Efficient arsenic depollution in water using modified maize powder

This article reports the synthesis of an efficient, low-cost material from maize powder to depollute arsenic-contaminated water. Arsenic is toxic for humans and other organisms even at low concentrations. The most well-known and severe case of arsenic poisoning through drinking water has been found in India and Bangladesh. Numerous inorganic materials have been tested for the removal of arsenic from water bodies over the last two decades. However, all such materials have several disadvantages such as unpredictable arsenic ion removal, high cost and the generation of toxic sludge that is often more difficult to manage. Alternatively, organic material from agricultural waste may be modified to enrich functional groups responsible for As sorption and, in turn, used to depollute contaminated waters. Here, Zea mays cob powder has been modified to remove arsenic species from water. Two modified materials were produced: an aminated maize powder and a thiolated maize powder. Amination was done using epichlorohydrin and dimethylamine. Thiolation was done using thioglycolic acids. Amination increased As (III) sorption from 70 to 75.8 % and As (V) sorption from 85 to 94.42 %, compared with unmodified maize powder. Thiolation increased As (III) sorption from 70 to 81.7 % and As (V) sorption from 85 to 90 %. Amination increased usability cycles from 3 to 5. Thiolation increased usability cycles from 3 to 6. The novel modified maize biosorbent has enough potential for the development of a low-cost technological pre-treatment step, prior to high-tech chemical treatments.     

MANAGING ROTATIONAL CANAL WATER SUPPLIES ON THE FARM1

ABSTRACT: A procedure to determine optimal irrigation scheduling strategies under rotational water delivery systems is presented. The methodology involves integration of water delivery amount and frequency, irrigation management strategies, evapotranspiration sequences and crop-evapotranspiration-production functions to arrive at an optimal irrigation strategy. Application of the methodology to a farm in the service area of Western Yamuna Canal (India) where a two-stage system of rotation, one among the irrigation channels and the other among the farmers, is in vogue, reveals that maximum production is obtained with water application in a rotational manner (RI) rather than with irrigation in every or alternate supply periods. Increase in mean water supply which can be effected through improvement in on-farm conveyance and application systems, has a greater effect on yield than decrease in variance of the supply. Benefit cost analyses indicates that precision land leveling is more cost effective in increasing water supply as compared to water-course lining.     

Induction of cytochrome P-450 and phosphatidylcholine synthesis by endosulfan in liver of rats: effect of quality of dietary proteins

Administration of endosulfan significantly increased microsomal protein, cytochrome P-450 content and the activity of aminopyrine N-demethylase. Effect of endosulfan and actinomycin D either alone or together on microsomal protein, cytochrome P-450, NADPH cytochrome c reductase, aniline hydroxylase, aminopyrine N-demethylase, phosphatidylcholine content, incorporation of 3H-choline and 14C-methionine were studied in rats given amino acid deficient and supplemented diets. Administration of endosulfan significantly increased the above parameters in both the dietary groups, whereas administration of actinomycin D did not have any effect in rats fed supplemented diets, however, significant decrease in the PC and the incorporation of choline and methionine into PC of rats fed deficient diet were observed. A positive correlation in the effect of endosulfan on hepatic mixed function oxidase activity and hepatic phosphatidylcholine is observed.     

Planning for alkali land reclamation under rainfall uncertainty

A chance-constrained linear programming model with rainfall as stochastic input has been developed to plan optimal land and water use in alkali soils under reclamation. The model is based on the water balance of a typical alkali catchment in the command area of the Western Jamuna Canal in Haryana (India). The zero-order decision rule has been used to obtain the deterministic equivalent of chance constraint and optimal solutions have been obtained for four levels of rainfall probability. Available water supplies at low rainfall probabilities were found to be inadequate to sustain the high cost reclamation technology. Exploitation of the full potential of agricultural land calls for the augmentation of available water supplies.     

Seasonal variation of indoor radon in dwellings of Malwa region, Punjab

Indoor radon measurements in 105 dwellings belonging to 21 villages of Muktsar and Ferozepur districts of Malwa region, Punjab, have been carried out, using LR-115 type II cellulose nitrate films in the bare mode. The annual average indoor radon value in the study area varies from 76.25 to 145.50 Bq m⁻³, which is well within the recommended action level [ICRP, 1993. Protection against radon at home and work. Annals of ICRP, ICRP Publication, p. 65]. Seasonal variation of indoor radon shows high values in winter and low values in summer. The winter/summer ratio of radon concentration has been computed for all 105 dwellings. The winter/summer ratio of indoor radon ranges from 0.84 to 1.89 with an average of 1.46. The indoor radon values obtained in the present investigation are more than the world average of 40 Bq m⁻³     

Bricks as historical record of heavy metals fallout: Study on copper accumulation in Agra soils since 1910

Peat, ice deposits and aquatic sediments, which have been used as a geochemical monitor of atmospheric heavy metal pollution until now, are open and dynamic systems and can be easily affected by climatic variations. In contrast, bricks, which are more compact, can act as a better geochemical monitor. Analysis of Cu, Cr, Ni, Pb and Zn in scores of soil and brick (baked/unbaked) samples, collected from a large area in and around a rapidly growing Indian city, Agra, reveals approximately similar concentrations in soils and bricks, thereby showing insignificant fractionation of these metals during brick making. Further, metals concentration in the core of bricks remains unaffected by any significant amount of acidic and alkaline rain. Thus, the feasibility of a novel role of bricks as a geochemical monitor of atmospheric heavy metal pollution has been tested. Utilizing this concept, an attempt has also been made to trace the history of atmospheric copper depositions in the soils of Agra during the last 100 years.     

Investigation on Temporal Variation in Methane Emission from Different Rice Cultivars under the Influence of Weeds

A study of temporal variation in methane efflux from the rice-fields indicated that weeds could modulate the CH4 emission by transporting atmospheric O2 more efficiently than rice plants to the rhizosphere, which suppressed CH4 formation in the oxic condition, inhibiting methanogenic activity. A more oxic environment in the sediment was reflected by the higher redox potential in the weed growing plots. Besides, cultivar differences in methane efflux might be attributed to various plant activities, more importantly root exudation, development of aerenchyma and the biomass. Peak emission of CH4 at the flowering stage in all the rice cultivars was associated with maximum extension of root mat, releasing exudates, which serve as carbon source for the methanogenic bacteria for CH4 formation.     

Dosimetric impact of natural terrestrial radioactivity on residents of lower Himalayas,India

Environmental Geochemistry and Health - A comprehensive radio-ecological evaluation of soil samples of Solan and Shimla districts of Himachal Pradesh has been carried out for risk and dose...     

Effect of iron on lipid peroxidation, and enzymatic and non-enzymatic antioxidants and bacoside-A content in medicinal plant Bacopa monnieri L

The effect of Fe was investigated in medicinally important plant, Bacopa monnieri L. and the response on malondialdehyde (MDA) content, superoxide dismutase (SOD), peroxidase (POD) and ascorbate peroxidase (APX) was found different in roots and leaves of the metal treated plants. Iron induced stress was observed as indicated by high level of lipid peroxidation, being more steep increase in leaves than roots. In roots, SOD activity was found to increase in metal treated plants except 80 and 160 microM at 72 h, whereas, it decreased in leaves except 10 and 40 microM after 48 h as compared to their respective controls. Among H2O2 eliminating enzymes, POD activity increased in roots, however, it decreased in leaves except at 10 and 40 microM Fe after 48 h as compared to control. At 24 and 48 h, APX activity and ascorbic acid content followed the similar trend and were found to increase in both parts of the metal treated plants as compared to their respective controls. The level of cysteine content in the roots increased at initial period of exposure; however, no marked change in its content was noticed in leaves. In both roots and leaves, non-protein thiol content was found to increase except at higher metal concentrations at 72 h. The data of proline content have shown significant (p<0.01) increase at 40 microM onwards in both part of the plants after 48 and 72 h. Correlation coefficient was evaluated between metal accumulations with various parameters and also between different antioxidant parameters with MDA. Since the level of bacoside-A (active constituent) content in metal treated plants increases, therefore, it is advisable to assess the biological activity of the plants before using for medicinal purposes, particularly in developing countries.     

Performance and diagnostic evaluation of ozone predictions by the Eta-Community Multiscale Air Quality Forecast System during the 2002 New England Air Quality Study

A real-time air quality forecasting system (Eta-Community Multiscale Air Quality [CMAQ] model suite) has been developed by linking the National Centers for Environmental Estimation Eta model to the U.S. Environmental Protection Agency (EPA) CMAQ model. This work presents results from the application of the Eta-CMAQ modeling system for forecasting ozone (O3) over the Northeastern United States during the 2002 New England Air Quality Study (NEAQS). Spatial and temporal performance of the Eta-CMAQ model for O3 was evaluated by comparison with observations from the EPA Air Quality System (AQS) network. This study also examines the ability of the model to simulate the processes governing the distributions of tropospheric O3 on the basis of the intensive datasets obtained at the four Atmospheric Investigation, Regional Modeling, Analysis, and Estimation (AIRMAP) and Harvard Forest (HF) surface sites. The episode analysis reveals that the model captured the buildup of O3 concentrations over the northeastern domain from August 11 and reproduced the spatial distributions of observed O3 very well for the daytime (8:00 p.m.) of both August 8 and 12 with most of normalized mean bias (NMB) within +/- 20%. The model reproduced 53.3% of the observed hourly O3 within a factor of 1.5 with NMB of 29.7% and normalized mean error of 46.9% at the 342 AQS sites. The comparison of modeled and observed lidar O3 vertical profiles shows that whereas the model reproduced the observed vertical structure, it tended to overestimate at higher altitude. The model reproduced 64-77% of observed NO2 photolysis rate values within a factor of 1.5 at the AIRMAP sites. At the HF site, comparison of modeled and observed O3/nitrogen oxide (NOx) ratios suggests that the site is mainly under strongly NOx-sensitive conditions (>53%). It was found that the modeled lower limits of the O3 production efficiency values (inferred from O3-CO correlation) are close to the observations.