Leaching kinetics of valuable metals from waste Li-ion batteries using neural network approach

Journal of Material Cycles and Waste Management - The kinetic study of valuable metals recovery from waste lithium-ion batteries (LIBs) using the artificial neural network (ANN) was investigated. A...     

A charge model for household waste management services: a case study of Tehran municipality

In practice, it is difficult to implement Pay-As-You-Throw charge systems based on accurate estimates of waste generation. In many cities, this is made impossible, due to lack of technical and administrative infrastructure and cultural considerations, especially in developing countries. This paper presents an alternative two-component charge model that is the combination of cost-accounting technique of Waste Management Services (WMSs) and econometric functions of waste generation. Practical and computation steps considered by the model are presented as a proposal to reform the current system of waste charge in Tehran municipality. The presented model is simple to implement and resolves some of the disadvantages of the traditional methods of waste charge systems, including insufficient revenue to cover the cost of waste management and unfairness related to social inequality.     

The association between bisphenol A exposure and type-2 diabetes: a world systematic review

The present study was conducted to systematically review, analyze, and interpret all the relevant evidence in the literature on the possible link between exposure to bisphenol A (BPA) and the risk of type-2 diabetes mellitus (T2DM). We developed a comprehensive search strategy and used it to search Web of Science, Scopus, PubMed, and Google Scholar up to March 31, 2016, producing 3108 hits, of which 13 original papers were included. Findings of these studies were quite controversial; few studies indicated a significant positive association between BPA exposure and T2DM, while some other failed to detect such a relationship. Overall, it can be suggested that chance is unlikely the plausible explanation for the observed association between BPA exposure and T2DM. This was mainly because even in the negative studies some clues could be found in favor of a statistically significant relationship between BPA and T2DM. Additionally, some of the studies had shortcomings in defining the exposure and outcome measures, which, if present, might have led to underestimating the relationship between BPA exposure and T2DM. The theoretical plausibility of such a relationship found earlier in animal studies also supports this point. However, more definitive answer requires the conduct of future longitudinal studies, in which the possible association between BPA exposure and T2DM is assessed over much longer periods of time with more temporally robust BPA measurements. In addition, it would be quite beneficial if future studies be conducted in areas where data is still lacking (e.g., South America, Australia/Oceania, and Europe).

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Organochlorine contaminants in the hair of Iranian pregnant women

In the present study, the hair of pregnant women was sampled between November 2007 and January 2008 in Ahvaz and Noushahr cities and the countryside of Noushahr, Iran. They were analyzed for organochlorine pesticides (OCPs), such as dichlorodiphenyltrichloroethane (DDT) and its metabolites, hexachlorobenzene (HCB), α-, β-, and γ-hexachlorocyclohexane (HCH) isomers and seven polychlorinated (PCBs) congeners (IUPAC Nos. 28, 52, 101, 118, 138, 153 and 180). Significant differences between the concentrations of investigated pollutants were found between the locations (p < 0.05). For HCHs, the γ-HCH isomer was measured at higher mean concentrations (6 ng g⁻¹ hair) compared to the β-HCH isomer (0.03 ng g⁻¹), which generally is the most prevalent HCH in biological matrices. Very high mean concentrations of p,p′-DDT in countryside of Noushahr (24 ng g⁻¹) combined with lower values (0.6) of ratio p,p′-DDE/p,p′-DDT in the hair samples suggest recent exposure to “fresh” DDT in this region. Significant differences in OCPs and PCBs were found between primiparous and multiparous mothers (p < 0.05). There was no correlation between levels of OCPs and PCBs in the hair of Iranian pregnant women and their age. There was a significant difference (p < 0.05) in the organochlorine levels, including HCHs, between mothers who have eaten fish once a week and those who consumed fish more than once per week in Noushahr.     

Monitoring and assessment of seasonal land cover changes using remote sensing: a 30-year (1987–2016) case study of Hamoun Wetland,Iran

The availability of Landsat data allows improving the monitoring and assessment of large-scale areas with land cover changes in rapid developing regions. Thus, we pretend to show a combined methodology to assess land cover changes (LCCs) in the Hamoun Wetland region (Iran) over a period of 30-year (1987–2016) and to quantify seasonal and decadal landscape and land use variabilities. Using the pixel-based change detection (PBCD) and the post-classification comparison (PCC), four land cover classes were compared among spring, summer, and fall seasons. Our findings showed for the water class a higher correlation between spring and summer (R²?=?0.94) than fall and spring (R²?=?0.58) seasons. Before 2000, ~?50% of the total area was covered by bare soil and 40% by water. However, after 2000, more than 70% of wetland was transformed into bare soils. The results of the long-term monitoring period showed that fall season was the most representative time to show the inter-annual variability of LCCs monitoring and the least affected by seasonal-scale climatic variations. In the Hamoun Wetland region, land cover was highly controlled by changes in surface water, which in turn responded to both climatic and anthropogenic impacts. We were able to divide the water budget monitoring into three different ecological regimes: (1) a period of high water level, which sustained healthy extensive plant life, and approximately 40% of the total surface water was retained until the end of the hydrological year; (2) a period of drought during high evaporation rates was observed, and a mean wetland surface of about 85% was characterized by bare land; and (3) a recovery period in which water levels were overall rising, but they are not maintained from year to year. After a spring flood, in 2006 and 2013, grassland reached the highest extensions, covering till more than 20% of the region, and the dynamics of the ecosystem were affected by the differences in moisture. The Hamoun wetland region served as an important example and demonstration of the feedbacks between land cover and land uses, particularly as pertaining to water resources available to a rapidly expanding population.     

Mercury speciation in the Persian Gulf sediments

The concentrations of total mercury (Hg) and methyl mercury (MMHg) were determined in 78 marine sediments in the Iranian coastal waters of the Persian Gulf along nine transects perpendicular to the coastline. Total Hg ranged from 10 to 56 ng g( - 1)d.w. and MMHg from 0.1 to 0.4 ng g( - 1) d.w. The fraction of methyl mercury accounted from 0.3% to 1.1% of the total mercury amount. The organic carbon (OC) content ranged from 0.4% to 1.8%. The present study indicates that the levels of Hg in the sediments of the Iranian coast of the Persian Gulf were all in the concentration range of unpolluted areas regarding Hg (<100 ng g( - 1)). The concentrations of total Hg, methyl mercury and organic carbon were generally higher in the deeper stations. Total Hg and MMHg were significantly correlated, but no significant correlations could be found between the Hg and OC levels.     

River water quality management under incomplete information: application of an N-person iterated signaling game

One of the important issues in river quality management is to provide pollution control strategies which are acceptable for all stakeholders. When there is only one water quality checkpoint in a reach of a river which receives pollution loads of several dischargers and dischargers are penalized for any water quality violation, the game theory can be used for modeling the natural process of bargaining among load dischargers considering the assimilative capacity of a river. There are also some types of uncertainties in river water quality management which should be incorporated throughout the bargaining process. Signaling games can be utilized for modeling the bargaining among dischargers and developing perfect Bayesian equilibrium (PBE) strategies for pollution control. In this paper, a new methodology called N-person iterated signaling game is developed for river quality management considering the existing uncertainties in pollution loads of dischargers. The methodology can provide the stable PBE waste load allocation strategies. The practical utility of the proposed methodology is illustrated by applying it to a reach of the Zarjub River in Iran. This reach includes seven pollution load dischargers.     

Quantification of PAHs and chlorinated compounds by novel solid-phase microextraction based on the arrays of tin oxide nanorods

The results of an innovative study on a new and highly efficient stationary phase based on the SnO₂ nanorods coating on fused silica have been reported in this paper. SnO₂ nanorods have been grown on fused silica fibers using a hydrothermal process. The extraction properties of the fiber were investigated using headspace solid-phase microextraction (HS-SPME) mode coupled with gas chromatography–mass spectrometry detection for 1,4-dichloro-2-nitrobenzene, biphenyl, and acenaphthene. The effect of different variables on extraction efficiency was studied simultaneously using Box–Behnken method as experimental design. The variables of interest in the HS-SPME were salt effect, adsorption temperature, extraction, and desorption time. Under optimal conditions, the calibration curves were linear up to 10²–10⁵ ng?L^?1 (R ²?>?0.998) with detection limits of 10^?3, 10^?1, and 10 ng?L^?1 for acenaphthene, biphenyl, and 1,4-dichloro-2-nitrobenzene, respectively. The relative standard deviations for single fiber and fiber to fiber were less than 9.8 and 12.5 %, respectively. The high stability of the SnO₂ nanostructure coating is proved at relatively high temperatures (up to 300 °C) with a high extraction capacity and long lifespan (more than 100 times). By applying the proposed technique, promising recoveries (93–98 %) were obtained in the analysis of environmental water samples.     

A new catalytic oxidation method for sensitive quantification of bromate in flours and bottled water using AgNPs

In this paper, a simple and sensitive spectrophotometric method for the determination of nanomolar level of bromate, based on the catalytic effect of silver nanoparticles on the oxidation of acid red 14 by potassium bromate, is described. The reaction rate was monitored spectrophotometrically by measuring the decrease in absorbance of acid red 14 at 516 nm. The detection limit of the method was 8 ng/mL, and the linear range was between 15 and 130 ng/mL. The effects of acidity, concentration of reactants and reaction time, and external ions were also discussed. The optimum reaction conditions were fixed, and some kinetic parameters determined. The relative standard deviation for the determination of bromate at the concentration of 50 ng/mL was calculated to be 0.996 % (n?=?10). The method has been successfully applied to the determination of bromate in flours and bottled waters.     

Limitations of habitats as biodiversity surrogates for conservation planning in estuaries

Increasing pressures on global biodiversity and lack of data on the number and abundance of species have motivated conservation planners and researchers to use more readily available information as proxies or surrogates for biodiversity. “Habitat” is one of the most frequently used surrogates but its assumed value in marine conservation planning is not often tested. The present study developed and tested three alternative habitat classification schemes of increasing complexity for a large estuary in south-east Australia and tested their effectiveness in predicting spatial variation in macroinvertebrate biodiversity and selecting estuarine protected areas to represent species. The three habitat classification schemes were: (1) broad-scale habitats (e.g., mangroves and seagrass), (2) subdivision of each broad-scale habitat by a suite of environmental variables that varied significantly throughout the estuary, and (3) subdivision of each broad-scale habitat by the subset of environmental variables that best explained spatial variation in macroinvertebrate biodiversity. Macroinvertebrate assemblages differed significantly among the habitats in each classification scheme. For each classification scheme, habitat richness was significantly correlated with species richness, total density of macroinvertebrates, assemblage dissimilarity, and summed irreplaceability. However, in a reserve selection process designed to represent examples of each habitat, no habitat classification scheme represented species significantly better than a random selection of sites. Habitat classification schemes may represent variation in estuarine biodiversity; however, the results of this study suggest they are inefficient in designing representative networks of estuarine protected areas.