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251.
Kamaraj M. Ranjith K. S. Rajeshwari Sivaraj Rajendra Kumar R. T. Hasna Abdul Salam 《环境科学学报(英文版)》2014,26(11):2362-2368
Photocatalytic degradation of Bisphenol A (BPA), a representative endocrine disruptor chemical, was carried out under irradiation of sunlight in the presence of CexZn1-xO nanophotocatalyst. Cerium (Ce) ions were successfully incorporated into the bulk lattice of ZnO by simple co-precipitation process. The CexZn1-xO composite nanostructures exhibited higher photocatalytic efficiency than pure ZnO in the degradation of BPA under sunlight irradiation and nearly complete mineralization of BPA was achieved. The degradation rate was strongly dependent on factors such as the size and structure of catalyst, doping material concentration, BPA concentration, catalyst load, irradiation time and pH levels. This work suggested that the CexZn1-xO assisted photocatalytic degradation is a versatile, economic, environmentally benign and efficient method for BPA removal in the aqueous environment. 相似文献
252.
Sadaf Sadia Arain Tasneem Gul Kazi Hassan Imran Afridi Kapil Dev Brahman Naeemullah Sumaira Khan Abdul Haleem Panhwar Muhammad Afzal Kamboh Jamil R. Memon 《Environmental monitoring and assessment》2015,187(5):309
The present study was aimed to evaluate the cadmium (Cd) and lead (Pb) levels in the blood samples of adolescent boys, chewing different smokeless tobacco (SLT) products in Pakistan. For comparative purpose, boys of the same age group (12–15 years), not consumed any SLT products were selected as referents. To determine trace levels of Cd and Pb in blood samples, a preconcentration method, vortex-assisted liquid–liquid microextraction (VLLME) has been developed, prior to analysis by flame atomic absorption spectrometry. The hydrophobic chelates of Cd and Pb with ammonium pyrrolidinedithiocarbamate were extracted into the fine droplets of ionic liquid (IL) 1-butyl-3-methylimidazolium hexafluorophosphate, while nonionic surfactant, Triton X-114 was used as a dispersing medium. The main factors affecting the recoveries of Cd and Pb, such as concentration of APDC, centrifugation time, volume of IL and TX-114, were investigated in detail. It was also observed that adolescent boys who consumed different SLT products have 2- to 3-fold higher levels of Cd and Pb in their blood samples as compared to referent boys (p?<?0.001). 相似文献
253.
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255.
In the industrial area of Chinhat, Lucknow (India) wastewater coming from pesticide manufacturing and other industries is
used to irrigate the agricultural crops. This practice has been polluting the soil and pollutants might reach the food chain.
Gas chromatographic analysis revealed the presence of certain organochlorine pesticides in soil samples. Samples were extracted
using different solvents, i.e., hexane, acetonitrile, methanol, chloroform, and acetone (all were HPLC-grade, SRL, India).
Soil extracts were assayed for mutagenicity using Ames Salmonella/mammalian microsome test. Mutagenicity was observed in the test samples and TA98 was the most responsive strain for all the
soil extracts (irrigated with wastewater) in terms of mutagenic index in the presence (+S9) and absence (−S9) of metabolic
activation. In terms of slope (m) of linear dose–response curve for the most responsive strain TA98 exhibited highest sensitivity
against the soil extracts in the presence and absence of S9 fraction. Hexane-extracted soil sample (wastewater) exhibited
maximum mutagenicity in terms of net revertants per gram of soil in the presence and absence of S9 mix as compared to the
other soil extracts. Groundwater-irrigated soil extracts displayed low level of mutagenicity as compared to wastewater-irrigated
soil. The soil is accumulating a large number of pollutants due to wastewater irrigation and this practice of accumulation
has an adverse impact on soil health. 相似文献
256.
Ghumman AR Ghazaw YM Hashmi HN Kamal MA Niazi MF 《Environmental monitoring and assessment》2012,184(3):1671-1681
Many drainage schemes and salinity control projects have been executed world wide. Pipe drainage has widely been used in Pakistan,
Egypt and India to control waterlogging. The impact of pipe drainage on land and water was evaluated in this paper using data
of three pipe drainage projects in Pakistan namely Khushab Salinity Control and Reclamation Project, Fourth Drainage Project
in Faisalabad and Swabi Salinity Control and Reclamation Project. Data by regular monitoring of these projects were collected.
The effect of pipe drainage on water table depth at these three locations has been compared. Water quality and soil salinity
improvement due to the pipe drainage has also been investigated. Data, related to water table depths and discharges from drain
pipes/wells, was collected. Observation wells, installed at various places by the Water and Power Development Authority, were
used for collection of this data. To evaluate the impact of the projects on salinity, soil samples from all the three locations
were tested. A questionnaire was prepared to get the view of the people about the projects. It was revealed that in these
areas, due to subsurface pipe drainage, the percentage of the abandoned land has been considerably decreased. Over drainage
was observed in a few places of the projects. The farmers at such places were asked to change their cropping patterns. Ultimately,
there has been an increase in area under cultivation, crop yields and cropping intensity in the projects’ area. 相似文献
257.
Azhar Mashiatullah Muhammad Zaman Chaudhary Nasir Ahmad Tariq Javed Abdul Ghaffar 《Environmental monitoring and assessment》2013,185(2):1555-1565
Concentrations of 12 metals (Fe, Mn, Cr, Mo, Ni, Pb, Se, Sr, U, V, Zn, and Zr) in surface sediments of Karachi Coast, Pakistan were determined to evaluate their distribution and pollution assessment. The measured metals in the sediments were found to be in the range of Fe, 0.84–6.96 %; Mn, 300–1,300 μg/g; Cr, 12.0–319.84 μg/g; Mo, 0.49–2.03 μg/g; Ni, 1.53–58.86 μg/g; Pb, 9.0–49.46 μg/g; Se, 0.25–.86 μg/g; Sr, 192–1185 μg/g; U, 0.19–1.66 μg/g; V, 15.80–118.20 μg/g; Zn, 15.60–666.28 μg/g; and Zr, 44.02–175.26 μg/g. The mean contents of the metal studied were: Fe, 3.07 %, Mn, 0.05 %; Cr, 96.75 μg/g; Mo, 1.34 μg/g; Ni, 31.39 μg/g; Pb, 23.24 μg/g; Se, 0.61 μg/g; Sr, 374.83 μg/g; U, 0.64 μg/g; V, 61.75 μg/g; Zn, 204.75 μg/g; and Zr:76.27 μg/g, and arrangement of the metals from higher to lower mean content in this area is: Fe?>?Zn?>?Mn?>?Sr?>?Zn?>?Cr?>?Zr?>?V?>?Ni?>?Pb?>?Mo?>?U?>?Se. There is no significant correlation among most of these metals, indicating different anthropogenic and natural sources. To assess ecotoxic potential of marine sediments, Numerical Sediment Quality Guidelines were also applied. The concentration of Pb in all the sediments except one was lower than the threshold effect concentration (TECs) showing that there are no harmful effects to marine life from Pb. On the other hand, the concentrations of Cr, Ni, and Zn exceeded TEC in three stations, indicating their potential risk. The degree of pollution in sediments for metals was assessed by calculating enrichment factor (EF) and pollution load index (PLI). The results indicated that sediments of Layari River Mouth Area, Fish Harbour, and KPT Boat Building Area are highly enriched with Cr and Zn (EF?>?5). Sediments of Layari River Outfall Zone were moderately enriched with Ni and Pb (EF?>?2). The pollution load index was found in the range of 0.98 to 1.34. Lower values of PLI (≤1) at most of sampling locations imply no appreciable input from anthropogenic sources. However, relatively higher PLI values (>1) at Layari River Mouth Area, Fish Harbour, and KPT Boat Building Area are attributed to increased human activity in the area. 相似文献
258.
In this study, we explored the multiple heavy metal-resistant yeast isolated from heavy metal-polluted environment. The isolated yeast showed maximum growth at 30 °C, pH 7.0, and the strain was identified as Candida tropicalis through 18S ribosomal RNA (rRNA) gene sequence analysis. Yeast cells grew well in medium containing different concentrations of heavy metal ions [CdCl2, Pb(NO3)2, NaAsO2, CuSO4 and K2Cr2O7]. Minimum inhibitory concentration (MIC) against different metal ions was ranged from 5 to 19 mM, and the metal resistance value against each metal observed by yeast cells was 5 mM (Cr), 10 mM (Cd), 15 mM (As), 14 mM (Cu) and 19 mM (Pb) and increased in the following order: Pb > Cu > As ≥ Cd > Cr. The total cellular glutathione, GSH/GSSG redox couple and metallothioneins like protein (MT) were assayed by growing cultures for 24 h and exposed to 100 mg/L of each heavy metal ion. Remarkable increase in γ-glutamylcysteinylglycine (GSH) level was determined in arsenic and cadmium treatment followed by chromium, lead and copper. Stressed cells had much more oxidized GSH than unstressed cells. GSH/GSSG ratio was significantly increased in cadmium and copper treatment in contrast to chromium, arsenic and lead. Statistical analysis revealed significantly higher cysteine level in all metal-treated samples as compared to control. Antioxidant glutathione transferase activity was not detected in metal-treated and untreated yeast samples. One-dimensional electrophoresis of proteins revealed marked differences in banding pattern of heavy metal-exposed yeast samples. A prominent 20 kDa band was observed in all treated samples suggesting that some differential proteins could be over-expressed during heavy metal treatment and might be involved in cell resistance mechanisms. 相似文献
259.
A. M. O. Abdul Raheem F. A. Adekola I. O. Obioh 《Environmental Modeling and Assessment》2009,14(4):497-509
A combination of multivariate statistical methods including factor analysis, principal component analysis, principal component
regression, and multiple linear regression (MLR) were employed to evaluate the influence of seasons on the concentrations
of ozone, sulfur (IV) oxide, and oxides of nitrogen in ambient air of Nigerian cities of Lagos and Ilorin. The former city
is located in the coastal area, and it is highly congested with a high intensity of marine, vehicular, and industrial activities,
and the latter city is a medium size town, located in the central guinea savannah zone of Nigeria. Samples were collected
using a high-volume sampler from near the ground at various sites of diverse human and industrial activities, during wet and
dry seasons from 2003 to 2006. The PCA reveals three distinct groupings during the day for all data, which is a reflection
of different factors contributing to the atmospheric chemistry of these cities. The predicted ozone concentration values by
MLR agree fairly well with the measured data. The dependence of ozone on meteorological parameters including relative humidity,
air temperature, and sun exposure and the precursor pollutants depends on weather and the anthropogenic activities. The results
for the two cities indicate that reduction in the level of NO2 is accompanied by an increase in the level of ozone, suggesting the interconversion between the two via photochemical activity. 相似文献
260.
Abdul A. J. Mohamed Ibrahim Abdul Rahman Lee H. Lim 《Environmental monitoring and assessment》2014,186(10):6287-6300
This paper highlights the levels of anions (nitrate, nitrite, sulfate, bromide, chloride, and fluoride) and cations (potassium, sodium, magnesium, and calcium) in selected springs and groundwater sources in the urban-west region of Zanzibar Island. The levels of total dissolved solids (TDS) and sodium adsorption ratio (SAR) were also studied. Thirty water samples were collected in December 2012 from various types of water sources, which included closed hand-dug wells (CHDW), open hand-dug wells (OHDW), springwater (SW), public bore wells (PBW), and bore wells owned by private individuals (BWP), and analyzed after filtration and sometimes dilution. The cations were analyzed using inductively coupled plasma-optical emission spectrometry (ICP-OES). The anions were analyzed by chemically suppressed ion chromatography (IC). The ranges of the levels of the investigated parameters were as follows: Na 13.68–3,656 mg L?1, K 2.66–583 mg L?1, Mg 0.63–131.10 mg L?1, Ca 16.79–189.9 mg L?1, Cl? 8.61–4,340.97 mg L?1, F? 0–1.02 mg L?1, Br? 0–10.88 mg L?1, NO3 ? 0.18–342.4 mg L?1, NO2 ? 0–1.39, SO4 2? 4.43–534.02 mg L?1, TDS 7–6,380 mg L?1, and SAR 0.63–50. Except fluoride, most of the studied parameters in the water samples had concentrations beyond the permissible limits of the World Health Organization (WHO). The elevated concentrations are a result of seepage of contaminated water from on-site septic tanks, pit latrines, landfill leachates, fertilizer applications, and domestic effluents. These results should alert domestic water stakeholders in Zanzibar to the urgent task of initiating a quick mitigation response to control these alarming water risks. 相似文献