledge of indoor sources and its contributions in real conditions may help in the selection of materials and in the improvement of construction operations to reduce the indoor air pollution. 相似文献
235.
236.
Sicard P Dalstein-Richier L Vas N 《Environmental pollution (Barking, Essex : 1987)》2011,159(2):351-362
In the South-Eastern French Mediterranean region, high ozone concentrations were measured since many years and specific symptoms like chlorotic mottles were detected on Arolla pines. We presented results for the 2000-2008 period concerning the trend analysis for ambient ozone concentrations and related forest damages, with the Mann and seasonal Kendall tests. Ozone precursor’s emissions from Europe have been reduced over the last 20 years. Decreases in annual averages, median, 25th and 98th percentiles and maxima values were found. The seasonal trend analysis for the high-lying stations showed a decreasing trend for the warm season, when main ozone production is the photochemistry, and an increase for the cold period, caused by a reduced ozone titration. Statistics on Arolla Pine reveal strong correlations between mottling intensity and the high ozone concentrations. Finally, decreases for the ozone concentrations, and associated statistics, AOT40 values and for the mottling intensity on conifers needles were observed. 相似文献
237.
Mapped environmental classifications are defined using various procedures, but there has been little evaluation of the differences
in their ability to discriminate variation in independent ecological characteristics. We tested the performance of environmental
classifications of the streams and rivers of France that had been defined from the same environmental data using geographic
regionalization and numerical classification of individual river valley segments. Test data comprised invertebrate assemblages,
water chemistry, and hydrological indexes obtained from sites throughout France. Classification performance was measured by
analysis of similarity (ANOSIM). Geometric regions defined by a regular grid and without regard to environmental variables
and a posteriori classifications based on clustering the test datasets defined lower and upper bounds of performance for a
given number of classes. Differences in classification performances were generally small. The ANOSIM statistics for the a
posteriori classifications were around twice that of all environmental classifications, including geometrically defined regions.
The hydro-ecoregions performed slightly better for the invertebrate data and the network classification performed slightly
better for the chemistry and hydrological data. Our results indicate that environmental classifications that are defined using
different procedures can be comparable in terms of their ability to discriminate variation of ecological characteristics and
that alleged differences in performance arising from different classification procedures can be small relative to unexplained
variation. We conclude that definition procedures might have little effect on the performance of large-scale environmental
classifications and decisions over which procedures to use should be based primarily on pragmatic considerations. 相似文献
238.
Karst aquifers are uniquely vulnerable to contamination. In the Barton Springs segment of the karstic Edwards aquifer (Texas, U.S.A.), urban contaminants such as pesticides and volatile organic compounds frequently are detected in spring base flow. To determine whether contaminant concentrations change in response to storms, and if they therefore might act as tracers of focused recharge, samples were collected from Barton Springs at closely spaced intervals following three storms. Two herbicides (atrazine and simazine), two insecticides (carbaryl and diazinon), and a solvent (tetrachloroethene) described breakthrough curves over a 1-week period following one or more storms. The breakthrough curves were decomposed into two to five log-normal subcurves, which were interpreted as representing pulses of contaminants moving through the aquifer. Each subcurve could be used in the same way as an artificial tracer to determine travel time to and recovery at the spring. The contaminants have several advantages over artificial tracers: they represent the actual compounds of interest, they are injected essentially simultaneously at several points, and they are injected under those conditions when transport is of the most interest, i.e., following storms. The response of storm discharge, specific conductance, and contaminant loading at the spring depended on initial aquifer flow conditions, which varied from very low (spring discharge of 0.48 m3/s) to high (spring discharge of 2.7 m3/s): concentrations and recovery were the highest when initial aquifer flow conditions were low. This behavior provides information about aquifer structure and the influence of aquifer flow condition on transport properties. 相似文献
239.
An efficient sequential, biological and photocatalytic treatment to reduce the pollutant levels in wastewater due to the bleaching process during paper production is reported. For a biological pre-treatment, 800 ml of non-sterilized effluent was inoculated with Trametes versicolor immobilized in polyurethane foam, with 25 g l(-1) glucose, 6.75 mM CuSO(4), and 0.22 mM MnSO(4) added, and cultured at 25 degrees C with an air flow of 800 ml min(-1) for 8d. The fungus did not inhibit growth of the heterotropic populations of the effluent. After 4d of culture, the chemical oxygen demand (COD) reduction and colour removal (CR) were 82% and 80%, respectively, with laccase (LAC) and manganese peroxidase (MnP) activities of 345 U l(-1) and 78 U l(-1), respectively. The COD reduction and CR correlated positively (p<0.0001) with LAC and MnP activities. Chlorophenol removal was 99% of pentachlorophenol, 99% of 2,3,4,6-tetrachlorophenol (2,3,4,6-TCP), 98% of 3,4-dichlorophenol (3,4-DCP) and 77% of 4-chlorophenol (4-CP), while 2,4,5-trichlorophenol (2,4,5-TCP) increased to 0.2 mg l(-1). The pre-treated effluent was then exposed to a photocatalytic treatment. The treatment with photolysis resulted in 9% CR and 46% COD reduction, 42% CR and 60% COD reduction by photocatalysis, and 62% CR and 85% COD reduction by heterogeneous photocatalysis with the system TiO(2)/Ru(x)Se(y) (Fig. 4). With this treatment the bacterial and fungal populations also decreased by 5 logarithmic units with respect to the biological treatment alone (Fig. 5). The total sequential treatment resulted in a 92% CR (from 5800 UC), 97% COD reduction (from 59 g l(-1)) and 99% chlorophenol removal at 96 h and 20 min. 相似文献
240.
Chunyan Liu Jirko Holst Zhisheng Yao Nicolas Brüggemann Klaus Butterbach-Bahl Shenghui Han Xingguo Han Bart Tas Andreas Susenbeth Xunhua Zheng 《Atmospheric environment (Oxford, England : 1994)》2009,43(19):3086-3095
We present a methane (CH4) budget for the area of the Baiyinxile Livestock Farm, which comprises approximately 1/3 of the Xilin river catchment in central Inner Mongolia, P.R. China. The budget calculations comprise the contributions of natural sources and sinks as well as sources related to the main land-use in this region (non-nomadic pastoralism) during the growing season (May–September). We identified as important CH4 sources floodplains (mean 1.55 ± 0.97 mg CH4–C m?2 h?1) and domestic ruminants, which are mainly sheep in this area. Within the floodplain significant differences between investigated positions were detected, whereby only positions close-by the river or bayous emitted large amounts of CH4 (mean up to 6.21 ± 1.83 mg CH4–C m?2 h?1). Further CH4 sources were sheepfolds (0.08–0.91 mg CH4–C m?2 h?1) and pasture faeces (1.34 ± 0.22 mg CH4–C g?1 faeces dry weight), but they did not play a significant role for the CH4 budget. In contrast, dung heaps were not a net source of CH4 (0.0 ± 0.2 for an old and 0.0 ± 0.3 μg CH4–C kg?1 h?1 for a new dung heap). Trace gas measurements along two landscape transects (volcano, hill slope) revealed expectedly a mean CH4 uptake (volcano: 76.5 ± 4.3; hill: 28.3 ± 5.3 μg CH4–C m?2 h?1), which is typical for the aerobic soils in this and other steppe ecosystems. The observed fluxes were rarely influenced by topography.The CH4 emissions from the floodplain and the sheep were not compensated by the CH4 oxidation of aerobic steppe soils and thus, this managed semi-arid grassland did not serve as a terrestrial sink, but as a source for this globally important greenhouse gas. The source strength amounted to 1.5–3.6 kg CH4–C ha?1 during the growing season, corresponding to 3.5–8.7 kg C ha?1 yr?1. 相似文献