Heterogeneous UV/Fenton degradation of bisphenol A catalyzed by synergistic effects of FeCo2O4/TiO2/GO

A new method for bisphenol A (BPA) degradation in aqueous solution was developed. The characteristics of BPA degradation in a heterogeneous ultraviolet (UV)/Fenton reaction catalyzed by FeCo₂O₄/TiO₂/graphite oxide (GO) were studied. The properties of the synthesized catalysts were characterized using scanning electron microscopy, X-ray diffraction, and vibrating sample magnetometry. FeCo₂O₄ and TiO₂ were grown as spherical shape, rough surface, and relatively uniform on the surface of GO (FeCo₂O₄/TiO₂/GO). Batch tests were conducted to evaluate the effects of the initial pH, FeCo₂O₄/TiO₂/GO dosage, and H₂O₂ concentration on BPA degradation. In a system with 0.5 g L⁻¹ of FeCo₂O₄/TiO₂/GO and 10 mmol L⁻¹ of H₂O₂, approximately 90 % of BPA (20 mg L⁻¹) was degraded within 240 min of UV irradiation at pH 6.0. The reused FeCo₂O₄/TiO₂/GO catalyst retained its activity after three cycles, which indicates that it is stable and reusable. The heterogeneous UV/Fenton reaction catalyzed by FeCo₂O₄/TiO₂/GO is a promising advanced oxidation technology for treating wastewater that contains BPA.

     

庐山不同森林植被类型土壤特性及其健康评价

土壤作为森林生态系统的一个重要因子,评价森林土壤健康状况对森林健康的维护经营以及森林系统功能的发挥具有重要意义。在系统调查和分析庐山8种森林植被类型土壤特性的基础上,评价指标分别从物种多样性以及不同的森林土壤特性中进行筛选,包括物种多样性系数、枯落物层厚度、腐殖质层厚度、土层厚度、容重、粘粒含量、有机质、p H值、阳离子交换量、全氮、水解氮、有效磷、速效钾、磷酸酶活性等指标,基于SPSS19.0软件对所获得数据进行差异性检验和相关分析,确定各项指标的权重,应用合适的土壤健康评分函数,将测得的指标值转换为对应指标的分值,最后通过加权综合法,计算其土壤健康指数,并对不同森林植被类型土壤健康状况进行评价。结果表明,8种森林植被类型下最终的土壤健康指数大小排序为:针阔混交林(0.78)常-落混交林(0.72)灌丛(0.69)常绿阔叶林(0.67)落叶阔叶林(0.64)竹林(0.59)马尾松林(0.53)黄山松林(0.46)。     

新区域主义视角下的管治尺度构建——以南京都市圈建设为例

在新区域主义的理论视角下,对南京都市圈的新区域实体和区域管治进行研究,指出南京都市圈是新区域主义在我国的一种表现形式。研究表明：①南京都市圈建设是从政府到管治过程,因为在决策中引入了非政府部门和私营部门的参与者;②南京都市圈建设也涉及到区域身份与发展愿景的构建,这是区域协调的起点;③在旅游和引资促销,以及交通网络建设上,南京都市圈内的城市合作不断加强。此外,南京都市圈的新区域主义不同于西方的市场主导的新区域主义。南京都市圈的新区域主义是由政府主导的,并有企业和非政府机构参与的新区域主义。研究指出,南京都市圈是在既有区域制度和政治地理上出现的新管治尺度,是一种新的区域管治模式。南京都市圈建设的有益经验将为和谐规划提供一些启迪。     

Continuous measurement of peroxyacetyl nitrate (PAN) in suburban and remote areas of western China

Knowledge on atmospheric abundance of peroxyacetyl nitrate (PAN) is important in assessing the severity of photochemical pollution, and for understanding chemical transformation of reactive odd nitrogen and its impact on the budget of tropospheric ozone (O₃). In summer 2006, continuous measurements of PAN were made using an automatic GC–ECD analyzer with an on-line calibrator at a suburban site of Lanzhou (LZ) and a remote site of Mt. Waliguan (WLG) in western China, with concurrent measurements of O₃, total reactive nitrogen (NO_y) and carbon monoxide (CO). At LZ, several photochemical episodes were observed during the study, and the average mixing ratio of PAN (plus or minus standard deviation) was 0.76 (±0.89) ppbv with the maximum value of 9.13 ppbv, compared to an average value of 0.44 (±0.16) ppbv at remote WLG. The PAN mixing ratios in LZ exhibited strong diurnal variations with a maximum at noon, while enhanced concentrations of PAN were observed in the evening and a minimum in the afternoon at WLG. The daily O₃ and PAN concentration maxima showed a strong correlation (r² = 0.91) in LZ, with a regression slope (PAN/O₃) of 0.091 ppbv ppbv^?1. At WLG, six well-identified pollution plumes (lasting 2–8 h) were observed with elevated concentrations of PAN (and other trace gases), and analysis of backward particle release simulation shows that the high-PAN events at WLG were mostly associated with the transport of air masses that had passed over LZ.     

摆管淋水试验装置的校准方法探讨

文中简述了摆管淋水试验装置的基本结构及其常见的校准方式,对其中的“摆角校准”这一技术难点提出了可行的解决方案并作了较详尽的说明分析。     

真空灭弧室导电回路产生的磁场环境对灭弧室短路开断的影响

设计良好的导电回路对真空断路器灭弧性能的提高有着重要的意义。本文首先从结构上分析了三种不同导电回路的优缺点,接着,分析了三种不同导电回路的电动斥力和吹弧磁场,为通过选择不同导电回路,触头直径和开距提高真空断路器灭弧性能提供方法和思路。     

阳离子染料废水治理技术

介绍了阳离子染料废水的特点,以及近年来阳离子染料废水的各种处理技术,并对阳离子染料废水处理技术的发展进行了展望,指出阳离子废水处理技术正朝着各种工艺优化组合的方向发展。     

热分解技术在修复多氯联苯污染土壤中的应用

针对我国土壤中PCBs的污染特点,介绍了一种修复土壤的热分解技术,并详述了该技术的工作流程、影响因素、处理效率等问题。最后对该技术的发展趋势进行了展望,并对其在推广过程中可能遇到的困难进行了分析。     

地下土壤渗滤系统处理农村生活污水应用研究

研究了地下土壤渗滤系统在农村生活污水处理中的应用,并详细地比较了面积分别为9,45,90 m2以及200 m2的处理系统在工程实际中出水水质的不同.实验结果表明,随着土地处理系统面积的增大,出水的各个水质指标(CODCr、BOD5、TP、NH3-N)相应变好.结合施工、运行及管理等方面的优点,推荐收集各户生活污水再集中建设土地处理系统,系统面积在90-300 m2之间.     

关于淮安市饮用水源地污染应急监测的思

回顾分析了淮安市饮用水源地污染事件的应急监测和处置方法,总结了应急监测及处置工作的经验教训和启示,对更好地驾驭今后可能发生的各种复杂的环境事件提供了帮助。