全文获取类型
收费全文 | 91779篇 |
免费 | 1228篇 |
国内免费 | 1140篇 |
专业分类
安全科学 | 3721篇 |
废物处理 | 3363篇 |
环保管理 | 14005篇 |
综合类 | 21158篇 |
基础理论 | 26494篇 |
环境理论 | 74篇 |
污染及防治 | 15318篇 |
评价与监测 | 5551篇 |
社会与环境 | 3907篇 |
灾害及防治 | 556篇 |
出版年
2022年 | 813篇 |
2021年 | 822篇 |
2020年 | 658篇 |
2019年 | 872篇 |
2018年 | 1200篇 |
2017年 | 1213篇 |
2016年 | 2222篇 |
2015年 | 1844篇 |
2014年 | 2591篇 |
2013年 | 9271篇 |
2012年 | 2237篇 |
2011年 | 2535篇 |
2010年 | 3322篇 |
2009年 | 3422篇 |
2008年 | 2068篇 |
2007年 | 1957篇 |
2006年 | 2350篇 |
2005年 | 2320篇 |
2004年 | 2626篇 |
2003年 | 2470篇 |
2002年 | 2042篇 |
2001年 | 2415篇 |
2000年 | 2068篇 |
1999年 | 1539篇 |
1998年 | 1386篇 |
1997年 | 1364篇 |
1996年 | 1496篇 |
1995年 | 1581篇 |
1994年 | 1482篇 |
1993年 | 1334篇 |
1992年 | 1335篇 |
1991年 | 1299篇 |
1990年 | 1248篇 |
1989年 | 1219篇 |
1988年 | 1058篇 |
1987年 | 992篇 |
1986年 | 995篇 |
1985年 | 1060篇 |
1984年 | 1159篇 |
1983年 | 1171篇 |
1982年 | 1177篇 |
1981年 | 1095篇 |
1980年 | 944篇 |
1979年 | 928篇 |
1978年 | 823篇 |
1977年 | 720篇 |
1976年 | 638篇 |
1974年 | 605篇 |
1973年 | 634篇 |
1972年 | 632篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
511.
M. R. Theobald U. Dragosits C. J. Place J. U. Smith M. Sozanska L. Brown D. Scholefield A. Del Prado J. Webb P. G. Whitehead A. Angus I. D. Hodge D. Fowler M. A. Sutton 《Water, Air, & Soil Pollution: Focus》2004,4(6):135-142
The distribution and impacts of different nitrogen pollutants are inextricably linked. To understand the problem fully, the interactions between the different pollutants need to be taken into account. This is particularly important when it comes to abatement techniques, since measures to reduce emissions of one nitrogen pollutant can often lead to an increase in another. This project represents a step towards greater understanding of these issues by linking together new and existing nitrogen flux models into a larger framework. The modelling framework has been constructed and some of the nitrogen flows between fields, farms and the atmosphere have been modelled for a UK study area for typical farm management scenarios. 相似文献
512.
Davey L. Jones John F. Farrar Kevin K. Newsham 《Water, Air, & Soil Pollution: Focus》2004,4(6):169-175
Amino acids constitute one of the largest inputs of organic nitrogen (N) to most polar soils and have been hypothesized to be important in regulating vegetational succession and productivity in Arctic ecosystems. Our understanding of amino acid cycling in these soils, however, is poor. The aim of this study was to investigate the size and rate of turnover of the amino acid pool in a range of Arctic and Antarctic soils. Our results indicate that in polar soils with either high or low ornithogenic inputs the amino acid pool is small in comparison to the inorganic N pool (NO–3 and NH+4). The free amino acid pool constituted only a small proportion of the total dissolved organic nitrogen (DON) pool in these soils. Here we show that these low concentrations may be due to rapid use by the soil microbial community in both Arctic and Antarctic soils. The turnover of the amino acid pool in soil was extremely rapid, with a half-life ranging from 2 to 24 h, indicating that this N pool can be turned over many hundred times each summer when polar soils are frequently unfrozen. The implications of amino acids in N cycling and plant and microbial nutrition are discussed. 相似文献
513.
Ed Gidman Royston Goodacre Bridget Emmett Lucy J. Sheppard Ian D. Leith Dylan Gwynn-Jones 《Water, Air, & Soil Pollution: Focus》2004,4(6):251-258
The potential for metabolic fingerprinting via Fourier-transform infrared (FT-IR) spectroscopy to provide a novel approach for the detection of plant biochemical responses to N deposition is examined. An example of spectral analysis using shoot samples taken from an open top chamber (OTC) experiment simulating wet ammonium deposition is given. Sample preparation involved oven drying and homogenisation via mill grinding. Slurries of a consistent dilution were then prepared prior to FT-IR analysis. Spectra from control, 8 and 16 kg N ha–1 yr–1 treatments were then subjected to cross-validated discriminant function analysis. Ordination diagrams showed clear separation between the three N treatments examined. The potential for using Calluna vulgaris (L.) Hull as a bioindicator of N deposition is further evident from these results. The results also clearly demonstrate the power of FT-IR in discriminating between subtle phenotypic alterations in overall plant biochemistry as affected by ammonium pollution. 相似文献
514.
Jonn A. Foulk Wayne Y. Chao Danny E. Akin Roy B. Dodd Patricia A. Layton 《Journal of Polymers and the Environment》2004,12(3):165-171
Municipal solid wastes generated each year contain potentially useful and recyclable materials for composites. Simultaneously, interest is high for the use of natural fibers, such as flax (Linum usitatissimum L.), in composites thus providing cost and environmental benefits. To investigate the utility of these materials, composites containing flax fibers with recycled high density polyethylene (HDPE) were created and compared with similar products made with wood pulp, glass, and carbon fibers. Flax was either enzyme- or dew-retted to observe composite property differences between diverse levels of enzyme formulations and retting techniques. Coupling agents would strengthen binding between fibers and HDPE but in this study fibers were not modified in anyway to observe mechanical property differences between natural fiber composites. Composites with flax fibers from various retting methods, i.e., dew- vs. enzyme-retting, behaved differently; dew-retted fiber composites resulted in both lower strength and percent elongation. The lowest level of enzyme-retting and the most economical process produces composites that do not appear to differ from the highest level of enzyme-retting. Flax fibers improved the modulus of elasticity over wood pulp and HDPE alone and were less dense than glass or carbon fiber composites. Likely, differences in surface properties of the various flax fibers, while poorly defined and requiring further research, caused various interactions with the resin that influenced composite properties. 相似文献
515.
Nugraha E. Suyatma Alain Copinet Lan Tighzert Veronique Coma 《Journal of Polymers and the Environment》2004,12(1):1-6
Biodegradable film blends of chitosan with poly(lactic acid) (PLA) were prepared by solution mixing and film casting. The main goal of these blends is to improve the water vapor barrier of chitosan by blending it with a hydrophobic biodegradable polymer from renewable resources. Mechanical properties of obtained films were assessed by tensile test. Thermal properties, water barrier properties, and water sensitivity were studied by differential scanning calorimeter analysis, water vapor permeability measurements, and surface-angle contact tests, respectively. The incorporation of PLA to chitosan improved the water barrier properties and decreased the water sensitivity of chitosan film. However, the tensile strength and elastic modulus of chitosan decreased with the addition of PLA. Mechanical and thermal properties revealed that chitosan and PLA blends are incompatible, consistent with the results of Fourier transform infrared (FTIR) analysis that showed the absence of specific interaction between chitosan and PLA. 相似文献
516.
David S. Reay Keith A. Smith Anthony C. Edwards 《Water, Air, & Soil Pollution: Focus》2004,4(2-3):437-451
Dissolved nitrous oxide (N2O), nitrate (NO3 -), and ammonium (NH4 +) concentrations in an agricultural field drain were intensively measured over the period of field nitrogen (N) fertilisation and for several weeks thereafter. Supersaturations of dissolved N2O were observed in field drain waters throughout the study. On entry to an open drainage ditch, concentrations of dissolved N2O rapidly decreased and a total N2O-N emission via this pathway of 13.2 g over the period of study (45 days) was calculated. This compared with a predicted emission of the order of 300 g, based on measured losses of NO3 - and NH4 + in the field drainage water, and the default IPCC emission factor of 0.01 kg N2O-N per kg Nentering rivers and estuaries. In contrast to widespread evidence of a clear relationship between the amount of N applied to agricultural land and subsequent direct N2O emission from the soil surface, the relationship between the amount of N2O in soil drainage waters and the amount of N applied was poor. We conclude that the complexity, both spatially and temporally, of the processes ultimately responsible for the amount of N2O in agricultural drainage waters make a straightforward relationship between N2O concentration and N application rate unlikely in all but the simplest of systems. 相似文献
517.
Argiriou Athanassios A. Kassomenos Pavlos A. Lykoudis Spyridon P. 《Water, Air, & Soil Pollution: Focus》2004,4(4-5):65-74
It is well known that air pollution is one of the major factors affecting human health and the activities in a town. Among the various air pollutants an interesting one, especially for sunny climates, is the reactive O3. O3 varies significantly through the year; it is therefore very important to know the onset and the duration of the warm period of the year since at that time O3 concentrations increase significantly. In this work, an attempt was made to determine the onset of warm season of the year as well as its duration in various sites located in Northeastern Mediterranean. For this purpose, a fuzzy clustering method is used. The method was applied on the isobaric thickness between 1000 and 500 hPa for the period from 1974 to 1997. The results were compared to conventional methods based on synoptic classification and were found to be in good agreement. 相似文献
518.
This article presents a review of in situ technologies for the remediation of soils contaminated with lead, zinc, and/or cadmium. The objective of this review is to assess the developmental status of the available in situ technologies and provide a general summary of typical applications and limitations of these technologies. The literature review identified seven in situ remediation technologies—solidification/stabilization, vitrification, electrokinetic remediation, soil flushing, phytoextraction, phytostabilization, and chemical stabilization. These technologies were considered for their ability to meet a specific set of remediation objectives under a range of conditions. Each of these technologies has both strengths and weaknesses for addressing particular remedial situations discussed in the article for each of the technologies. A general summary of which technologies are most applicable to common remedial scenarios is also provided. © 2004 Wiley Periodicals, Inc. 相似文献
519.
An Erratum has been published for this article in Remediation 14(4) 2004, 141. The selection of remediation options for the management of unacceptable risks at contaminated sites is hindered by insufficient information on their performance under different site conditions. Therefore, there is a need to define “operating windows” for individual remediation options to summarize their performance under a variety of site conditions. The concept of the “operating window” has been applied as both a performance optimization tool and decision support tool in a number of different industries. Remediation‐option operating windows could be used as decision support tools during the “options appraisal” stage of the Model Procedures (CLR 11), proposed by the Environment Agency (EA) for England and Wales, to enhance the identification of “feasible remediation options” for “relevant pollutant linkages.” The development of remediation‐option operating windows involves: 1) the determination of relationships between site conditions (“critical variables”) and option performance parameters (e.g., contaminant degradation or removal rates) and 2) the identification of upper‐ and lower‐limit values (“operational limits”) for these variables that define the ranges of site conditions over which option performance is likely to be sufficient (the “operating window”) and insufficient (the “operating wall”) for managing risk. Some research has used case study data to determine relationships between critical variables and subsurface natural attenuation (NA) process rates. Despite the various challenges associated with the approach, these studies suggest that available case study data can be used to develop operating windows for monitored natural attenuation (MNA) and, indeed, other remediation options. It is envisaged that the development of remediation‐option operating windows will encourage the application of more innovative remediation options as opposed to excavation and disposal to landfill and/or on‐site containment, which remain the most commonly employed options in many countries. © 2004 Wiley Periodicals, Inc. 相似文献
520.