海洋微生物胞外分泌物(EPS)对船用结构钢腐蚀行为的影响

目的研究微生物活性与船用钢DH32腐蚀行为之间的关系,并通过胞外分泌物的提取,研究分泌物浓度对材料腐蚀性能的影响。方法通过傅里叶红外光谱(FT–IR)分析胞外分泌物的组成,通过电感耦合等离子体发射光谱仪(ICP-OES)分析金属离子的含量,并使用用原子力显微镜(AFM)观测去除腐蚀产物后的表面形貌。结果通过电化学阻抗谱的拟合分析,短期内,EPS通过阻碍溶解氧的扩散抑制腐蚀速度,EPS浓度越高,效果越好,即实验初期试样腐蚀的速度与EPS浓度成反比。随着时间的延长,EPS浓度低的溶液中,其EPS络合金属离子的能力很快达到饱和,所以尽管其络合行为能促进试样的阳极溶解,但影响作用有限,此时起到主要影响的还是EPS抑制溶解氧扩散。对于浓度高的EPS溶液,其过量的EPS会促进EPS的官能团与材料表面更多的Fe~(2+)/Fe~(3+)离子键合,使得沉积的EPS保护层变得疏松失去隔离溶解氧的作用,进而加速试样腐蚀。结论海洋微生物胞外分泌物对船用钢腐蚀行为的影响与胞外分泌物的结构与浓度有关,随着浓度升高,EPS从抑制腐蚀变为加速腐蚀。     

Effect of sulfur source on photocatalytic degradation performance of CdS/MoS2 prepared with one-step hydrothermal synthesis

Cd S/Mo S_2,an extremely efficient photocatalyst,has been extensively used in hydrogen photoproduction and pollutant degradation.Cd S/Mo S_2can be synthesized by a facile one-step hydrothermal process.However,the effect of the sulfur source on the synthesis of Cd S/Mo S_2via one-step hydrothermal methods has seldom been investigated.We report herein a series of one-step hydrothermal preparations of Cd S/Mo S_2using three different sulfur sources:thioacetamide,L-cysteine,and thiourea.The results revealed that the sulfur source strongly affected the crystallization,morphology,elemental composition and ultraviolet(UV)–visible-light-absorption ability of the Cd S/Mo S_2.Among the investigated sulfur sources,thioacetamide provided the highest visible-light absorption ability for Cd S/Mo S_2,with the smallest average particle size and largest surface area,resulting in the highest efficiency in Methylene Blue(MB)degradation.The photocatalytic activity of Cd S/Mo S_2synthesized from the three sulfur sources can be arranged in the following order:thioacetamideL-cysteinethiourea.The reaction rate constants(k)for thioacetamide,L-cysteine,and thiourea were estimated to be 0.0197,0.0140,and 0.0084 min~(-1),respectively.However,thioacetamide may be limited in practical application in terms of its price and toxicity,while L-cysteine is relatively economical,less toxic and exhibited good photocatalytic degradation performance toward MB.     

Comparative study of carbonic anhydrase activity in waters among different geological eco-environments of Yangtze River basin and its ecological significance

This study provides the presence of carbonic anhydrase(CA) activity in waters of the Yangtze River basin, China, as well as the correlation of CA activity with HCO-3 concentration and CO_2 sink flux. Different degrees of CA activity could be detected in almost all of the water samples from different geological eco-environments in all four seasons. The CA activity of water samples from karst areas was significantly higher than from non-karst areas(PP3-concentration(r = 0.672, P2 sink flux(r = 0.602, P = 0.076) in karst areas. This suggests that CA in waters might have a promoting effect on carbon sinks for atmospheric CO_2 in karst river basins. In conditions of similar geological type, higher CA activity was generally detected in water samples taken from areas that exhibited better eco-environments, implying that the CA activity index of waters could be used as an indicator for monitoring ecological environments and protection of river basins. These findings suggest that the role of CA in waters in the karst carbon sink potential of river basins is worthy of further in-depth studies.     

Occupational exposure assessment of phthalate esters in indoor and outdoor microenvironments

Phthalate esters(PAEs) are widely used as plasticizers in consumer products. PAEs are a group of environmental hormone which disrupts human and animals' endocrine systems. Different occupational groups are exposed to various levels of PAEs. In the present study, four typical occupational groups were chosen, including doctors, college teachers, college students, and drivers who worked in public traffic system. In order to understand the exposure levels to PAEs via inhalation, air samples were collected from multiple microenvironments including indoor and outdoor in Hangzhou to measure the gas and particle concentrations of six PAEs, together with time spent in different microenvironments of these four groups. A comprehensive PAEs exposure model was built to estimate the daily PAEs exposure through inhalation, oral and dermal pathways. The Monte Carlo simulation results show that doctors were exposed to the highest level of PAEs, and consequently had the highest health risk among these four occupational groups. In contrast, college students had the lowest health risk. By setting the exposure level of staying in residences as the baseline, doctors and drivers were two occupations exposed to high PAEs health risk. Di-(2-ethylhexyl) phthalate(DEHP) was the largest contributor among the six phthalates, posing moderate health risk(10-5–10-6) to every occupation. For traffic microenvironments alone, the total exposure levels for different transportation modes were in the descending order of busses, cars, cabs, tubes, motor bikes, and walking.     

Spatial and temporal variation of haze in China from 1961 to 2012

The purpose of this study is to analyze the climatic characteristics and long-term spatial and temporal variations of haze occurrence in China. The impact factors of haze trends are also discussed. Meteorological data from 1961 to 2012 and daily PM₁₀ concentrations from 2003 to 2012 were employed in this study. The results indicate that the annual-average hazy days at all stations have been increasing rapidly from 4 days in 1961 to 18 days in 2012. The maximum number of haze days occur in winter (41.1%) while the minimum occur in summer (10.4%). During 1961-2012, the high occurrence areas of haze shifted from central to south and east regions of China. The Beijing-Tianjin-Hebei (Jing-Jin-Ji) region, Shanxi, Shaanxi, and Henan Province are the high occurrence areas for haze, while the Yangtze River Delta (YRD) and the Pearl River Delta (PRD) have become regions with high haze occurrences in the last 25 years. Temperature and pressure are positively correlated with the number of haze days. However, wind, relative humidity, precipitation, and sunshine duration are negatively correlated with the number of haze days. The key meteorological factors affecting the formation and dissipation of haze vary for high and low altitudes, and are closely related to anthropogenic activities. In recent years, anthropogenic activities have played a more important role in haze occurrences compared with meteorological factors.     

Assessment of Potential Capability of Water Bamboo Leaves on the Adsorption Removal Efficiency of Cationic Dye from Aqueous Solutions

Removal of toxic pollutants from water and wastewater is becoming an important process with the increase of industrial activities. The present study focused on assessing the suitability and efficiency of water bamboo leaves (WBL) for the removal of cationic dye from aqueous solutions. The effect of different variables in the batch method including solution pH (2–12), initial dye concentration (50–250 mg L^?1), adsorbent dose (0.05–0.30 g), contact time (5–180 min) and temperature (283–333 K) on the dye removal was investigated. The adsorption kinetics was discussed in view of four kinetics models. The results showed that the pseudo-second-order kinetics model described dye adsorption on WBL very well. The experimental equilibrium data were also tested by four isotherm models. It was found that adsorption of dye on WBL fitted well with the Langmuir isotherm model, implying the binding energy on the whole surface of the adsorbent was uniform and the dye molecules onto the surface of the adsorbent were monolayer coverage. Calculation of various thermodynamic parameters of the adsorption process indicated feasibility and exothermic nature of dye adsorption.     

规模化畜禽养殖业零排放模式探究

针对中国畜禽养殖业污染日益严重的现状,在分析现阶段中国规模化畜禽养殖业污染治理现状的基础上,提出运用循环经济的理论,因地制宜的采取污染物减排措施.分别从废水、粪便资源化利用以及病死猪的无害化处理三个角度分析了规模化畜禽养殖业的零排放模式,加快推进了生态环境治理体系和治理能力的现代化,从而实现资源整合,提高畜禽养殖废弃物处理设备的利用效率,将污染物变成可再生的资源,为规模化畜禽养殖业污染物处理实现零排放及循环利用提供参考.     

关于绿色建筑体系与低碳经济的探讨

针对绿色建筑体系与低碳经济的探讨问题,介绍了什么是绿色建筑,提出了绿色建筑是中国低碳经济建设的必然要求,探讨了绿色建筑的发展,主要包括:国外某些国家绿色建筑的发展和中国绿色建筑的发展,提出了绿色建筑的认识误区,主要包括绿色并不等于高价格和高成本、绿色建筑不仅局限于新建建筑和建筑节能不只是政府的职责,总结出中国绿色建筑的推广与运用,主要是研究和推广符合中国国情的绿色建筑、大力推广“绿色建筑”的标识和中国绿色建筑推广的实例.     

农用地土壤环境分类管理研究

通过分析国内外农用地土壤环境分类管理经验,结合我国土壤环境质量状况,以土壤环境风险管控为主线,将农用地土壤分为优先保护类、安全利用类和严格管控类3个类别,并提出相应的分类管理措施,保障农产品质量安全和人体健康。