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51.
Ulrich Harréus MD PhD Philipp Baumeister Norbert Kleinsasser Maximilian Reiter Beatrice Bachmeier Christoph Matthias 《毒物与环境化学》2013,95(2):205-214
The etiology of salivary gland malignancies still remains unclear. Metal compounds are of special interest since they show ubiquitous presence in the environment, are present in many working places, and are accepted (co-)carcinogens in some other malignancies. Metals enter the body as xenobiotics by inhalation or ingestion. This study investigated the genotoxic potential of sodium dichromate (Na2Cr2O7), nickel sulfate (NiSO4), cadmium sulfate (CdSO4) and zinc chloride (ZnCl2) on human salivary gland cells and lymphocytes. Macroscopically healthy tissue of salivary glands was harvested from 46 patients during surgery and isolated to single cells by enzymatic digestion. The cells were incubated with Na2Cr2O7, NiSO4, CdSO4 or ZnCl2. Na2Cr2O7 was also incubated in combination with the other metal compounds listed. Carcinogenic and co-carcinogenic effects of cadmium were tested by incubation with Na2Cr2O7 and consecutive repair intervals. DNA damage and repair were evaluated by the Comet assay, determining DNA-strand breaks. The extent of damage was quantified using a digital analysis system. Na2Cr2O7 produced significantly enhanced DNA-strand breaks in human salivary gland tissue and lymphocytes. All other metal compounds exerted no damaging effect on both cell types. Co-incubation of Na2Cr2O7 with the other metals revealed a significant additive effect only for CdSO4. Specific analysis of the influence of cadmium showed a reduction of DNA-repair after Na2Cr2O7-induced strand breaks in salivary gland cells. This study provides evidence that exposure to distinct metals may significantly contribute to malignant salivary gland tumors. In consequence, further studies as epidemiological and toxicological data are warranted to determine the role of distinct metals as potential (co-) carcinogens. 相似文献
52.
Ulrich Oberndorfer Peter Schmidt Marcus Wagner Andreas Ziegler 《Journal of Environmental Economics and Management》2013
This paper empirically analyzes the effect of the inclusion of German corporations in the Dow Jones STOXX Sustainability Index (DJSI STOXX) and the Dow Jones Sustainability World Index (DJSI World) on stock performance. In order to receive robust estimation results, we apply an (short-term) event study approach that is based on both a modern asset pricing model, namely the three-factor model according to Fama and French [24], and additionally a t-GARCH(1,1) model. Our empirical results suggest that stock markets may penalize the inclusion of a firm in sustainability stock indexes. This finding is mainly driven by a strongly negative effect of the inclusion in the DJSI World. In contrast, we do not find significant average cumulative abnormal returns for the inclusion in the DJSI STOXX. This suggests that the inclusion in a more visible sustainability stock index may have larger negative impacts. 相似文献
53.
Siobhan F. Cox Merlyn C. M. Chelliah Jennifer M. McKinley Sherry Palmer Ulrich Ofterdinger Michael E. Young Mark R. Cave Joanna Wragg 《Environmental geochemistry and health》2013,35(5):553-567
Potentially toxic elements (PTEs) including nickel and chromium are often present in soils overlying basalt at concentrations above regulatory guidance values due to the presence of these elements in underlying geology. Oral bioaccessibility testing allows the risk posed by PTEs to human health to be assessed; however, bioaccessibility is controlled by factors including mineralogy, particle size, solid-phase speciation and encapsulation. X-ray diffraction was used to characterise the mineralogy of 12 soil samples overlying Palaeogene basalt lavas in Northern Ireland, and non-specific sequential extraction coupled with chemometric analysis was used to determine the distribution of elements amongst soil components in 3 of these samples. The data obtained were related to total concentration and oral bioaccessible concentration to determine whether a relationship exists between the overall concentrations of PTEs, their bioaccessibility and the soils mineralogy and geochemistry. Gastric phase bioaccessible fraction (BAF %) ranged from 0.4 to 5.4 % for chromium in soils overlying basalt and bioaccessible and total chromium concentrations are positively correlated. In contrast, the range of gastric phase BAF for nickel was greater (1.4–43.8 %), while no significant correlation was observed between bioaccessible and total nickel concentrations. However, nickel BAF was inversely correlated with total concentration. Solid-phase fractionation information showed that bioaccessible nickel was associated with calcium carbonate, aluminium oxide, iron oxide and clay-related components, while bioaccessible chromium was associated with clay-related components. This suggests that weathering significantly affects nickel bioaccessibility, but does not have the same effect on the bioaccessibility of chromium. 相似文献
54.
Sherry Palmer Ulrich Ofterdinger Jennifer M. McKinley Siobhan Cox Amy Barsby 《Environmental geochemistry and health》2013,35(5):569-584
Correlation analyses were conducted on nickel (Ni), vanadium (V) and zinc (Zn) oral bioaccessible fractions (BAFs) and selected geochemistry parameters to identify specific controls exerted over trace element bioaccessibility. BAFs were determined by previous research using the unified BARGE method. Total trace element concentrations and soil geochemical parameters were analysed as part of the Geological Survey of Northern Ireland Tellus Project. Correlation analysis included Ni, V and Zn BAFs against their total concentrations, pH, estimated soil organic carbon (SOC) and a further eight element oxides. BAF data were divided into three separate generic bedrock classifications of basalt, lithic arenite and mudstone prior to analysis, resulting in an increase in average correlation coefficients between BAFs and geochemical parameters. Sulphur trioxide and SOC, spatially correlated with upland peat soils, exhibited significant positive correlations with all BAFs in gastric and gastro-intestinal digestion phases, with such effects being strongest in the lithic arenite bedrock group. Significant negative relationships with bioaccessible Ni, V and Zn and their associated total concentrations were observed for the basalt group. Major element oxides were associated with reduced oral trace element bioaccessibility, with Al2O3 resulting in the highest number of significant negative correlations followed by Fe2O3. spatial mapping showed that metal oxides were present at reduced levels in peat soils. The findings illustrate how specific geology and soil geochemistry exert controls over trace element bioaccessibility, with soil chemical factors having a stronger influence on BAF results than relative geogenic abundance. In general, higher Ni, V and Zn bioaccessibility is expected in peat soil types. 相似文献
55.
We analyzed several species of the weevil family Mecininae (Coleoptera, Curculionidae) that all feed on iridoid glycoside
(IG) containing plants of the Plantaginaceae to investigate whether the beetles sequester these deterrent substances from
their host plants. Within the Mecininae two genera of the tribe Cionini were found to sequester aucubin and catalpol: Cionus Clairville
and Schellenberg and Cleopus Dejean. Both analyzed genera of the Mecinini, Mecinus Germar and Rhinusa Stephens, do not sequester IGs although the compounds are present in their food plants. They thus represent the first case of specialists
on IG plants that have not evolved adaptations to use the compounds. However, in contrast to the Cionini these genera have
a hidden lifestyle, so that their need for defence might be lower. Both Cionus and Cleopus, sequester catalpol with a higher efficiency than aucubin. However, in contrast to Cionus species, Cleopus species only sequester catalpol. In species feeding on Scrophularia, the aucubin concentration is higher while in beetles on Verbascum catalpol is usually dominating. This pattern can also be detected in the only species living on both plants, Cionus hortulanus. The ability to sequester IGs must have a single origin at the base of the sister genera Cionus and Cleopus. 相似文献
56.
Ecological and physiological studies focused on dietary preferences, lipid biochemistry and energetics within the three Antarctic
chaetognaths Eukrohnia hamata, E. bathypelagica and E. bathyantarctica from meso- and bathypelagic depths. Eukrohnia hamata and E. bathypelagica respired 0.15 μL O2 mg dry mass (DM)−1 h−1, which translates to an average metabolic loss of only <1.1% of body carbon per day. Lipid storage was not substantial in
E. bathypelagica (mean 11.5 ± 6.5% DM) and E. bathyantarctica (mean 15.4 ± 4.1% DM) during summer and winter, suggesting year-round feeding of these predators mainly on copepods. In E. bathypelagica, total fatty acids were dominated by the fatty acids 16:0, 20:5(n-3) and 22:6(n-3) and in E. bathyantarctica also by 18:1(n-9), a fatty acid usually found in storage lipids. Only the latter species was characterized by significant
amounts of wax esters, consisting largely of the common fatty alcohols 16:0, 20:1(n-9) and the unusual fatty alcohol isomer
22:1(n-9). 相似文献
57.
The plant surface is the substrate upon which herbivorous insects and natural enemies meet and thus represents the stage for
interactions between the three trophic levels. Plant surfaces are covered by an epicuticular wax layer which is highly variable
depending on species, cultivar or plant part. Differences in wax chemistry may modulate ecological interactions. We explored
whether caterpillars of Spodoptera frugiperda, when walking over a plant surface, leave a chemical trail (kairomones) that can be detected by the parasitoid Cotesia marginiventris. Chemistry and micromorphology of cuticular waxes of two barley eceriferum wax mutants (cer-za.126, cer-yp.949) and wild-type cv. Bonus (wt) were assessed. The plants were then used to investigate potential surface effects on
the detectability of caterpillar kairomones. Here we provide evidence that C. marginiventris responds to chemical footprints of its host. Parasitoids were able to detect the kairomone on wild-type plants and on both
cer mutants but the response to cer-yp.949 (reduced wax, high aldehyde fraction) was less pronounced. Experiments with caterpillar-treated wt and mutant leaves
offered simultaneously, confirmed this observation: no difference in wasp response was found when wt was tested against cer-za.126 (reduced wax, wt-like chemical composition) but wt was significantly more attractive than cer-yp.949. This demonstrates for the first time that the wax layer can modulate the detectability of host kairomones. 相似文献
58.
Ben Vanpeperstraete Sébastien Duyck Medani P. Bhandari Janis Brizga Leida Rijnhout Sylvia Lorek A. Peter Castro Chiung Ting Chang Herman Daly Robert J. Didham Gianluca Ferraro Oliver Greenfield Ashok Khosla Ernst Ulrich von Weizsäcker Birgit Lode Simon Miles Henrique Pacini Semida Silveira Leisa Perch Jaap Rijnsburger Mukul Sanwal Sameera Savarala S. Jacob Scherr Kallidaikurichi E. Seetharam A.M.M. Adeeb Donna Shepherd Adrian Smith Lisinka Ulatowska Alice Vincent Werner John 《Natural resources forum》2011,35(4):334-342
59.
Ulrich Liebenthal Sebastian Linnenberg Jochen Oexmann Alfons Kather 《International Journal of Greenhouse Gas Control》2011,5(5):1232-1239
When integrating a post-combustion CO2 capture process and CO2 compression into a steam power plant, the three interface quantities heat, electricity and cooling duty must be satisfied by the power plant, leading to a loss in net efficiency. The heat duty shows to be the largest contributor to the overall net efficiency penalty of the power plant. Additional energy penalty results from the cooling and electric power duty of the capture and compression units.In this work, the dependency of the energy penalty on the quantity and quality of the heat duty is analyzed and quantified for a state-of-the-art hard coal fired power plant. Furthermore, the energy penalty attributed to the additional cooling and power duty is quantified. As a result correlations are provided which enable to predict the impact of the heat, cooling and electricity duty of post-combustion CO2 capture processes on the net output of a steam power plant in a holistic approach. 相似文献
60.
Weise Katrin Kurth Thomas Politowski Irina Winkelmann Carola Schäffer Andreas Kretschmar Susanne Berendonk Thomas Ulrich Jungmann Dirk 《Environmental science and pollution research international》2022,29(18):26706-26725
Environmental Science and Pollution Research - Although the development and application of nanomaterials is a growing industry, little data is available on the ecotoxicological effects on aquatic... 相似文献