Seasonal evolution of gas-phase PCB concentrations in the Venice Lagoon area

The concentrations of gas-phase PCBs were measured from March 2002 to June 2003 at two sites of the Venice Lagoon and at one site of the Euganei hills. The aims of this study were to evaluate the various gas-phase PCB sources, the spatial and temporal variability of PCB concentrations in the gas-phase that enter the Venice Lagoon atmosphere and the influence of the air temperature on PCB trends. The highest annual average concentration of summation PCBs was observed at the station directly influenced by "urban" sources with values about 3 and 1.5 times higher compared to the concentrations found at the stations where "marine" sources and "not subjected to direct local sources" were respectively sampled from. The temporal trends of summation PCBs concentrations were similar at the three sampling stations corresponding to seasonal temperature changes. Greater concentrations occurred in the summer and first autumn months while the lower ones occurred in late autumn and winter. The temperature dependences were investigated using plots of the natural logarithm of the summation PCBs concentrations vs. reciprocal mean temperatures.     

The influence of climate and dam construction on the Ibera wetlands, Argentina

The purpose of this work is to assess the impact on the Esteros del Ibera wetland ecosystem caused by the Yacyreta dam, a large hydroelectric power plant on the Parana River, Argentina, in comparison to other factors of environmental change. The project of the dam started around 1970. The power plant began operating in 1994. In 1989, the neighboring Ibera wetland ecosystem showed a substantial increase in the water level for which several different causes were conceivable, including climate change and the dam construction. We analyzed all existing hydrometeorological data and studied other changes that were observed in this ecosystem. A water balance model was used to analyze different scenarios. Increased groundwater inflow, generated since the construction of the dam, appears to be affecting the wetland more than any other factor. The study has implications for the assessment of global and regional consequences of building dams.

Isomeric analysis of BTEXs in the atmosphere using beta-cyclodextrin capillary chromatography coupled with thermal desorption and mass spectrometry

An analytical method capable of determining trace levels of BTEX-aromatics (benzene, toluene, ethylbenzene, m-, p- and o-xylenes) in the atmosphere with as high resolution as possible has been developed. The method is based on the preconcentration of air samples using a multibed tube (Carbopack C, Carbograph 1) at ambient temperature, followed by thermal desorption, and analysis of aromatic species by a beta-cyclodextrin capillary chromatography coupled with mass spectrometry. The resolution achieved was sufficient for individual separation of BTEXs as well as m- and p-xylenes. The BTEX-ratios have been determined in an air tunnel and in on-road, suburban and rural forest atmosphere. The ethylbenzene/m-xylene ratios could provide a deep insight into anthropogenic related NMHC patterns at different locations and under different meteorological conditions and may reflect photochemical processes in the best way.     

Multivariate tools to investigate the spatial contaminant distribution in a highly anthropized area (Gulf of Naples,Italy)

Environmental Science and Pollution Research - The Gulf of Naples located in a high anthropized coastal area is subjected to an infrastructural intervention for the installation of a submarine...     

Chronic exposure to lead acetate promotes changes in the alveolar bone of rats: microstructural and physical–chemical characterization

Environmental Science and Pollution Research - There are a few data relating to the effects of lead (Pb) exposure on the alveolar bone, which has very distinct morphophysiological characteristics...