Flammability of heat transfer fluid aerosols produced by electrospray measured by laser diffraction analysis

Accidental release of pressurized high flash point heat transfer fluids can result in fire and explosion hazard scenarios in the process industry. An experimental investigation on ignition of aerosols of a heat transfer fluid is carried out, and characterization of aerosol and its ignition process by non-intrusive laser diffraction technique is reported. Propagation speed of the aerosol combustion flame front as analyzed from the laser diffraction measurement agrees with high-speed visual camera observation. Flammability of the aerosol, which is based on the chances of the global flame appearance in the aerosol, is mainly controlled by aerosol droplet size and the droplet volume concentration.     

Risk measures constituting a risk metrics which enables improved decision making: Value-at-Risk

In this work, a novel approach is proposed for expressing the risks of process plants consisting of a large number of scenarios, in the form of a risk metrics of leading indicators to prevent potential high profile industry accidents. The methodology includes: 1) risk estimation of a portfolio by CPQRA (or QRA), 2) monetization of the tangible risks with the inclusion of the lost time of production, 3) estimation of the maximum portfolio loss using Value-at-Risk approach, 4) inclusion of intangible risks using FN-curve and, 5) generation of F$-curve of tangible risks. The proposed methodology can particularly help in understanding the stakes at risk by performing the overall cost-benefit analysis, for identifying the most risky scenarios and identifying critical equipments to enable better risk-informed decision making in order to adopt appropriate risk mitigation measures. This work establishes the groundwork for developing measures for understanding and comparing the large number of risk values derived from QRA studies for large portfolios. It will aid in less subjective decision making as it enables the decision maker to choose the most preferred portfolio option among alternatives. Decisions made with the accurate understanding of the consequences of risks can significantly reduce potential work-related fatalities, property losses and save millions of dollars.     

Uncertainty aspects in process safety analysis

Uncertainties of input data as well as of simulation models used in process safety analysis (PSA) are key issues in the application of risk analysis results. Mostly, it is connected with an incomplete and uncertain identification of representative accident scenario (RAS) and other vague and ambiguous information required for the assessment of particular elements of risk, especially for determination of frequency as well as severity of the consequences of RAS. The authors discuss and present the sources and types of uncertainties encountered in PSA and also methods to deal with them. There are different approaches to improve such analysis including sensitivity analysis, expert method, statistics and fuzzy logic. Statistical approach uses probability distribution of the input data and fuzzy logic approach uses fuzzy sets. This paper undertakes the fuzzy approach and presents a proposal for fuzzy risk assessment. It consists of a combination of traditional part, where methods within the process hazard analysis (PHA) are used, and “fuzzy part”, applied quantitatively, where fuzzy logic system (FLS) is involved. It concerns frequency, severity of the consequences of RAS and risk evaluation. In addition, a new element called risk correction index (RCI) is introduced to take into account uncertainty concerned with the identification of RAS. The preliminary tests confirmed that the final results on risk index are more precisely and realistically determined.     

Melt Strength and Rheological Properties of Biodegradable Poly(Lactic Aacid) Modified via Alkyl Radical-Based Reactive Extrusion Processes

Poly(lactic acid) (PLA) has been modified using twin-screw reactive extrusion to improve its melt properties and crystallinity. In this work lauroyl peroxide was used as an alkyl free radical source, abstracting hydrogen atoms from the PLA backbone leading to branching and chain extension reactions. Once the linear viscoelastic region was determined for these polymers, changes in dynamic rheology (dynamic viscosity real and loss modulus) were measured. Gel permeation chromatography showed that the molecular weight and polydispersity increased to a maximum with the addition of 1.00 and 0.50?wt% peroxide, respectively. Low temperature ?? transitions in dynamical mechanical thermal traces gave further evidence that branching had also occurred. G?ttfert Rheotens measurements showed a three fold increase in melt strength due to both increased chain length and branching. Thermal analysis showed the level of crystallisation had decreased also possibly due to branching. Reductions in crystallinity and improved melt strength are known to be critical for film and foam formation.     

Modeling the population dynamics of cotton bollworm Helicoverpa armigera (Hübner) (Lepidoptera: Noctuidae) over a wide area in northern China

The cotton bollworm Helicoverpa armigera (Lepidoptera: Noctuidae) is one of the most serious crop pests in northern China, calling for accurate prediction of pest outbreaks and strategies for pest control. A computer model is developed to simulate the population dynamics of H. armigera over a wide area in northern China. The area considered covers 12 provinces where serious outbreaks of H. armigera have been observed. In this model, pest development is driven by local ambient temperature, and adults migrate long distances between regions and select preferred hosts for oviposition within a region. Six types of host including cotton, wheat, corn, peanut, soybean and a single category composed of all other minor hosts are considered in this model. Survival rates of eggs and larvae are based on life-table data, and simulated as a function of host type, host phenology and temperature. The incidence of diapause depends on temperature and photoperiod experienced during the larval stage. Survival rate of non-diapause pupae is a nonlinear function of rainfall, and overwinter survival rate is a nonlinear function of temperature. Insecticide is applied when population density exceeds the economic threshold on a host crop within a region. Comparisons of model output with light-trap data indicate that our model reflects the pest population dynamics over a wide area, and could potentially be used for testing novel pest control strategies in northern China.     

An approach for domino effect reduction based on optimal layouts

An approach to reduce the probability of producing a domino effect in process industry is developed in this work. It is assumed that optimal layouts should include appropriate analysis to reduce risk during the process design stage. The model developed for this approach combines the estimation of probability of damage due to overpressure, proposed by Mingguang and Juncheng (2008), and escalation threshold values defined by Cozzani, Gubinelli, and Salzano (2006). These equations are combined with other typical layout constraints as well as bounding the probability constraint, which has resulted in a highly non-linear MINLP problem. Solving a case study used by other authors provides evidence for reliability of the developed approach. In this way, layouts are designed to reduce the escalation probability yielding safe distributions.     

Key parametric analysis on designing an effective forced mitigation system for LNG spill emergency

Concerns over public safety and security of a potential liquefied natural gas (LNG) spill have promoted the need for continued improvement of safety measures for LNG facilities. The mitigation techniques have been recognized as one of the areas that require further investigation to determine the public safety impact of an LNG spill. Forced mitigation of LNG vapors using a water curtain system has been proven to be effective in reducing the vapor concentration by enhancing the dispersion. Currently, no engineering criteria for designing an effective water curtain system are available, mainly due to a lack of understanding of the complex droplet–vapor interaction. This work applies computational fluid dynamics (CFD) modeling to evaluate various key design parameters involved in the LNG forced mitigation using an upwards-oriented full-cone water spray. An LNG forced dispersion model based on a Eulerian–Lagrangian approach was applied to solve the physical interactions of the droplet–vapor system by taking into account the various effects of the droplets (discrete phase) on the air–vapor mixture (continuous phase). The effects of different droplet sizes, droplet temperatures, air entrainment rates, and installation configurations of water spray applications on LNG vapor behavior are investigated. Finally, the potential of applying CFD modeling in providing guidance for setting up the design criteria for an effective forced mitigation system as an integrated safety element for LNG facilities is discussed.     

Hovering guards of the stingless bee <Emphasis Type="Italic">Tetragonisca angustula</Emphasis> increase colony defensive perimeter as shown by intra- and inter-specific comparisons

Social insects need to defend their nest against robbery, parasitism and predation. The stingless bee Tetragonisca angustula is unique in that it has guards that hover near the nest entrance in addition to guards that stand at the entrance. We tested both the general hypothesis that hovering guards increase the effectiveness with which flying intruders are detected and the specific hypothesis that hovering guards improve the detection of workers of the obligate robber bee, Lestrimellita limao. In an intraspecific study comparing colonies, we found a strong positive relationship between the number of hovering guards and the distance at which a dummy robber bee or L. limao worker, experimentally moved towards the nest entrance, was detected. These results were mirrored in an interspecific study showing that four species of stingless bees with similar population colonies but which lacked hovering guards, detected L. limao only at the nest entrance, in contrast to T. angustula. In addition, we found that a greater number of attacks by guards occurred when dummies were impregnated with citral, a major component of L. limao mandibular gland odour. Our results support the hypothesis that T. angustula hovering guards increase the detection perimeter for flying intruders, especially L. limao.     

Changes in landscape and vegetation of coastal dunes in northwest Europe: a review

In coastal dunes, landscape changes are a rule, rather than an exception. This paper gives an overview of changes in landscape and vegetation with a focus on the past century. The history of dunes is characterised by phases of sand drift, alternated with geomorphological stability. The historical development of dune woodland during these stable phases has been documented for sites all over Europe. Vegetation reconstructions of historical open dune habitats however is very difficult due to limited preservation of fossil remains. People have drastically altered coastal dune landscapes through centuries of exploitation and more recently development of the coast. Historical land use has generally pushed vegetation back into a semi-natural state. During roughly the past century a tendency of increasing fixation and succession is observed on coastal dunes throughout northwest Europe. Six causes of change are discussed. 1) Changes in land use, mainly abandonment of agricultural practices, have led to the development of late successional stages such as scrub and woodland. 2) Crashing rabbit populations due to myxomatosis in the 1950s caused vigorous grass growth and probably stimulated scrub development. 3) A general tendency of landscape fixation is observed due to both natural and anthropogenic factors. 4) Eutrophication, mainly due to atmospheric nitrogen deposition is clearly linked to grass encroachment on acidic but also on some calcareous dunes. 5) The impact of climate change on vegetation is still unclear but probably lengthening of growing season and maybe enhanced CO₂ concentrations have led to an acceleration of succession. 6) A general anthropogenisation of the landscape occurs with rapid spread of non-native species as an important consequence. The reconstruction of a natural reference landscape is considered largely unattainable because of irreversible changes and the long tradition of human impact, in many cases since the development of the dunes. Two contradictory elements need reconciliation. First, the general acceleration of succession and scrub and woodland development in particular is partly caused by a decreased anthropogenic interference in the landscape and deserves more appreciation. Second, most biodiversity values are largely linked to open, early succession dune habitats and are threatened by the same tendency. Apart from internal nature management, in which grazing plays an important part, re-mobilisation of stable, senescent dunes is an important challenge for dune management.