Statistical apportionment and risk assessment of selected metals in sediments from Rawal Lake (Pakistan)

The present study was carried out in order to evaluate the statistical apportionment and risk assessment of selected metals (Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Pb, Sr, and Zn) in freshly deposited sediments in Rawal Lake, Pakistan. Composite sediment samples were collected, oven-dried, grounded, homogenized, and processed to assess the water-soluble and acid extractable concentrations of the metals in the water extract and acid extract of the sediments using flame atomic absorption spectrophotometer. Statistical methods were used to identify the possible sources of the metals. Sediment quality guidelines and potential acute toxicity were used to evaluate the ecotoxicological sense of selected metals. Non-carcinogenic health risk assessment was also carried out to determine the potential adverse health risks to the inhabitants. Relatively higher concentration was noted for Ca, Fe, Mg, Na, K, Mn, and Sr in the sediment samples. Principal component analysis and cluster analysis revealed anthropogenic contributions of Cd, Pb, Cr, Mn, Fe, and Li in the sediments. Enrichment factors of the metals in sediments showed severe to moderate enrichment of Cd, Pb, Ca, Fe, Li, Mn, and Sr. Geoaccumulation indices and contamination factors evidenced significant contamination by Cd and Pb, although, on the whole, low degree of contamination was noted. The levels of some metals exceeded the sediment quality guidelines, which revealed frequently adverse biological effects to the dwelling biota in the aquatic ecosystem. The sediments were found to be significantly contaminated by Cd, Pb, Cr, Mn, Fe, and Li.     

Spatial patterns of heavy metals in soil under different geological structures and land uses for assessing metal enrichments

One hundred and thirty composite soil samples were collected from Hamedan county, Iran to characterize the spatial distribution and trace the sources of heavy metals including As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, and Fe. The multivariate gap statistical analysis was used; for interrelation of spatial patterns of pollution, the disjunctive kriging and geoenrichment factor (EF_G) techniques were applied. Heavy metals and soil properties were grouped using agglomerative hierarchical clustering and gap statistic. Principal component analysis was used for identification of the source of metals in a set of data. Geostatistics was used for the geospatial data processing. Based on the comparison between the original data and background values of the ten metals, the disjunctive kriging and EF_G techniques were used to quantify their geospatial patterns and assess the contamination levels of the heavy metals. The spatial distribution map combined with the statistical analysis showed that the main source of Cr, Co, Ni, Zn, Pb, and V in group A land use (agriculture, rocky, and urban) was geogenic; the origin of As, Cd, and Cu was industrial and agricultural activities (anthropogenic sources). In group B land use (rangeland and orchards), the origin of metals (Cr, Co, Ni, Zn, and V) was mainly controlled by natural factors and As, Cd, Cu, and Pb had been added by organic factors. In group C land use (water), the origin of most heavy metals is natural without anthropogenic sources. The Cd and As pollution was relatively more serious in different land use. The EF_G technique used confirmed the anthropogenic influence of heavy metal pollution. All metals showed concentrations substantially higher than their background values, suggesting anthropogenic pollution.     

Mean Vehicle Speed Distributions for the Spatiotemporal Estimation of Exhaust Emissions

Link Emissions Models estimate traffic-related air pollution emissions at the individual road link level and inform governmental policies for air quality management. The current South Australian Link Emissions Model (CLEM) assumes constant spatiotemporal traffic flow at a single fixed mean speed, a potential limitation as the variability of exhaust emissions with vehicle speed has been established in the literature.We extend CLEM to eliminate the assumption of constant traffic flow, through the derivation of mean Australian vehicle speed distributions for different road types. Specifically, we successfully model the vehicle speed profile data from the second National In-Service Emissions study using Nearest Neighbour Kernel Density Estimation. We propose a mean speed Distribution Link Emissions Model (DLEM) for exhaust emission estimation based on the derived mean speed distributions. DLEM is an augmented, enhanced version of CLEM, accommodating a range of vehicle speeds and road types. The performance of the extended model, DLEM, is analysed in comparison to the current model, CLEM, through a case study analysis of vehicle exhaust emissions on a typical arterial road in Adelaide, South Australia. Results indicate use of DLEM and, by extension, mean vehicle speed distributions, has a strong impact on emission estimation. In particular, the fixed speed model, CLEM, may be substantially underestimating exhaust emissions of carbon monoxide, non-methane volatile organic compounds and particulate matter less than 2.5 μm in diameter. These are common exhaust pollutants that have been extensively linked with adverse health effects including respiratory morbidity and premature mortality.     

Production and Purification of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) Degrading Enzyme from Streptomyces sp. AF-111

A poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) degrading bacterial strain designated as AF-111 was isolated from sewage sludge sample. The bacterium was identified by 16S rRNA gene sequencing. The results revealed that strain AF-111 showed 99 % similarity with Streptomyces althioticus strain NRRL B-3981 and designated as Streptomyces sp. strain AF-111. An extracellular PHBV depolymerase enzyme was produced under optimized conditions and purified through ammonium sulphate fractionation and column chromatography. The enzyme was purified to homogeneity, indicated by sodium dodecyl sulfate–polyacrylamide gel electrophoresis and molecular weight was found to be approximately 51 kDa. Effect of temperature, pH, metal ions and inhibitors on the PHBV depolymerase activity was determined. The enzyme was stable at wide range of temperature (35–55 °C) and pH (6–8). PHBV depolymerase was stable in the presence of different metal ions except iron and zinc which had inhibitory effect on depolymerase activity. Both ethylenediamine teteracetic acid and phenylmethyl sulphonyl fluoride strongly inhibited enzyme activity which indicates that this enzyme belongs to the serine hydrolase family like other polyhydroxyalkanoate depolymerases. The results show that a depolymerase from strain AF-111 can effectively degrade PHBV, therefore, it can be applied in the process of biochemical monomer recycling.     

Canada shows the way

Editorial

Canada shows the way     

Mobilising social energy against environmental challenge: understanding the groundwater recharge movement in western India

This paper explores a large-scale and growing popular movement to augment groundwater recharge in the Saurashtra region of western India, an area that has been facing acute water scarcity and other associated problems. As a social phenomenon, the movement is at an early stage of its development. However, it is interesting to study it for many reasons. First, even a decade after it began, it is still growing in scale and following. Second, it is entirely spontaneous and internally driven, necessitating no public resources or support. Third, early indications are that its social and ecological impacts are beneficial and highly significant. Fourth, the movement was catalysed and spearheaded by spiritual and religious institutions, which made ingenious use of non-economic messages and motivators in forging a new natural resource ethic based on a broad, collective rationality among movement members. It appears, however, that beyond a threshold, the movement acquired a logic and energy of its own which might fuel its future sustainability and growth. Finally, the movement has important lessons to offer because mobilising social energy on such a scale and intensity can perhaps be one of most effective responses to many of the environmental challenges the world faces today.     

Three-dimensional nickel ion transport through porous media using magnetic resonance imaging

The transport of Ni2+ ions in a column, filled with porous media, was observed in three dimensions and time by magnetic resonance imaging (MRI) in a clinical scanner. For porous media we used glass beads or quartz sand in a saturated continuous flow mode. The magnetic moment of Ni2+ decreased the T1 relaxation time of 1H in aqueous solution. This concentration-dependent effect was used by a fast low angle shot (FLASH) MRI sequence for imaging the concentration of the dissolved ions. Since Ni2+ behaves as a conservative tracer under the chosen conditions, the tracer motion was representative for the water flow in the porous medium. Currently, we can achieve an isotropic spatial resolution of 1.5 mm and a temporal resolution of 170 s. The transport observation gives direct access to hydraulic flow properties of the porous media. The fluid flow velocity field was calculated by a fronttracking method and the statistical properties of the velocities were investigated. We also compared the experimental data with the three-dimensional particle tracking model PARTRACE, which uses the experimental flow field as input.     

Disparity of a Seat Cushion and Its Influence on Postural Control

Properties of supporting surfaces of a seat have an influence on postural control. Centre of pressure (COP) displacement parameters reflect both the balance controlling process and movements of the centre of a mass of entire body. The subjects of the study were 9 healthy men. A seat cushion was examined with a 2-force platform setup. Force exertion at a seat pan and feet and COP displacement at a seat pan were measured to analyse postural control. Analysis of variance determined the differences in postural control depending on a cushion type among the subjects. Significant differences in COP displacement parameters were in COP trajectory length, medio-lateral COP displacement and COP velocity. The results of the study showed that foam cushion ensures better postural control.     

Left-sided gastroschisis and bilateral multicystic dysplastic kidneys: a rare combination of anomalies

Left-sided gastroschisis is very rare. We report a case of left-sided gastroschisis associated with bilateral multicystic dysplastic kidneys. This combination of anomalies is unknown. The pathogenesis of gastroschisis is not well understood. It is now viewed as a malformation rather than disruption. The findings in this case support this view. The combination of dysplastic kidneys with ventral body wall defect suggests an early developmental defect. Copyright © 2007 John Wiley & Sons, Ltd.