制定区域大气环境总量控制方案的技术方法

提出了区域大气环境总量控制方案制定的技术路线和主要技术，即污染物的基础允许排放量，平权允许排放量和优化允许排放量的确定方法，以上海市某加工区ＳＯ２总量控制方案作了实例分析。     

玉米/空心菜间作降低土壤及蔬菜中硝酸盐含量的研究

菜地中过量的施用氮肥使土壤剖面中累积了大量的硝酸盐，会增加地下水的硝酸盐污染的风险．选择了深根系的玉米和浅根系的空心菜间作来验证深根系作物和浅根系作物问作将降低土壤剖面硝酸盐累积的假说．结果表明，间作有降低蔬菜地上部硝酸盐浓度和土壤剖面硝酸盐残留量的趋势；与单作种植相比，间作玉米的产量有显著增加，间作空心菜的产量没有显著降低；与单作玉米和空心菜相比，问作五米的根系表层分布较多，间作空心菜的根长密度有所降低．这为降低土壤剖面及蔬菜中的硝酸盐累积提供了新的途径。     

有机─无机复混肥的性质与肥效研究

有机—无机复混肥（以下简称有机复肥）是由单一的Ｎ、Ｐ、Ｋ化肥加入一定量的优质有机物质经造粒制成．颗粒直径大部分＞３ｍｍ。其性质：在水中比等氮、磷、钾量的无机复肥溶解快，不溶物少，氮的释放量大，密封条件下氨的挥发和在土壤中被水淋洗后氮的损失量均小。对水稻的增产效果比等量的氮、磷、钾单一化肥明显；对玉米的增产效果与进口复肥的相比，若两者的施用量相等，则其产量相当。     

部分氮杂环类化合物的遗传毒性及其QSAR研究

本文利用蚕豆细胞微核试验评价了１０种氮杂环类化合物的遗传毒性，一化合物的最低未占据轨道能Ｅｌｕｍｏ、分子的量负的原子净电荷ｑ建立了较好的相关方程：ＭＮ＝－２．９６（１．１４）＋４．９３（０．４８）Ｅｌｕｍｏ＋１３．６８（２．７２）ｑ＾－Ｒ＾２＝０．９４ ＳＥ＝０．７１ Ｆ＝５３．９２ Ｐ〈０．０００５推测此类化合物的至于致毒机制可能是它们作为电荷给予体和氢键予体作用于生物受体而引起的突变。     

大气中硝酸和颗粒物硝酸盐的测定

研究了用扩散管差分法和多种叠滤膜法测量大气中粒物硝酸盐和气体硝酸，扩散管差分法可以测量颗粒物硝酸盐和气体硝酸，避免了采样时颗粒物硝酸盐的人为损失。Ｆｌｏｕｒｏｐｏｒｅ聚四氟乙烯膜等惰性膜也可以采集颗粒物硝酸盐，其后的ＮａＣｌ浸渍膜采集硝酸，而玻璃纤维膜几乎同时采集了颗粒物硝酸盐和硝酸。     

采用微机控制气相色谱法在野外进行稻田甲烷排放率的连续观测

介绍一套稻田甲烷排放率的野外全自动观测系统。该系统采用微机控制、气相色谱法，在供电正常的情况下，实现了稻田甲烷样品的自动采集和分析，同时配有八个温度传感器，以测量空气、水及土壤的温度。温度和甲烷测定数据由微机自动贮存，可长期连续工作，无需值守。本系统对稻田甲烷测量的标准偏差为２４５μＶ·Ｓ（峰面积），变异系数为１．１８％（ｎ＝５）。若将色谱条件做适当改变，即可测量其它微量气体。     

大理苍山洱海自然保护区旅游与环境可持续发展规划的研究

苍山洱海是国家级自然保护区，同时又是国家级风景名胜区，由于旅游业的开展而引发的环境、生态问题日趋突出。针对客观实际，在保护和开发并举的原则下，对该区域的旅游区、旅游模式等进行了规划，提出了旅游区域的环境保护指标、旅游容量，同时制定了相应的管理措施     

水样品中重碳酸根离子排斥色谱法研究

本文研究了用离子排斥色谱法分析了水样品中重碳酸根的最佳色谱条件，分离方式和流动相的选择，样品溶液ｐＨ值与峰高的关系，实验结果显示，该方法具有简便，用样量少，灵敏度高于和干扰少等优点，测量下限为０．１２μｇ．ｍｌ＾－１ＨＣＯ＾－３在１－１０μｇ．ｍ＾－１和１０－１００μｇ．ｍｌ＾－１浓度范围内，ＨＣＯ３浓度与峰高的线性相关系数在０．９９５以上，该方法用于自来水和油田水样品的分析获得较好的结果。     

Bioaccumulation and elimination of avermectin B1a in the earthworms (Eisenia fetida)

The acute toxicity, bioaccumulation, and elimination of avermectin B1a (AVM B1a) in earthworm (Eisenia fetida) were investigated in different exposure systems. The LC50 of AVM B1a on earthworms were 24.1 mg/kg and 17.1 mg/kg, respectively, for 7 and 14 days in artificial soil. The LC50 tested by the filter paper for 2 days was 4.63 microg/cm2. The earthworms were cultivated in artificial soil containing 0.6 mg/kg and 3.0 mg/kg AVM B1a, respectively for bioaccumulation experiments. The AVM B1a residues in earthworms were determined with HPLC-fluorescence method. The results showed that AVM B1a was taken up from the concentrated artificial soil by the earthworms and the steady-state levels were reached after 9-18 days of exposure. On the 18th day, the final concentrations of AVM B1a in the earthworms treated with two different dosages were 107 ng/g and 165 ng/g, respectively; there were not significantly accumulation. About 80.0% and 94.8% of the accumulated AVM B1a were eliminated respectively in two groups within 1 day after they were exposed to AVM B1a-free soil, but a trace amount of AVM B1a was found for a relative long time in earthworms.     

Estimation of apparent rate coefficients for phenanthrene and pentachlorophenol interacting with sediments

To gain information on organic pollutants in water-sediment systems, a compartment model was applied to study the sorption course of phenanthrene and pentachlorophenol (PCP) in sediments. The model described the time-dependent interaction of phenanthrene and PCP with operationally defined reversible and irreversible (or slowly reversible) sediment fractions. The interactions between these fractions were described using first order differential equations. By fitting the models to the experimental data, apparent rate constants were obtained using numerical optimization software. The model optimizations showed that the amount of reversible phase increased rapidly in the first 10 d with the sorption time, then decreased after 10 d, while the amount of irreversible phase increased in the total sorption course. That suggested the mass transport between reversible phase and irreversible phase. The extraction efficiency with hot methanol ranged from 36% to 103% for phenanthrene and from 65% to 101% for PCP, with the trend of decreasing with sorption time.