Organophosphates in aircraft cabin and cockpit air--method development and measurements of contaminants

Methods for measurements and the potential for occupational exposure to organophosphates (OPs) originating from turbine and hydraulic oils among flying personnel in the aviation industry are described. Different sampling methods were applied, including active within-day methods for OPs and VOCs, newly developed passive long-term sample methods (deposition of OPs to wipe surface areas and to activated charcoal cloths), and measurements of OPs in high-efficiency particulate air (HEPA) recirculation filters (n = 6). In total, 95 and 72 within-day OP and VOC samples, respectively, have been collected during 47 flights in six different models of turbine jet engine, propeller and helicopter aircrafts (n = 40). In general, the OP air levels from the within-day samples were low. The most relevant OP in this regard originating from turbine and engine oils, tricresyl phosphate (TCP), was detected in only 4% of the samples (min-max 相似文献   

Editorial: special issue Environmental monitoring and assessment

Environmental and Ecological Statistics -     

Depletion of selective serotonin reuptake inhibitors during sewage sludge composting

Sewage and sewage sludge is known to contain pharmaceuticals, and since sewage sludge is often used as fertilizer within agriculture, the reduction of the selective serotonin reuptake inhibitors (SSRIs) Citalopram, Sertraline, Paroxetine, Fluvoxamine and Fluoxetine during composting has been investigated. Sewage sludge was spiked with the SSRIs before the composting experiment started, and the concentration of the SSRIs in the sludge during a 21 day composting period was measured by liquid phase microextraction (LPME) and high-performance liquid chromatography–mass spectrometry. All the SSRIs had a significant decrease in concentration during the composting process. The highest reduction rates were measured for Fluoxetine and Paroxetine and the lowest for Citalopram. In addition three out of four known SSRI metabolites were found in all the samples, and two of them showed a significant increase in concentration during the composting period.     

Radon risk assessment: The effect of voluntary sampling distributions and bias

This paper examines the problem of estimating indoor radon concentrations for radon-induced lung cancer risk assessment. Previous authors have identified various problems and possible corrections for the use of generally available radon screening measurements. Bias evident in data collected from volunteers is described; regional databases developed from voluntary data generally exhibit higher mean values than those obtained from random samples. Tools are developed to better characterize the differences in voluntary and random concentration distributions. Application is demonstrated using voluntary and random radon survey data for the state of North Dakota.     

Understanding organizational diversity management programs: A theoretical framework and directions for future research

With the changing demographic composition of the workforce, managing diversity in organizations is an important organizational function. Organizations have employed varying approaches to diversity management (DM), resulting in varying organizational outcomes. Meanwhile, researchers have called for more theoretical development within the DM area. We present a framework rooted in social and cross‐cultural psychological research, to foster theory development and empirical testing in the area of DM. We also derive several propositions to guide future research on DM and note some boundary conditions that suggest research opportunities of their own. Our framework contributes a theoretical conceptualization that enhances our understanding of organizations' DM efforts, integrates current typologies, and suggests new directions of inquiry for management scholars as well as guidelines for practitioners in the area. Copyright © 2012 John Wiley & Sons, Ltd.     

Determination of antibiotic substances in hospital sewage water using solid phase extraction and liquid chromatography/mass spectrometry and group analogue internal standards

A method for determination of antibiotics in hospital sewage water has been developed and validated. Analogue internal standards for fluoroquinolones, sulfonamides, trimethoprim, beta-lactams (penicillins and cephalosporins), nitroimidazoles and tetracyclines were successfully used for calibration and shown to generally improve precision compared to external calibration. Matrix components caused ion suppression/enhancement effects during the MS detection for all analytes studied. Two effects were observed: general suppression and short-term variations in the MS response. In the hospital sewage water large temporal variations in the analyte concentration were observed during the course of the sampling period (seven grab samples in 13 h). Analyte concentrations varied within the following ranges (in microg l(-1)): ciprofloxacin, 3.6-101.0; metronidazole, 0.1-90.2; sulfamethoxazole, 0.4-12.8; ofloxacin, 0.2-7.6; trimethoprim, 0.6-7.6; and doxycycline, 0.6-6.7.     

SOURCES OF VARIABILITY IN CONDUCTING PEBBLE COUNTS: THEIR POTENTIAL INFLUENCE ON THE RESULTS OF STREAM MONITORING PROGRAMS1

Pebble counts have been used for a variety of monitoring projects and are an important component of stream evaluation efforts throughout the United States. The utility of pebble counts as a monitoring tool is, however, based on the monitoring objectives and the assumption that data are collected with sufficient precision to meet those objectives. Depending upon the objective, sources of variability that can limit the precision of pebble count data include substrate heterogeneity at a site, differences in substrate among sample locations within a stream reach, substrate variability among streams, differences in when the substrate sample is collected, differences in how and where technicians pick up substrate particles, and how consistently technicians measure the intermediate axis of a selected particle. This study found that each of these sources of variability is of sufficient magnitude to affect results of monitoring projects. Therefore, actions such as observer training, increasing the number of pebbles measured, evaluating several riffles within a reach, evaluating permanent sites, and narrowing the time window during which pebble counts are conducted should be considered in order to minimize variability. The failure to account for sources of variability associated with pebble counts within the study design may result in failing to meet monitoring objectives.     

Valuation of commercial central Himalayan medicinal plants

This study estimates the national-level annual volume and value of commercial medicinal plant harvest in Nepal. Data were collected using open-ended questionnaires administered to local medicinal plant traders (n=149) in 15 districts in Nepal and regional wholesalers (n=53) in India. The annual trade volume is estimated to range from 7000 to 27 000 tons, with 14 500 tons harvested in the case year 1997-1998. The corresponding annual export value, calculated using regional wholesaler purchasing prices in the main markets in India, is estimated at US dollars 7-30 million, with a value of US$16 million in 1997-1998. Around 10% of rural households are involved in commercial harvesting. Lower ecological zones dominate supplies in both volume and value terms; herbs constitute the most important life form in value terms. Around 36% of volume and 51% of value derive from destructive harvesting. It is argued that annual volume and value figures are likely to be conservative estimates. The implications of findings for Himalayan medicinal plant conservation and trade are briefly discussed.     

Solid-phase microextraction coupled with atomic emission spectroscopy--rapid screening for volatile chlorinated compounds

Solid-phase microextraction (SPME) coupled with atomic emission spectroscopy was evaluated as a rapid screening tool for volatile halogenated compounds in water samples. After extraction, the SPME fiber was introduced to the injector where the analytes were rapidly and efficiently desorbed. The analytes entered the detector over a short period of time and produced one well-defined analyte signal. Element selective responses were measured to confirm the presence and to roughly estimate the content of volatile compounds. The total time for extraction and detection was approximately 5 min, which makes this method a rapid and promising technique for determination of total amount of volatile halogenated compounds. The proposed technique may prove useful as a screening test in order to pinpoint the samples that need further assessment by capillary gas chromatography.     

Photoacclimation in phytoplankton: implications for biomass estimates, pigment functionality and chemotaxonomy

Chl a and C-normalized pigment ratios were studied in two dinophytes (Prorocentrum minimum and Karlodinium micrum), three haptophytes (Chrysochromulina leadbeateri, Prymnesium parvum cf. patelliferum, Phaeocystis globosa), two prasinophytes (Pseudoscourfieldia marina, Bathycoccus prasinos) and the raphidophyte Heterosigma akashiwo, in low (LL, 35 μmol photons m⁻² s⁻¹) and high light (HL, 500 μmol photons m⁻² s⁻¹). Pigment ratios in LL and HL were compared against a general rule of photoacclimation: LL versus HL ratios ≥1 are typical for light-harvesting pigments (LHP) and <1 for photoprotective carotenoids. Peridinin, prasinoxanthin, gyroxanthin-diester and 19′-butanoyloxy-fucoxanthin were stable chemotaxonomic markers with less than 25% variation between LL versus HL Chl a–normalized ratios. As expected, Chls exhibited LL/HL to Chl a ratios >1 with some exceptions such as Chl c ₃ in P. globosa and MV Chl c ₃ in C. leadbeateri. LL/HL to Chl a ratios of photosynthetic carotenoids were close to 1, except Hex-fuco in P. globosa (four-fold higher Chl a ratio in HL vs LL). Although pigment ratios in P. globosa clearly responded to the light conditions the diadinoxanthin-diatoxanthin cycle remained almost unaltered at HL. Total averaged pigment and LHP to C ratios were significantly higher in LL versus HL, reflecting the photoacclimation status of the studied species. By contrast, the same Chl a-normalized ratios were weakly affected by the light intensity due to co-variation with Chl a. Based on our data, we suggest that the interpretation of PPC and LHP are highly dependent on biomass normalization (Chl a vs. C).