Uranium speciation in moorland river water samples: a comparison of experimental results and computer model predictions

An on-line method has been developed for separating inorganic and organic bound uranium species present in river water samples. The method utilised a small chelating resin (Hyphan) column incorporated into the sample introduction manifold of an ICP-MS instrument. The method was evaluated for samples from rivers on Dartmoor (Devon, UK), an area of granite overlain with peat bogs. The results indicate that organic-uranium species form a major proportion (80%) of the total dissolved uranium present. Further work with synthetic water samples indicated that the level of dissolved organic carbon played a greater role in determining the level of organic-uranium species than did sample pH. Computer models for the water samples were constructed using the WHAM program (incorporating uranium data from the Nuclear Energy Agency Thermochemical Database project) in order to predict the levels of organic-uranium species that would form. By varying the proportion of humic and fulvic acids used in the humic component, predictions within 10% of the experimental results were obtained. The program did exhibit a low bias at higher pH values (7.5) and low organic carbon concentrations (0.5 microg ml(-1)), but under the natural conditions prevalent in the Dartmoor water samples, the model predictions were successful.     

Denitrification in suburban lawn soils

There is great uncertainty about the fate of nitrogen (N) added to urban and suburban lawns. We used direct flux and in situ chamber methods to measure N and NO fluxes from lawns instrumented with soil O sensors. We hypothesized that soil O, moisture, and available NO were the most important controls on denitrification and that N and NO fluxes would be high following fertilizer addition and precipitation events. While our results support these hypotheses, the thresholds of soil O, moisture, and NO availability required to see significant N fluxes were greater than expected. Denitrification rates were high in saturated, fertilized soils, but low under all other conditions. Annual denitrification was calculated to be 14.0 ± 3.6 kg N ha yr, with 5% of the growing season accounting for >80% of the annual activity. Denitrification is thus an important means of removing reactive N in residential landscapes, but varies markedly in space, time, and with factors that affect soil saturation (texture, structure, compaction) and NO availability (fertilization). Rates of in situ NO flux were low; however, when recently fertilized soils saturated with water were incubated in the laboratory, we saw extraordinarily high rates of NO production for the first few hours of incubation, followed by rapid NO consumption later in the experiment. These findings indicate a lag time between accelerated NO production and counterbalancing increases in NO consumption; thus, we cannot yet conclude that lawns are an insignificant source of NO in our study area.     

In Flanders Fields: De/politicization and Democratic Debate on a GM Potato Field Trial Controversy in News Media

In May 2011, a highly mediatized direct action in the form of a “field liberation” took place in Flanders, Belgium, against a field trial of genetically modified potatoes. This direct action and its aftermath revealed the conflictual and antagonistic nature of the genetically modified organisms debate in Flanders. Consequently, it serves as a particularly suitable case to investigate the post-political thesis with regard to environmental discourse and politics. The aim of this paper is to investigate in what ways news media in their reporting contribute to processes of depoliticization and, resultantly, impede a democratic debate on the issues at stake. This paper attempts to provide an answer to this question based on a critical discourse analysis of the reporting by Flanders’ two generalist, elite newspapers, De Standaard and De Morgen and the alternative online news site DeWereldMorgen. The findings reveal the existence of three ideological cultures, which are characterized by different degrees of de/politicization. We conclude by discussing how this study adds to our understanding of the relation between the depoliticization of environmental discourse, democratic debate and twenty-first-century news media.     

Partnerships for Local Environmental Action: Observations on the First Two Years of Rural Action for the Environment

Rural Action for the Environment is a key element of the UK Government's 'Action for the Countryside' initiative. It has two main elements: the provision of advice, training, information and grants to local communities; and the formation of county based networks of environmental organizations to provide the necessary support infrastructure to local projects. This paper suggests that Rural Action is a laudable attempt to move towards a more 'enabling' style of operation which may ultimately result in a significant increase in the level of interest and involvement in environmental action. However, it has also highlighted a number of important problems which are likely to afflict all future attempts to encourage local communities to formulate and carry out sustainable environmental improvements in their areas. Particular difficulties result from the need to reconcile the multiple and possibly contradictory objectives of different agencies, the problems of engaging the interest of local people, the time and other resource constraints faced by those who seek to implement such initiatives and the political imperative to achieve action on the ground as rapidly as possible. Each of these issues will need to be addressed by future schemes if widespread involvement in locally determined environmental action is to be secured.