全文获取类型
收费全文 | 2539篇 |
免费 | 80篇 |
国内免费 | 881篇 |
专业分类
安全科学 | 188篇 |
废物处理 | 148篇 |
环保管理 | 204篇 |
综合类 | 1276篇 |
基础理论 | 441篇 |
污染及防治 | 901篇 |
评价与监测 | 123篇 |
社会与环境 | 94篇 |
灾害及防治 | 125篇 |
出版年
2024年 | 1篇 |
2023年 | 42篇 |
2022年 | 123篇 |
2021年 | 94篇 |
2020年 | 80篇 |
2019年 | 89篇 |
2018年 | 77篇 |
2017年 | 108篇 |
2016年 | 111篇 |
2015年 | 146篇 |
2014年 | 222篇 |
2013年 | 269篇 |
2012年 | 198篇 |
2011年 | 213篇 |
2010年 | 193篇 |
2009年 | 170篇 |
2008年 | 164篇 |
2007年 | 128篇 |
2006年 | 148篇 |
2005年 | 102篇 |
2004年 | 89篇 |
2003年 | 77篇 |
2002年 | 86篇 |
2001年 | 112篇 |
2000年 | 74篇 |
1999年 | 72篇 |
1998年 | 72篇 |
1997年 | 51篇 |
1996年 | 39篇 |
1995年 | 36篇 |
1994年 | 30篇 |
1993年 | 21篇 |
1992年 | 19篇 |
1991年 | 7篇 |
1990年 | 14篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 1篇 |
排序方式: 共有3500条查询结果,搜索用时 844 毫秒
371.
372.
Location and migration of cations in Cu(2+)-adsorbed montmorillonite 总被引:10,自引:0,他引:10
Locations of Cu2+ ion in Cu(2+)-adsorbed montmorillonite have been studied by electron paramagnetic resonance (EPR), supplemented by X-ray diffraction (XRD) and differential thermal analysis (DTA). In the EPR spectra of Cu(2+)-adsorbed montmorillonite, three signals, corresponding to Cu2+ ion, have been simultaneously recorded. Some Cu2+ ions seemed to replace the original interlayer metal cations and some entered into the hexagonal cavities. A small fraction of Cu2+ ions penetrated into the octahedral vacancies. There were two ways for the adsorption of Cu2+ ion by montmorillonite--exchangeable and specific. On heating, the hydrated Cu2+ ion in the interlayer loses the coordinating water and then enters into the hexagonal cavities. When the heating temperature further increased, dehydroxylation occurs, which facilitates Cu2+ ion in the hexagonal cavities to penetrate into the octahedral vacancies. 相似文献
373.
河豚毒素检测技术研究进展 总被引:2,自引:0,他引:2
对检测河豚毒素的主要方法包括生物检测方法、理化检测方法、免疫学方法、传感器方法进行了介绍,并对目前检测方法的优缺点进行比较分析。小鼠测定法是河豚毒素检测的标准方法;理化检测法方法准确,但是对设备要求高,前处理严格;免疫学方法费用较高;传感器方法是新方法,还有待进一步规范。各种检测方法都有其优缺点,河豚毒素检测时应根据要求选择方法。 相似文献
374.
Yi H. Liu Chun M. Wang Yi R. Guo Xiao Liang Wenjun Gui Guo N. Zhu 《Journal of environmental science and health. Part. B》2013,48(6):547-556
A heterologous indirect enzyme-linked immunosorbent assay (ELISA) was developed, which was based on monoclonal antibody (Mab) to determine parathion residue in agricultural and environmental samples. Eight Mabs were produced by introducing the heterologous indirect ELISA into the screening procedure. It was shown that these Mabs had more broad-reactivity with twenty competitors than that of 5H7 (Mab produced by homologous screening). So it became much easier using these new Mabs to develop heterologous immunoassays. In addition, all the developed heterologous ELISAs could be used to determine parathion residue in semiquantitative or quantitative level, and their detection limitation (LOD) was around 2 ng/mL. Compared with the previous heterologous ELISA (hapten 11/5H7) with IC50 of 13.3 ng/mL, a better heterologous ELISA (hapten 11/1E1) was obtained with IC50 of 3.8 ng/mL, which improved the sensitivity 3.5 times. Finally, the latter was applied to parathion residue determination in spiked agricultural and environmental samples without extraction or cleanup. The average recoveries of parathion added to water, soil, cucumber, Chinese cabbage and carrot were between 80.4 % and 111.8 %. The LOD for water and soil samples was 5 ng/mL, and the LOD for cucumber, rice and corn samples was 10 ng/mL. 相似文献
375.
分析了工程建设过程中常见的人为失误,以及人为失误产生的根源,从技术和管理两方面探讨了人为失误的预防和控制措施,以期达到有效管控事件发生,确保工程建设过程安全的目的. 相似文献
376.
In this study, an inexact fuzzy chance-constrained two-stage mixed-integer linear programming (IFCTIP) approach is proposed for supporting long-term planning of waste-management systems under multiple uncertainties in the City of Regina, Canada. The method improves upon the existing inexact two-stage programming and mixed-integer linear programming techniques by incorporating uncertainties expressed as multiple uncertainties of intervals and dual probability distributions within a general optimization framework. The developed method can provide an effective linkage between the predefined environmental policies and the associated economic implications. Four special characteristics of the proposed method make it unique compared with other optimization techniques that deal with uncertainties. Firstly, it provides a linkage to predefined policies that have to be respected when a modeling effort is undertaken; secondly, it is useful for tackling uncertainties presented as intervals, probabilities, fuzzy sets and their incorporation; thirdly, it facilitates dynamic analysis for decisions of facility-expansion planning and waste-flow allocation within a multi-facility, multi-period, multi-level, and multi-option context; fourthly, the penalties are exercised with recourse against any infeasibility, which permits in-depth analyses of various policy scenarios that are associated with different levels of economic consequences when the promised solid waste-generation rates are violated. In a companion paper, the developed method is applied to a real case for the long-term planning of waste management in the City of Regina, Canada. 相似文献
377.
378.
N Ahmad G Bugueno L Guo R Marolt 《Journal of environmental science and health. Part. B》1999,34(5):829-848
A method is described for the determination of organochlorine and organophosphate pesticide residues in fruits, vegetables and sediments. The concentrated solvent extract was sealed in a polymeric membrane tube, dialysed in cyclohexane and the solvent replaced with hexane. The organophosphates were analysed on a specific thermionic detector without further clean-up. For the organochlorine pesticides the extract was eluted through 3 g of alumina and analysed on GC/ECD. The clean-up for sediment extract was carried out on a 10 g alumina column with 100 mL hexane containing 5% acetone and the eluate was concentrated to 5 mL. The detection limit for organophosphates on a 40 g sample and a final volume of 10 mL was on the average 0.01 mg/kg. The detection limit for organochlorine pesticides, with the final volume of 25 mL, was 0.005 mg/kg for all pesticides except for p,p'-DDT and endosulfan sulphate, which was 0.01 mg/kg. The detection limit for organochlorine pesticides in sediment, with the final volume of 2 mL, was less than 1 microgram/kg and for organophosphate pesticides less than 10 micrograms/kg when the final volume was made to 0.5 mL. At the detection limits the method produced a very high coefficient of variation for both organochlorine and organophosphate pesticides. 相似文献
379.
380.
Lianghu Su Guangzhai Guo Xinlong Shi Minyu Zuo Dongjie Niu Aihua Zhao Youcai Zhao 《Waste management (New York, N.Y.)》2013,33(6):1411-1417
Co-disposal of refuse with municipal solid waste incinerator (MSWI) bottom ash (IBA) either multi-layered as landfill cover or mixed with refuse could pose additional risk to the environment because of enhanced leaching of heavy metals, especially Cu. This study applied short-term accelerated weathering to IBA, and monitored the mineralogical and chemical properties of IBA during the weathering process. Cu extractability of the weathered IBA was then evaluated using standard leaching protocols (i.e. SPLP and TCLP) and co-disposal leaching procedure. The results showed that weathering had little or no beneficial effect on Cu leaching in SPLP and TCLP, which can be explained by the adsorption and complexation of Cu with DOM. However, the Cu leaching of weathered IBA was reduced significantly when situated in fresh simulated landfill leachate. This was attributed to weakening Cu complexation with fulvic acid or hydrophilic fractions and/or intensifying Cu absorption to neoformed hydr(oxide) minerals in weathered IBA. The amount of total leaching Cu and Cu in free or labile complex fraction (the fraction with the highest mobility and bio-toxicity) of the 408-h weathered IBA were remarkably decreased by 86.3% and 97.6% in the 15-day co-disposal leaching test. Accelerated weathering of IBA may be an effective pretreatment method to decrease Cu leaching prior to its co-disposal with refuse. 相似文献