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241.
Kudłak B Rogowska J Wolska L Kałas M Łęczyński L Namieśnik J 《Journal of environmental monitoring : JEM》2012,14(4):1231-1236
The paper presents the results of toxicity determinations carried out on sediment samples collected in the vicinity of the wreck of the German s/s Stuttgart (the southern part of the Gulf of Gdańsk, off the Polish coast) in relation to the determination of polycyclic aromatic hydrocarbons (PAHs). The toxicity of surface and core sediment samples was assessed using two biotest organisms-the bioluminescent bacteria Vibrio fischeri and the ostracod Heterocypris incongruens. PAH levels in these samples were determined by GC-MS. The surface sediments collected at W2 (ca. 34 m north of the shipwreck) and W4 (ca. 415 m north-east of the wreck) as well as the core sediments collected at WR3 (ca. 400 m north-east of the wreck) were the most heavily polluted with substances toxic to the biotest organisms. The chronic and acute toxicities in the case of most of the surface sediment samples studied are correlated. This may suggest that not only hydrophobic chemicals (like PAHs from fuel residues) but also more polar chemicals (resulting from the conversion of aromatic hydrocarbons) are responsible for the toxicity levels found. There is a clear dependence between the levels of chronic toxicity and PAH concentrations in the core sediment samples. In addition, a simultaneous decrease in the PAH content and chronic toxicity was noted in all the core sediment samples at depths below 80 cm. 相似文献
242.
Danuta Barałkiewicz Maria Chudzińska Barbara Szpakowska Dariusz Świerk Ryszard Gołdyn Renata Dondajewska 《Environmental monitoring and assessment》2014,186(10):6789-6803
We studied the effect of storm water drained by the sewerage system and discharged into a river and a small reservoir, on the example of five catchments located within the boundaries of the city of Poznań (Poland). These catchments differed both in terms of their surface area and land use (single- and multi-family housing, industrial areas). The aim of the analyses was to explain to what extent pollutants found in storm water runoff from the studied catchments affected the quality of surface waters and whether it threatened the aquatic organisms. Only some of the 14 studied variables and 22 chemical elements were important for the water quality of the river, i.e., pH, TSS, rain intensity, temperature, conductivity, dissolved oxygen, organic matter content, Al, Cu, Pb, Zn, Fe, Cd, Ni, Se, and Tl. The most serious threat to biota in the receiver came from the copper contamination of storm water runoff. Of all samples below the sewerage outflow, 74 % exceeded the mean acute value for Daphnia species. Some of them exceeded safe concentrations for other aquatic organisms. Only the outlet from the industrial area with the highest impervious surface had a substantial influence on the water quality of the river. A reservoir situated in the river course had an important influence on the elimination of storm water pollution, despite the very short residence time of its water. 相似文献
243.
Renata Pilarczyk Jerzy Wójcik Paweł Czerniak Piotr Sablik Bogumiła Pilarczyk Agnieszka Tomza-Marciniak 《Environmental monitoring and assessment》2013,185(10):8383-8392
Concentrations of toxic heavy metals (cadmium (Cd), lead (Pb)) and major nutritional and trace elements (Ca, Mg, P, Cu, Fe, Mn, Se, Zn) were analyzed in the milk of Simmental (n?=?20) and Holstein-Friesian (n?=?20) cows from an organic farm. Elements were determined using inductively coupled plasma emission atomic spectrometry. The conducted research showed that the milk of Simmental cows was characterized by the more advantageous mineral composition and lower concentration of noxious heavy metals compared to the milk of Holstein-Friesian cows. In the milk of Simmental cows, significantly lower concentrations of Pb and Cd (P?<?0.001) and Cu (P?<?0.05) and significantly higher concentrations of Fe and Mg (P?<?0.05) as well as nonsignificantly higher concentrations of Ca, Mn, and Se were found. In the milk of both breeds, very low Cu concentrations were recorded. The higher-than-recommended concentration of Pb in milk was also found. In the milk of both breeds, the significant positive correlations between concentrations of the following elements were observed: Pb–Cd, Pb–Se, Cd–Se, Cd–Mn, Zn–Cu, Zn–P, Ca–P, Ca–Mg, and Mg–P. The correlations between other elements within each of the analyzed breeds separately were also found. 相似文献
244.
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246.
W. Rogula-Kozłowska B. Błaszczak S. Szopa K. Klejnowski I. Sówka A. Zwoździak M. Jabłońska B. Mathews 《Environmental monitoring and assessment》2013,185(1):581-601
The paper discusses ambient concentrations of PM2.5 (ambient fine particles) and of 29 PM2.5-related elements in Zabrze and Katowice, Poland, in 2007. The elemental composition of PM2.5 was determined using energy dispersive X-ray fluorescence (EDXRF). The mobility (cumulative percentage of the water-soluble and exchangeable fractions of an element in its total concentration) of 18 PM2.5-related elements in Zabrze and Katowice was computed by using sequential extraction and EDXRF combined into a simple method. The samples were extracted twice: in deionized water and in ammonium acetate. In general, the mobility and the concentrations of the majority of the elements were the same in both cities. S, Cl, K, Ca, Zn, Br, Ba, and Pb in both cities, Ti and Se in Katowice, and Sr in Zabrze had the mobility greater than 70%. Mobility of typical crustal elements, Al, Si, and Ti, because of high proportion of their exchangeable fractions in PM, was from 40 to 66%. Mobility of Fe and Cu was lower than 30%. Probable sources of PM2.5 were determined by applying principal component analysis and multiple regression analysis and computing enrichment factors. Great part of PM2.5 (78% in Katowice and 36% in Zabrze) originated from combustion of fuels in domestic furnaces (fossil fuels, biomass and wastes, etc.) and liquid fuels in car engines. Other identified sources were: power plants, soil, and roads in Zabrze and in Katowice an industrial source, probably a non-ferrous smelter or/and a steelwork, and power plants. 相似文献
247.
Jann Peyrat Małgorzata Braun Christian Dolnik Maike Isermann Hartmut Roweck 《Journal of Coastal Conservation》2009,13(4):235-246
Coastal dune ecosystems are among the most dynamic habitats with high conservation value in Europe but are also under strong
anthropogenic pressure regarding coastal protection and recreation. Hence, it is of high importance to know about long-term
natural and anthropogenic changes and development of protected dune habitats for nature conservation, as well as for coastal
management. This paper aims to identify the vegetation dynamics on the Łeba Bar/Poland over a period of 74 years by cartometric
comparison using modern Geographical Information System (GIS). To quantify the rate of vegetation dynamics two aerial photographs
dating from 1932 and 2006 were digitalized and analyzed with GIS to produce digital vegetation maps. Information about decrease,
increase and stability of vegetation types of this area are discussed. The results show that there has been a clear reduction
in the total area of bare sand and a considerable increase of woodlands and dense grass communities. Nevertheless, the remaining
extensive drift sand areas and deflation hollows on the Łeba Bar offer one of the most important habitats for pioneer vegetation
on bare sand of migrating dunes and dunes at the Southern Baltic coast. The present work proved the need to observe the future
development of the vegetation communities and to implement management measures to maintain the dynamic of this unique dune
landscape. 相似文献
248.
The effect of bed properties on methane removal in an aerated biofilter--model studies 总被引:1,自引:0,他引:1
The capacity of laboratory-scale aerated biofilters to oxidize methane was investigated. Four types of organic and mineral-organic materials were flushed with a mixture of CH4, CO2 and air (1:1:8 by volume) during a six-month period. The filter bed materials were as follows: (1) municipal waste compost, (2) an organic horticultural substrate, (3) a composite of expanded perlite and compost amended with zeolite, and (4) the same mixture of perlite and compost amended with bentonite. Methanotrophic capacity during the six months of the experiment reached maximum values of between 889 and 1036 g m−2 d−1. Batch incubation tests were carried out in order to determine the influence of methane and oxygen concentrations, as well as the addition of sewage sludge, on methanotrophic activity. Michaelis constants KM for CH4 and O2 were 4.6-14.9%, and 0.7-12.3%, respectively. Maximum methanotrophic activities Vmax were between 1.3 and 11.6 cm3 g−1 d−1. The activity significantly increased when sewage sludge was added. The main conclusion is that the type of filter bed material (differing significantly in organic matter content, water-holding capacity, or gas diffusion coefficient) was not an important factor in determining methanotrophic capacity when oxygen was supplied to the biofilter. 相似文献
249.
The long-term operational stability (159 d) in removal of organics and ammonia from synthetic wastewater was investigated. The experiment was carried out in two identical plug flow membrane bioreactors (MBR) (each with a submerged A4 Kubota membrane) operated under aerobic conditions. The vacuum distillate of a crude oil fraction in the emulsified state, which was used to model the petroleum pollutants, was added into the feed medium. The performance of biological treatment was evaluated by physicochemical analyses such as nitrogen forms, COD, and BOD. Additionally, monitoring of PAHs in the wastewaters was performed using HPLC-diode array detector. Moreover, the community structure of bacteria was analyzed by polymerase chain reaction-denaturing gradient gel electrophoresis. The MBR treatment was very effective with reduction by more than 90% of COD and Total Organic Carbon. Nearly complete removal of petroleum originated non-polar micropollutants was observed. The influence of the highest dosage of petroleum pollutants (1000 μLL(-1)) on the bacterial community was noted. 相似文献
250.
Analysis of annual fluctuations in the content of phenol,chlorophenols and their derivatives in chlorinated drinking waters 总被引:3,自引:0,他引:3
Michałowicz J Stufka-Olczyk J Milczarek A Michniewicz M 《Environmental science and pollution research international》2011,18(7):1174-1183