Effect of pretreatment techniques on food waste solubilization and biogas production during thermophilic batch anaerobic digestion

The purpose of this study was to optimize the alkaline, ultrasonication, and thermal pretreatment in order to enhance the solubilization of food waste (FW) for the production of volatile fatty acids, hydrogen, and methane in thermophilic batch anaerobic digestion. Initially, the effect of pretreatment techniques in the acidogenic phase was studied, and the optimal combinations of different conditions were determined. It was found that each pretreatment technique affected food waste solubilization differently. Alkaline pretreatment increased hydrogen yield in the acidogenic sludge by four times over control. COD solubilization was increased by 47 % when FW pre-heated at 130 °C for 60 min. Ultrasonication at 20 kHz and 45 min reduced processing time to 38 h from the 60–80 h needed in normal operation. Response surface methodology (RSM) was used to optimize a combination of alkaline, ultrasonication, and thermal pretreatment. Optimized conditions were applied to methanogenic single-stage thermophilic AD process, and their impact on biogas production was monitored. Results showed that FW heated at 130 °C for 50 min geminates biogas production compared to control experiment. In conclusion, a short thermal pretreatment regime could significant affect biogas production in single-stage thermophilic AD.     

Stress in the workplace: a comparison of gender and occupations

Stressful incidents at work were examined using an open‐ended technique for three different occupations: clerical workers, university professors and sales associates. The study revealed both similarities and differences in stressors and coping techniques reported across occupations. Interpersonal conflict, work overload and time wasters were common across all occupations. Lack of control and work overload were reported as major stressors by the clerical group and interpersonal conflict as a major stressor by the academic and sales groups. Gender differences were also found. Copyright © 1999 John Wiley & Sons, Ltd.     

Thermodynamic analysis of in situ gasification-chemical looping combustion (<Emphasis Type="Italic">i</Emphasis>G-CLC) of Indian coal

Chemical looping combustion (CLC) is an inherent CO₂ capture technology. It is gaining much interest in recent years mainly because of its potential in addressing climate change problems associated with CO₂ emissions from power plants. A typical chemical looping combustion unit consists of two reactors—fuel reactor, where oxidation of fuel occurs with the help of oxygen available in the form of metal oxides and, air reactor, where the reduced metal oxides are regenerated by the inflow of air. These oxides are then sent back to the fuel reactor and the cycle continues. The product gas from the fuel reactor contains a concentrated stream of CO₂ which can be readily stored in various forms or used for any other applications. This unique feature of inherent CO₂ capture makes the technology more promising to combat the global climate changes. Various types of CLC units have been discussed in literature depending on the type of fuel burnt. For solid fuel combustion three main varieties of CLC units exist namely: syngas CLC, in situ gasification-CLC (iG-CLC) and chemical looping with oxygen uncoupling (CLOU). In this paper, theoretical studies on the iG-CLC unit burning Indian coal are presented. Gibbs free energy minimization technique is employed to determine the composition of flue gas and oxygen carrier of an iG-CLC unit using Fe₂O₃, CuO, and mixed carrier—Fe₂O₃ and CuO as oxygen carriers. The effect of temperature, suitability of oxygen carriers, and oxygen carrier circulation rate on the performance of a CLC unit for Indian coal are studied and presented. These results are analyzed in order to foresee the operating conditions at which economic and smooth operation of the unit is expected.     

Biology of marine fouling in Mangalore waters

A comprehensive study of the fouling organisms encountered at the New Mangalore Port at Panambur and the Fish Landing Jetty on the Nethravati-Gurpur estuary near the old Mangalore Port, India, was made. Barnacles, oysters, bryozoans, polychaetes and hydroids are the dominant groups of foulers encountered in this region. Barnacles are by far the most important foulers. Distinct seasonal abundance in settlement was noticed in the different groups. The major peak settlement of barnacles occurs in November and December. Continuous settlement of this group in the harbour indicates the presence of larvae throughout the year in the marine locality. The absence of freshly settled spat in the estuarine locality shows that these larvae do not foul structures in the Fish Landing Jetty during the monsson period. The pattern of oyster settlement indicates that the spat of Crassostrea madrasensis and c. cucullata settle during January, March, May and October in this region. This group remains in the fouling community throughout the year. Only typical marine bryozoans are harboured in abundance in the fouling community. Polychaetes occur in great numbers during April and December.The differences in the quality and quantity of the fouling communities are controlled by their breeding periodicity,seasonal fluctuations in the hydrographical conditions, and the species composition of the sedentary community of this region.     

探究性教学在大学语文课程中的运用——以讲授苏轼《水调歌头》一课为例

《大学语文》作为高职高专的一门公共基础课,因其丰富的人文内蕴、情感价值和审美趣味而承担了进一步提高大学生人文素质、增进文化修养的功能,从而培养大学生具有深厚人文精神的理想人格。在《大学语文》教学活动中开展探究性教学,既是教育改革全面实施素质教育的客观要求,也是大学生自我提升的内在需要。以讲授苏轼的《水调歌头·明月几时有》一课为例,阐述如何在高职高专《大学语文》课程的教学活动中引导和组织学生开展探究性教学。     

Electrokinetic extraction of lead from kaolinites: I. Numerical modeling

Experimental results obtained to date indicate electrokinetic extraction is viable in removing organic and inorganic contaminants from fine-grained soils. However, electrochemical reactions and soil-contaminant interactions that occur simultaneously may enhance or reduce the removal efficiency of the hazardous waste site remediation process. Many sites worldwide are contaminated by lead and its compounds, resulting in lead poisoning. It is difficult to remove lead from fine-grained soil because of the existence of a great variety of lead complexes and their pH-dependent and reversible physicochemical properties. The feasibility of electrokinetic extraction of lead from kaolinites is investigated theoretically, numerically, and experimentally in this study. This is the first paper of two companion papers presenting the theoretical and numerical modeling of the transport of lead species, and electrochemical reactions and soil-contaminant interactions occurring during the electrokinetic extraction process. The comparison between simulation results and experimental results is presented in the second paper.     

Dissipation of 14C carbaryl and quinalphos in soil under a groundnut crop (Arachis hypogaea L.) in semi-arid India

The dissipation of 14C carbaryl in undisturbed soil cores, and of quinalphos (25EC and 20AF) after seed and soil treatments, was investigated under field use conditions, in a semi-arid groundnut field. Residues were analyzed by TLC and HPLC and additionally by LSC for 14C carbaryl. The harvested seed kernels were also tested for the presence of insecticide residues. The movement of carbaryl was limited to 15 cm depth in the loamy sand of Jaipur and was detected till 120 days (DT50 of 14.93 days) after application. Bound residues and 1-naphthol had a DT50 of 11.45 and 13.68 days, respectively. Irrespective of the three types of soil samples investigated, the principal metabolite formed on seed and soil treatments with quinalphos, was 2-hydroxyquinoxaline. With seed treatment, a thiol metabolite of quinalphos was also detected. Higher yields of groundnut were realized with quinalphos treatments in comparison to those from control. Post-harvest, no pesticide residues were found in seeds.     

Cellular uptake and mutagenic potential of metal oxide nanoparticles in bacterial cells

Extensive production and consumption of nanomaterials such as ZnO and TiO₂ has increased their release and disposal into the environment. The accumulation of nanoparticles (NPs) in ecosystem is likely to pose threat to non-specific targets such as bacteria. The present study explored the effect of ZnO and TiO₂ NPs in a model bacterium, Salmonella typhimurium. The uptake of ZnO and TiO₂ bare NPs in nano range without agglomeration was observed in S. typhimurium. TEM analysis demonstrated the internalization and uniform distribution of NPs inside the cells. Flow cytometry data also demonstrates that both ZnO and TiO₂ NPs were significantly internalized in the S. typhimurium cells in a concentration dependent manner. A significant increase in uptake was observed in the S. typhimurium treated even with 8 and 80 ng mL⁻¹ of ZnO and TiO₂ NPs with S9 after 60 min, possibly the formation of micelles or protein coat facilitated entry of NPs. These NPs exhibited weak mutagenic potential in S. typhimurium strains TA98, TA1537 and Escherichia coli (WP2uvrA) of Ames test underscoring the possible carcinogenic potential similar to certain mutagenic chemicals. Our study reiterates the need for re-evaluating environmental toxicity of ZnO and TiO₂ NPs presumably considered safe in environment.