二氧化氯在医院含菌废水处理中的应用

二氧化氯混合消毒剂是新一代广谱高效消毒剂,消毒能力是次氯的3～5倍.二氧化氯发生器性能安全可靠,运行稳定,操作方便,对人体无不良作用.介绍了二氧化氯混合消毒剂在中国长城铝业公司职工医院含菌废水处理的应用实例.     

迈向21世纪的锅炉、压力容器、压力管道和特种设备安全科学技术

保护环境、发展经济关系到人类的前途和命运 ,是当今国际社会十分关注的重大问题。在我国 ,人们生产、生活中的安全问题是实现保护环境与发展经济的过程中需要研究解决的热点、难点问题。锅炉、压力容器、压力管道和特种设备涉及到社会生产和人民生活的各个方面 ,其安全及可靠性问题受到国家和各级政府的高度重视 ,因此 ,在市场经济发展的新形势下 ,如何有效地治理危险或危害设施、场所 ,最大限度地扼制并减少伤亡事故 ,是锅炉、压力容器、压力管道和特种设备安全科学技术需要认真解决的重要课题。     

基于FLAC3D分析的某铁矿充填效果研究

为解决辽宁某铁矿开采后地表沉陷问题,验证自研的复合激发尾砂胶结充填体充填效果,运用FLAC3D模拟软件对铁矿二步骤充填开采和地表沉陷进行数值模拟计算研究.研究结果表明:采用3种胶结充填体分别进行二步骤充填后,盐基、碱基、水泥基胶结充填体内部的应力平均值分别为0.92,0.79,0.93 MPa,最大位移值分别为38,2...     

PSO-SVM模型在化工事故风险预测中的应用研究

为了减少化工事故的发生,提高化工生产过程中事故风险预测的准确性,研究了粒子群优化算法与支持向量机(PSO-SVM)模型在事故风险预测中的应用.首先,统计分析近5年化工生产安全事故致因因素,得出化工事故风险因素统计特征,结合层次分析法,建立化工事故风险预测指标体系并确定各指标因素的权重值;然后,基于MATLAB计算生成的...     

高海拔排土场边坡安全稳定性SBAS-InSAR监测

为解决高海拔排土场边坡安全稳定性监测中常规监测仪器布置和人员值守的高投入、高风险问题,分析西藏山南桑日县某排土场边坡25景Sentinel-1A数据,利用短基线集合成孔径雷达干涉测量(SBAS-InSAR)技术监测终了排土场边坡从2018年11月4日-2020年12月23日期间的地表形变,采用基线估计状态空间模型、自适...     

铅芯橡胶支座等效线性分析模型参数的研究

针对目前铅芯橡胶支座等效线性分析模型动力参数选取不够合理的现状 ,笔者通过对铅芯橡胶支座水平动态试验分析 ,系统研究了铅芯橡胶支座等效线性分析模型参数与其几何结构及外加动力荷载特性的关系。研究结果表明 :铅芯橡胶支座等效线性分析模型参数 (水平耗能、等效刚度及等效阻尼比 )主要由其本身的几何构造及组成材料决定 ,且在往复加、卸载循环过程中具有较好的稳定性。笔者对试验数据进行数学统计分析 ,归纳出一些经验公式 ,为其等效线性化动力分析模型参数的合理选取提供了计算方法 ,从而提高其动力分析结果的安全性。     

Suggested protocol for collecting, handling and preparing peat cores and peat samples for physical, chemical, mineralogical and isotopic analyses

For detailed reconstructions of atmospheric metal deposition using peat cores from bogs, a comprehensive protocol for working with peat cores is proposed. The first step is to locate and determine suitable sampling sites in accordance with the principal goal of the study, the period of time of interest and the precision required. Using the state of the art procedures and field equipment, peat cores are collected in such a way as to provide high quality records for paleoenvironmental study. Pertinent field observations gathered during the fieldwork are recorded in a field report. Cores are kept frozen at -18 degree C until they can be prepared in the laboratory. Frozen peat cores are precisely cut into 1 cm slices using a stainless steel band saw with stainless steel blades. The outside edges of each slice are removed using a titanium knife to avoid any possible contamination which might have occurred during the sampling and handling stage. Each slice is split, with one-half kept frozen for future studies (archived), and the other half further subdivided for physical, chemical, and mineralogical analyses. Physical parameters such as ash and water contents, the bulk density and the degree of decomposition of the peat are determined using established methods. A subsample is dried overnight at 105 degree C in a drying oven and milled in a centrifugal mill with titanium sieve. Prior to any expensive and time consuming chemical procedures and analyses, the resulting powdered samples, after manual homogenisation, are measured for more than twenty-two major and trace elements using non-destructive X-Ray fluorescence (XRF) methods. This approach provides lots of valuable geochemical data which documents the natural geochemical processes which occur in the peat profiles and their possible effect on the trace metal profiles. The development, evaluation and use of peat cores from bogs as archives of high-resolution records of atmospheric deposition of mineral dust and trace elements have led to the development of many analytical procedures which now permit the measurement of a wide range of elements in peat samples such as lead and lead isotope ratios, mercury, arsenic, antimony, silver, molybdenum, thorium, uranium, rare earth elements. Radiometric methods (the carbon bomb pulse of (14)C, (210)Pb and conventional (14)C dating) are combined to allow reliable age-depth models to be reconstructed for each peat profile.     

Fate of bisphenol A during treatment with the litter-decomposing fungi Stropharia rugosoannulata and Stropharia coronilla

Bisphenol A is an endocrine disrupting compound, which is ubiquitous in the environment due to its wide use in plastic and resin production. Seven day old cultures of the litter-decomposing fungus Stropharia coronilla removed the estrogenic activity of bisphenol A (BPA) rapidly and enduringly. Treatment of BPA with purified neutral manganese peroxidase (MnP) from this fungus also resulted in 100% reduction of estrogenic activity, as analyzed using a bioluminescent yeast assay, and in the formation of polymeric compounds. In cultures of Stropharia rugosoannulata, estrogenic activity also quickly disappeared but temporarily re-emerged in the further course of cultivation. LC-MS analysis of the extracted estrogenic culture liquid revealed [M−H]⁻ ions with m/z values of 219 and 235. We hypothesize that these compounds are ring fission products of BPA, which still exhibit one intact hydroxyphenyl group to interact with estrogen receptors displayed by the yeast.     

Determination of o-phthalic acid in snow and its photochemical degradation by capillary gas chromatography coupled with flame ionization and mass spectrometric detection

Phthalic acid and its photochemical degradation has been determined in snow and rainwater samples collected during winters (2003-2010) in the Southeast of Massachusetts using capillary gas chromatography (GC) with flame ionization and mass spectrometric detection. Water samples were dried using a rotary evaporator and derivatized with a 14% BF₃/methanol reagent before GC analysis. The developed method proved simple and accurate. Phthalic acid was found in snow samples collected in a concentration range of 7.22-76.5 nM. The photodegradation of phthalate was carried out under 300 nm UV light. The direct photodecomposition of the acid is slow (5% h⁻¹). However, the addition of dissolved Fe(III) species at 2.0 μM accelerated the light-induced degradation of phthalic acid by 3.5 times in the atmospheric water samples. Photodegradation rates of phthalic acid increases with decreasing pH value of water samples in the range of pH 2.8-4.5.     

Chlorination of chlortoluron: kinetics, pathways and chloroform formation

Chlortoluron chlorination is studied in the pH range of 3-10 at 25 ± 1 °C. The chlorination kinetics can be well described by a second-order kinetics model, first-order in chlorine and first-order in chlortoluron. The apparent rate constants were determined and found to be minimum at pH 6, maximum at pH 3 and medium at alkaline conditions. The rate constant of each predominant elementary reactions (i.e., the acid-catalyzed reaction of chlortoluron with HOCl, the reaction of chlortoluron with HOCl and the reaction of chlortoluron with OCl⁻) was calculated as 3.12 (± 0.10) × 10⁷ M⁻² h⁻¹, 3.11 (±0.39) × 10² M⁻¹ h⁻¹ and 3.06 (±0.47) × 10³ M⁻¹ h⁻¹, respectively. The main chlortoluron chlorination by-products were identified by gas chromatography-mass spectrometry (GC-MS) with purge-and-trap pretreatment, ultra-performance liquid chromatography-electrospray ionization-MS and GC-electron capture detector. Six volatile disinfection by-products were identified including chloroform (CF), dichloroacetonitrile, 1,1-dichloropropanone, 1,1,1-trichloropropanone, dichloronitromethane and trichloronitromethane. Degradation pathways of chlortoluron chlorination were then proposed. High concentrations of CF were generated during chlortoluron chlorination, with maximum CF yield at circumneutral pH range in solution.