自然灾害防控产业的技术突破与发展路径战略研究∗

在全球气候变化及地质活动日益活跃的孕灾大环境下,我国亟待实现自然灾害的快速高效应急处理,相应的灾害防控产业升级同样势在必行。结合自然灾害防控关键环节的发展方向,通过文献整理、现场调研、专家咨询及问卷调查等方式,分析了自然灾害防控产业面临的问题与挑战,开展自然灾害防控产业技术突破与发展路径的研究,提出以下对策措施：构建更为完善的标准化体系,严格核定从业资格,实时把控自然灾害防控产业的市场动态, 保障产业市场良性竞争;立足本土化发展优势,集群化发展自然灾害防控产业,贯通自然灾害多产业链条;以自然灾害防灾减灾的基础研究为主导,通过理论创新和技术迭代,完成自然灾害产业升级,提升产业整体性、系统性和协同性,打造防灾减灾产业端的国际核心竞争力。本文将为自然灾害防控的产业高质量快速发展提供前瞻性、针对性、储备性的科学参考。     

生活垃圾堆肥工艺条件及其反应动力学研究

为了改善堆肥微环境 ,提高生活垃圾堆肥速率 ,研究堆肥工艺条件及其反应动力学是非常必要的。通过控制堆肥工艺条件 ,如初始温度、含水率、C/N比及堆料颗粒大小 ,研究生活垃圾堆肥过程中生物、化学及物理因素的变化。试验结果表明 ,生活垃圾堆肥反应符合一级反应动力学 ;合理控制堆肥初始反应条件 ,能明显提高堆肥效率。     

改善深圳河水质的补水方案及生态影响初步分析

深圳河旱季天然径流量小而污染负荷高,为了改善河流水质,在削减入河污染物的同时有必要采取补水措施。利用水质模型,计算了不同污水处理率下,分别以污水资源化再生水、珠江口海水和大鹏湾海水为补水水源时,深圳河达到基本不黑臭所需的补水量。讨论了补水方案对河流水质、盐度、水动力条件的改变及其对生态系统的影响。研究表明,引海水对河流生态系统的冲击不容忽视。而污水资源化是较优的补水方案。     

盐蚀环境下微生物矿化岩土材料的冻融特性研究

基于MICP技术将松散砂粒改良成微生物矿化岩土材料,通过室内冻融循环实验,研究矿化材料在4种不同的冻融环境中的表观形貌、质量损失率、饱和含水率、无侧限抗压强度随冻融循环周期的变化规律,以及利用NMR测试手段分析材料的孔隙变化。结果表明:随着冻融周期增加,在4种冻融液中矿化材料均伴随剥落现象,无侧限抗压强度均呈逐渐减小趋势,质量的损失和饱和含水率的增加严重影响了材料的抗冻性能,且在5%Na₂SO₄溶液中矿化材料的粉化速度较快,质量损失最大,劣化速度最快,NMR图谱中弛豫时间大于200 ms的未冻水含量在冻融过程变化最大,是造成样本质量的损失和强度的破坏的主要原因;在去离子水溶液中样本的抗冻能力也较弱,次于Na₂SO₄溶液;在3%NaCl溶液和混合溶液中由于NaCl的存在降低材料的凝固点,使得材料的抗冻能力延长,此研究为微生物矿化岩土材料在寒冷地区的工程应用提供基础实验依据。     

Uncovering the evolution of tin use in the United States and its implications

• US tin use decreases as the GDP value added by manufacturing sector increases. • Global and China’s tin use increases as the GDP added by manufacturing increases. • A sigmoid curve can fit the US tin use data well. • US tin use patterns is not due to the finite tin reserves or resources. • Policies, substitutions, etc. play key roles in the changing tin use patterns. Tin is of key importance to daily life and national security; it is considered an essential industrial metal. The United States (US) is the world’s largest economy and consumer of natural resources. Therefore, the analysis of historical tin use in the US is helpful for understanding future tin use trends in the world as a whole and in developing countries. Time series analysis, regression analysis with GDP or GDP/capita, and historical data fitted with logistic and Gompertz models are employed in this study. Historical tin use in the US shows three stages—increase-constant-decrease, as GDP per capita has increased. Tin use in the US is negatively correlated with the GDP value added by the manufacturing sector, while the use of tin worldwide and in China continues to increase along with the GDP value added by the manufacturing sector. Although a sigmoid curve can fit the US tin use data well, that use is not directly related to the limited tin reserves or resources. Rather, policies, economic restructuring, substitutions, new end-use markets, etc. have played key roles in the changing tin use patterns. This work contributes to understanding future tin use at both the global and national levels: tin use will continue to increase with GDP at the global level, but use patterns of tin at the national level can be changed through human intervention.     

Remediation of 2,4-dichlorophenol-contaminated groundwater using nano-sized CaO2 in a two-dimensional scale tank

• Nano CaO₂ is evaluated as a remediation agent for 2,4-DCP contaminated groundwater. • 2,4-DCP degradation mechanism by different Fe²⁺ concentration was proposed. • 2,4-DCP was not degraded in the system for solution pH>10. • The 2,4-DCP degradation area is inconsistent with the nano CaO₂ distribution area. This study evaluates the applicability of nano-sized calcium peroxide (CaO₂) as a source of H₂O₂ to remediate 2,4-dichlorophenol (2,4-DCP) contaminated groundwater via the advanced oxidation process (AOP). First, the effect and mechanism of 2,4-DCP degradation by CaO₂ at different Fe concentrations were studied (Fenton reaction). We found that at high Fe concentrations, 2,4-DCP almost completely degrades via primarily the oxidation of •OH within 5 h. At low Fe concentrations, the degradation rate of 2,4-DCP decreased rapidly. The main mechanism was the combined action of •OH and O₂^•−. Without Fe, the 2,4-DCP degradation reached 13.6% in 213 h, primarily via the heterogeneous reaction on the surface of CaO₂. Besides, 2,4-DCP degradation was significantly affected by solution pH. When the solution pH was>10, the degradation was almost completely inhibited. Thus, we adopted a two-dimensional water tank experiment to study the remediation efficiency CaO₂ on the water sample. We noticed that the degradation took place mainly in regions of pH<10 (i.e., CaO₂ distribution area), both upstream and downstream of the tank. After 28 days of treatment, the average 2,4-DCP degradation level was ≈36.5%. Given the inadequacy of the results, we recommend that groundwater remediation using nano CaO₂: (1) a buffer solution should be added to retard the rapid increase in pH, and (2) the nano CaO₂ should be injected copiously in batches to reduce CaO₂ deposition.     

Degradation characteristics and metabolic pathway of 4-nitrophenol by a halotolerant bacterium Arthrobacter sp. CN2

Arthrobacter sp. strain CN2, capable of degrading 4-nitrophenol, was isolated from activated sludge. Degradation of 4-nitrophenol was optimized at pH 7.7, 30?°C, and 0.53% of glucose. Salt tolerance of 4-nitrophenol degradation was as high as 6% (w/v). Several biodegradation intermediates were identified and quantified by high-performance liquid chromatography and mass spectrometry. 4-Nitrocatechol is involved in the degradation of 4-nitrophenol by CN2. Scale-up of 4-nitrophenol degradation was conducted in a bioreactor with different salinity. When the salinity was below 7%, the degradation rate of 4-nitrophenol was above 90% (100 mg L^?1, 3 L).     

Recent advances in the photocatalytic reduction of carbon dioxide

Fossil fuels are currently the major energy source and are rapidly consumed to supply the increasing energy demands of mankind. CO₂, a product of fossil fuel combustion, leads to climate change and will have a serious impact on our environment. There is an increasing need to mitigate CO₂ emissions using carbon–neutral energy sources. Therefore, research activities are devoted to CO₂ capture, storage and utilization. For instance, photocatalytic reduction of CO₂ into hydrocarbon fuels is a promising avenue to recycle carbon dioxide. Here we review the present status of the emission and utilization of CO₂. Then we review the photocatalytic conversion of CO₂ by TiO₂, modified TiO₂ and non-titanium metal oxides. Finally, the challenges and prospects for further development of CO₂ photocatalytic reduction are presented.     

左氧氟沙星在蒙脱石存在条件下对大肠杆菌的毒性效应

采用批实验研究了蒙脱石对左氧氟沙星的吸附机理及对左氧氟沙星抗菌作用的影响。结果表明,中性条件下存在培养基时,左氧氟沙星在蒙脱石上前2 h即达到吸附平衡,吸附等温线符合Langmuir吸附方程,吸附率达90%以上;蒙脱石吸附左氧氟沙星存在阳离子交换作用、氢键作用、疏水作用、阳离子键桥作用、静电吸附作用等物理化学过程;蒙脱石本身不具有抑菌、杀菌活性,且由于蒙脱石增大了微生物附着的比表面积,在特定情况下可以促进微生物的生长;扣除其对微生物生长的促进作用后,蒙脱石吸附左氧氟沙星降低了后者的毒性效应,其抑菌率降低约25%。上述结果为进一步研究抗生素在环境中的毒理效应提供了基础依据。     

乙酸钠为电子供体时反硝化耦合甲烷化过程的数学模拟

基于化学计量学与生物力能学确定生化反应的理论反应式,结合multiplicative Monod及non-competitive Monod方程,建立了反硝化耦合甲烷化的数学模型。以乙酸钠为电子供体,厌氧颗粒污泥为接种污泥,通过间歇实验获取模型的相关参数。结果表明:该模型能较好地分析反硝化耦合甲烷化过程底物降解、竞争规律及反硝化中间产物对甲烷化的抑制作用;预测气体的累积产气量及各菌群生物量变化。参数灵敏度分析表明:甲烷化、硝酸盐还原和亚硝酸盐过程的灵敏度因子分别为km,a、km,NO3和km,NO2,这证实最大比底物利用速率对底物降解过程影响最显著,其值分别为km,a=0.098 h-1,km,NO3=0.0824 h-1和km,NO2=0.0695 h-1。