Fate of heavy metals and radioactive metals in gasification of sewage sludge

The fates of radioactive cadmium, strontium, cesium, cobalt, arsenic, mercury, zinc, and copper spiked into sewage sludge were determined when the sludge was gasified by a process that maximizes production of char from the sludge (ChemChar process). For the most part the metals were retained in the char product in the gasifier. Small, but measurable quantities of arsenic were mobilized by gasification and slightly more than 1% of the arsenic was detected in the effluent gas. Mercury was largely mobilized from the solids in the gasifier, but most of the mercury was retained in a filter composed of char prepared from the sludge. The small amounts of mercury leaving the gasification system were found to be associated with an aerosol product generated during gasification. The metals retained in the char product of gasification were only partially leachable with 50% concentrated nitric acid.     

SALT PICKUP BY OVERLAND FLOW IN THE PRICE RIVER BASIN,UTAH1

ABSTRACT: This study emphasized a field investigation of salt release to overland flow from Mancos shale lands of the Price River Basin, Utah. Although a high degree of natural variation existed in the data, which precluded the separation of factors affecting diffuse salt loading that occurs during overland flow, a simplistic nonpoint source loading function developed on empirical concepts was fit to the data. This function was then used to calculate the average annual salt yield to the Price River by overland flow. It was found that even under severe conditions, the salt yields from Mancos shale lands due to overland flow is relatively minor, accounting for less than 1.5 percent of the average annual salt mass transported from the basin by the Price River.     

LAKE MICHIGAN DIVERSION - STREAM QUALITY PLANNING1

ABSTRACT: By United States Supreme Court action, the diversion of water from Lake Michigan and the Lake Michigan Drainage Basin in the Metropolitan Chicago Area is regulated at an annual maximum rate of 3,200 cfs. Approximately 1,700 cfs of this diversion is used for water supply, and the remaining 1,500 cfs consists primarily of stormwater runoff with lesser amounts of direct lake diversion, such as lockage and leakage, navigational makeup water flows, and discretionary diversion needed to maintain water quality standards in the Metropolitan Sanitary District of Greater Chicago's basic waterways. In order to assess the schedule of its discretionary diversion needs, the District, using a computer model of its basic waterway system, has calculated the minimum discretionary diversion requirements for projected water quality conditions as successive elements of the District's water pollution control program are completed. The results of these analyses can be used as a basis for developing plans for future allocations of the limited supply of Lake Michigan water to other uses such as domestic water supply, when and if such supplies become available.     

ACCIDENTAL AND PLANNED WEATHER MODIFICATION IN ILLINOIS1

ABSTRACT: Weather modification, both planned by man and that accidentally produced by man, has been under intensive study in Illinois for ten years. Most everyone in Illinois and the Midwest is living in a climate that now is modified inadvertently from its natural state. State atmospheric scientists have tackled weather modification through a series of interrelated studies beginning with climatic studies (to establish the background), experimental design studies, experimental field studies to verify changes and their causes, and finally socio-economic and environmental studies to measure the impacts of weather modification. Studies at St. Louis show that the city acts as a trigger of summer clouds and rainfall leading to 4 to 6 summer days with 3 cm or more rain somewhere just east of the city. Power plants and jet aircraft also accidentally produce climatic changes. A focus on planned weather modification has been on the design of needed midwestern experiments in rainfall enhancement and hail suppression including the societal and environmental impacts.     

ATMOSPHERIC CONTROLS OF WATER EXCHANGE IN GREAT LAKES BASIN1

ABSTRACT Existing meteorological controls of water exchange by precipitation and evaporation on the Great Lakes are almost entirely inadvertent and related to man's urban-industrial complexes and their effect upon precipitation processes. These inadvertent effects have led to 10 to 40% increases in precipitation in localized areas within the basin. Envisioned growth of urban-industrial complexes within the Great Lakes region should lead to more inadvertent weather modification in the Basin. The only existing planned weather modification efforts are those at Lake Erie which are attempting to eliminate by redistribution the concentration of lake-derived heavy snowfall along the south shore. It appears reasonable to assume that practical increases of lake precipitation on the order of 5-20% could be achieved on an operational basis over the Great Lakes in the next 10 years, but the time of accomplishment will depend on national priorities, international cooperation, and economic factors. These activities would certainly produce a sizeable increase in the water quantity of the Great Lakes and should result in an improvement in water quality. Operational methods of evaporation suppression applicable to the lakes are just not available. Meteorological controls to ameliorate certain undesirable lake-effect snowstorms are a near reality.     

QUANTITATIVE METHODS FOR PRELIMINARY DESIGN OF WATER QUALITY SURVEILLANCE SYSTEMS1

ABSTRACT: To assure attainment and maintenance of desired water quality levels in our rivers and streams, systematic monitoring must be performed. A preliminary phase of the design of water quality surveillance systems is the specification of sampling frequencies and station locations throughout the basin; that is, the development of an adequate space/time sampling plan. The purpose of this paper is to present some quantitative methods which have been developed to identify candidate sets of sampling frequencies and station locations, and to establish priorities for implementing the different frequencies and locations. These methods are useful in the cost/effectiveness trade-off analyses in surveillance system design, and are based on the surveillance system objective of pollution abatement in which it is desired to detect violations in state-federal water quality standards. A spatial priority measure is developed which is dependent both on the water quality profile in the stream and on the information obtained from monitoring stations located in other reaches. Also, a temporal sampling priority rating is presented which is a measure of the effectiveness of the surveillance system with respect to its ability to detect the violations in the standards. To illustrate the quantitative methods, the procedures are applied to the Wabash River Basin.     

MEASURING DROUGHT IMPACTS: THE ILLINOIS CASE1

ABSTRACT: Drought is an interaction between physical processes and human activities. This study quantified the impacts of precipitation deficiencies on streamflow, reservoirs, and shallow ground water supplies. An in-depth analysis of newspaper accounts of droughts between paired cities, one in drought and one not in drought, were used to measure the differences in the types of drought impacts, and in the time of onset of impacts as related to developing precipitation deficiencies. Precipitation deficiencies related to the onset and the magnitude of surface water supply adjustments, and to shallow ground water problems, were established. Thus, monitoring and prediction of the onset and magnitude of drought problems can now be done from readily available data on precipitation deficiencies. Newspapers were found to be reliable indicators for the timing of drought impacts and adjustments as precipitation deficiency develops. A review of local and state adjustments during two recent droughts revealed most decision makers lacked information and experience in dealing with drought.     

Motivations of aspiring male and female entrepreneurs

This study examines the motives that stimulate individuals into becoming business proprietors. More specifically, it aims to discover if entrepreneurs have multiple motives for creating their enterprises, if non-economic motives predominate over economic ones, and if men and women have similar reasons for business founding. Results, based on personal interviews with 35 men and 34 women, indicate that both genders have a variety of reasons for founding and that women, as well as men, are primarily motivated by autonomy, achievement, a desire for job satisfaction and other non-economic rewards. A desire to make money is not, however, an unimportant motive. Turning to differences in motives we find that women are less concerned with making money and often choose business proprietorship as a result of career dissatisfaction. They also see entrepreneurship as a means of meeting simultaneously their own career needs and the needs of their children.     

Environmental audit: III. Improving the management of environmental information for toxic substances

Environmental programs have been commonly driven by a preoccupation with the collection of data in the mistaken belief thatdata is synonymous withinformation. The distinction between data (that is, the quantified and qualitative attributes of a particular environment) and information (specifically, data processed so as to focus upon a particular environmental problem) will become far more important to environmental managers. They will increasingly manage their information through use of what has become known as information resource management (IRM) and the attendant use of critical success factors methodology. Environmental managers will thereby move away from concerns about data and specific EDP hardware and applications toward managing information as a valuable agency resource. In applying IRM, they will find it helpful to include a number of planning elements and to resolve early a number of issues critical to its successful use.     

USE OF CLIMATE PREDICTIONS TO DECIDE A WATER MANAGEMENT PROBLEM1

ABSTRACT: Seasonal precipitation predictions were utilized in a water management decision with major economic, societal, and political ramifications. A summer (1984) drought had created a situation calling for possible fall season use of state waters from two major multipurpose reservoirs with an ensuing effect on water price negotiations. Choices facing management and use of water from the reservoirs were to invoke expensive water restrictions with a 33 percent chance of being right, do nothing (66 percent chance of wrong outcome), or use the precipitation predictors (for above normal fall rain) having a 50 percent chance of error. Hydrologists chose to follow the precipitation predictions, which proved to be accurate for the fall of 1984, helping to reveal the long-term value of using well understood climate predictions in water management.