全文获取类型
收费全文 | 1286篇 |
免费 | 56篇 |
国内免费 | 398篇 |
专业分类
安全科学 | 74篇 |
废物处理 | 74篇 |
环保管理 | 107篇 |
综合类 | 629篇 |
基础理论 | 239篇 |
污染及防治 | 443篇 |
评价与监测 | 53篇 |
社会与环境 | 38篇 |
灾害及防治 | 83篇 |
出版年
2023年 | 18篇 |
2022年 | 72篇 |
2021年 | 49篇 |
2020年 | 45篇 |
2019年 | 34篇 |
2018年 | 43篇 |
2017年 | 49篇 |
2016年 | 48篇 |
2015年 | 77篇 |
2014年 | 92篇 |
2013年 | 125篇 |
2012年 | 110篇 |
2011年 | 115篇 |
2010年 | 91篇 |
2009年 | 79篇 |
2008年 | 95篇 |
2007年 | 84篇 |
2006年 | 92篇 |
2005年 | 57篇 |
2004年 | 37篇 |
2003年 | 39篇 |
2002年 | 43篇 |
2001年 | 32篇 |
2000年 | 26篇 |
1999年 | 30篇 |
1998年 | 29篇 |
1997年 | 27篇 |
1996年 | 18篇 |
1995年 | 17篇 |
1994年 | 12篇 |
1993年 | 17篇 |
1992年 | 10篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 2篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1971年 | 1篇 |
1969年 | 1篇 |
1962年 | 1篇 |
排序方式: 共有1740条查询结果,搜索用时 31 毫秒
91.
Recent research has shown that carbonaceous solid materials and zerovalent iron (Fe(0)) may potentially be used as media in permeable reactive barriers (PRBs) to degrade groundwater nitrate via heterotrophic denitrification in the solid carbon system, and via abiotic reduction and autotrophic denitrification in the Fe(0) system. Questions arise as whether the more expensive Fe(0) is more effective than the less expensive carbonaceous solid materials for groundwater nitrate remediation, and whether there is any synergistic effect of mixing the two different types of materials. We carried out batch tests to study the nature and rates of removal of added nitrate in the suspensions of single, binary, and ternary systems of cotton burr compost, Peerless Fe(0), and a sediment low in organic carbon. Cotton burr compost acted as both organic carbon source and supporting material for the growth of indigenous denitrifiers. Batch tests showed that cotton burr compost alone removed added nitrate at a greater rate than did Peerless Fe(0) alone on an equal mass basis with a pseudo-first-order rate constant k=0.0830+/-0.0031 h(-1) for cotton burr compost and a k=0.00223+/-0.00022 h(-1) for Peerless Fe(0); cotton burr compost also removed added nitrate at a faster rate than did cotton burr compost mixed with Peerless Fe(0) and/or the sediment. Furthermore, there was no substantial accumulation of ammonium ions in the cotton burr compost system, in contrast to the systems containing Peerless Fe(0) in which ammonium ions persisted as major products of nitrate reduction. It is concluded that cotton burr compost alone may be used as an excellent denitrification medium in a PRB for groundwater nitrate removal. Further study is needed to evaluate performance of its field applications. 相似文献
92.
Transport of simazine in unsaturated sandy soil and predictions of its leaching under hypothetical field conditions 总被引:2,自引:0,他引:2
Suárez F Bachmann J Muñoz JF Ortiz C Tyler SW Alister C Kogan M 《Journal of contaminant hydrology》2007,94(3-4):166-177
The potential contamination of groundwater by herbicides is often controlled by processes in the vadose zone, through which herbicides travel before entering groundwater. In the vadose zone, both physical and chemical processes affect the fate and transport of herbicides, therefore it is important to represent these processes by mathematical models to predict contaminant movement. To simulate the movement of simazine, a herbicide commonly used in Chilean vineyards, batch and miscible displacement column experiments were performed on a disturbed sandy soil to quantify the primary parameters and processes of simazine transport. Chloride (Cl(-)) was used as a non-reactive tracer, and simazine as the reactive tracer. The Hydrus-1D model was used to estimate the parameters by inversion from the breakthrough curves of the columns and to evaluate the potential groundwater contamination in a sandy soil from the Casablanca Valley, Chile. The two-site, chemical non-equilibrium model was observed to best represent the experimental results of the miscible displacement experiments in laboratory soil columns. Predictions of transport under hypothetical field conditions using the same soil from the column experiments were made for 40 years by applying herbicide during the first 20 years, and then halting the application and considering different rates of groundwater recharge. For recharge rates smaller than 84 mm year(-1), the predicted concentration of simazine at a depth of 1 m is below the U.S. EPA's maximum contaminant levels (4 microg L(-1)). After eight years of application at a groundwater recharge rate of 180 mm year(-1) (approximately 50% of the annual rainfall), simazine was found to reach the groundwater (located at 1 m depth) at a higher concentration (more than 40 microg L(-1)) than the existing guidelines in the USA and Europe. 相似文献
93.
Humic acids, extracted from sludge at the biologic-mechanical sewage treatment plant in Jastrzebie Zdroj, have been investigated by means of (1)H, (13)C and (31)P NMR spectroscopy. Sludge samples for studies were taken from the primary settling tank, the nitrification chamber, the digestion chamber and the sludge drying beds. The (1)H NMR analysis of humic acid extracted from sludge at various stages of sewage treatment confirmed the presence of the functional groups that are characteristic for humic substances, and the analysis showed changes in their relative intensities. The (13)C NMR indicated that the aromatisation of the humic acid increased during sewage treatment. Moreover, the analysis of the (31)P NMR spectra allowed us to observe the changes in the phosphorus groups of the studied humic acids. 相似文献
94.
西藏冰湖溃决主要特征 总被引:7,自引:1,他引:6
西藏是我国冰湖分布最多的地区。冰湖常发生溃决,其中最典型是终碛冰湖的溃决。冰湖溃决所导致的泥石流,具有突发性强、频率低、洪峰高、流量大、流量过程暴涨暴落和破坏力强及灾害波及范围广等特点。从20世纪30年代中期至今,已查明西藏15个冰川终碛湖至少发生过18次溃决。通过对这些溃决事件的分析,探讨了终碛湖溃决的时空分布特征,发现该事件的发生与气候变化,特别是与气候异常年份有显著的对应关系。结合近年冰湖分布和变化资料,讨论了未来的发展趋势。具体分析了溃决洪水过程和冰湖溃决洪水泥石流演变过程。 相似文献
95.
96.
97.
采用固相萃取法处理水样,气相色谱-高分辨双聚焦磁质谱法测定水中超痕量多氯萘,同位素内标法定量,并对样品前处理条件和仪器条件进行优化。试验表明:方法在0.500 ng/L~500 ng/L范围内线性良好;当取样体积为1 L时,方法检出限为0.005 ng/L~0.01 ng/L;对实际水样进行2个质量浓度水平的加标回收试验,平行测定6次的 RSD为2.7%~8.7%,回收率为70.2%~110%。方法适用性试验表明,水样中复杂的基质对测定无影响。 相似文献
98.
Fangli Su Tieliang Wang Haozhen Zhang Zhi Song Xue Feng Kan Zhang 《Environmental monitoring and assessment》2018,190(6):365
The aims of the present investigation were to reveal the distribution and enrichment characteristics of copper in soil and Phragmites australis of Liao River estuary wetland. The concentrations of copper in root, stem, leaf, and ear of Phragmites australis as well as in soil were determined to study the absorption capacity of copper by wild Phragmites australis of Liao River estuary wetland. The study was carried out at test pool of the Shenyang Agricultural University, and the experimental materials (soil, irrigating water and Phragmites australis) were derived from Liao River estuary wetland. The concentrations of copper in soil and Phragmites australis were 16.4441 to 49.0209 mg/kg and 0.8621 to 89.5524 mg/kg, respectively. The results indicated that the enrichment coefficients of copper in different tissues of Phragmites australis changed with the growth of Phragmites australis. The results revealed that the enrichment coefficients of copper in the whole Phragmites australis were greater than 1 at each growing stage of the Phragmites australis. The results also showed that the transfer coefficients of Phragmites australis to copper changed with the growth of Phragmites australis. The results revealed that the Phragmites australis had a good removal effect on copper from soil and had some characteristics of copper hyperaccumulator. 相似文献
99.
100.
T酸一次洗水初步处理的研究 总被引:4,自引:0,他引:4
采用重氮化-偶合-混凝沉淀和重氮化-混凝沉淀两种方法对T酸一次洗水的初步处理进步了研究。T酸一次洗水经两种方法处理后,COD去除率分别为61.3%、50.5%,色度去除率分别为74.6%、71%。 相似文献