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181.
Bhanu Pratap Ram M.V. Nitin 《Journal of Loss Prevention in the Process Industries》2005,18(4-6):283-292
An approach, based purely on steady-state analyses, for synthesizing effective control structures for reactive distillation (RD) columns is presented. The main idea is to analyze the steady-state relationships between the manipulated (input) variables and the potential controlled (output) variables to identify input–output (IO) pairings that are sensitive and avoid steady-state multiplicities providing a large range of nearly linear operating region around the base case design. Traditional SISO control loops are then implemented using these IO pairings to obtain control structures that maintain the column near the design product purity and conversion for the anticipated primary disturbances. The Niederlinski Index is used to eliminate dynamically unstable pairings in control structures with multiple loops. The approach is demonstrated on an example MTBE RD column. The impact of steady-state multiplicities on control structure design is highlighted. 相似文献
182.
Septic system leachfields can release dissolved nitrogen in the form of nitrate into ground water, presenting a significant source of pollution. Low cost, passive modifications, which increase N removal in traditional leachfields, could substantially reduce the overall impact on ground water resources. Bench-scale laboratory models were constructed to evaluate the effect of placing an organic layer below the leachfield on total N removal. The organic layer provides a carbon source for denitrification. Column units representing septic leachfields were constructed with sawdust-native soil organic layers placed 0.45 m below the influent line and with thicknesses of 0.0, 0.3, 0.6, and 0.9 m. Using a synthetic septic tank effluent, NO(3)-N concentrations at 3.8 m below the influent line were consistently below 1 mg L(-1) during 10 months of operation compared with a NO(3)-N concentration of nearly 12 mg L(-1) in the control column. The average total N removal increased from 31% without the organic layer to 67% with the organic layer. Total N removal appeared limited by the extent of organic N oxidation and nitrification in the 0.45-m aerobic zone. Design modifications targeted at improving nitrification above the organic layer may further increase total N removal. Increased organic layer thicknesses from 0.3 m to 0.9 m did not significantly improve average total N removal, but caused a shift in residual nitrogen from organic N to ammonia N. Results indicate that addition of a layer of carbon source material at least 0.3 m thick below a standard leachfield substantially improves total N removal. 相似文献
183.
John V. Westra Julie K.H. Zimmerman Bruce Vondracek 《Journal of the American Water Resources Association》2005,41(2):309-322
ABSTRACT: Farmers can generate environmental benefits (improved water quality and fisheries and wildlife habitat), but they may not be able to quantify them. Furthermore, farmers may reduce their incomes from managing lands to produce these positive externalities but receive little monetary compensation in return. This study simulated the relationship between agricultural practices, water quality, fish responses to suspended sediment and farm income within two small watersheds, one of a cool water stream and one of a warm water stream. Using the Agricultural Drainage and Pesticide Transport (ADAPT) model, this study related best management practices (BMPs) to calculated instream suspended sediment concentrations by estimating sediment delivery, runoff, base flow, and streambank erosion to quantify the effects of suspended sediment exposure on fish communities. By implementing selected BMPs in each watershed, annual net farm income declined $18,000 to $28,000 (1 to 3 percent) from previous levels. “Lethal” fish events from suspended sediments in the cool water watershed decreased by 60 percent as conservation tillage and riparian buffers increased. Despite reducing suspended sediments by 25 percent, BMPs in the warm water watershed did not reduce the negative response of the fisheries. Differences in responses (physical and biological) between watersheds highlight potential gains in economic efficiency by targeting BMPs or by offering performance based “green payments.” 相似文献
184.
185.
E.V. Antonakou K.G. Kalogiannis S.D. Stephanidis K.S. Triantafyllidis A.A. Lappas D.S. Achilias 《Waste management (New York, N.Y.)》2014,34(12):2487-2493
Pyrolysis appears to be a promising recycling process since it could convert the disposed polymers to hydrocarbon based fuels or various useful chemicals. In the current study, two model polymers found in WEEEs, namely polycarbonate (PC) and high impact polystyrene (HIPS) and their counterparts found in waste commercial Compact Discs (CDs) were pyrolysed in a bench scale reactor. Both, thermal pyrolysis and pyrolysis in the presence of two catalytic materials (basic MgO and acidic ZSM-5 zeolite) was performed for all four types of polymers. Results have shown significant recovery of the monomers and valuable chemicals (phenols in the case of PC and aromatic hydrocarbons in the case of HIPS), while catalysts seem to decrease the selectivity towards the monomers and enhance the selectivity towards other desirable compounds. 相似文献
186.
Matichenkov Vladimir V. Bocharnikova Elena A. Pakhnenko Ekaterina P. Khomiakov Dmitry M. 《Environmental science and pollution research international》2017,24(31):24311-24317
Environmental Science and Pollution Research - The poor adsorption capacity of sandy soils is one of the primary reasons of a high level of phosphorus (P) leaching. Silicon (Si)-rich soil... 相似文献
187.
Population Structure of Sable in the Baikal Mountain Land: Analysis of Genetic and Phenotypic Traits
Russian Journal of Ecology - The genetic and phenotypic structure (according to the fur color) of 14 sable samples from the Baikal mountain land (BML) has been studied by analyzing 257 animals for... 相似文献
188.
Effects of productivity on biodiversity in forest ecosystems across the United States and China 下载免费PDF全文
In the global campaign against biodiversity loss in forest ecosystems, land managers need to know the status of forest biodiversity, but practical guidelines for conserving biodiversity in forest management are lacking. A major obstacle is the incomplete understanding of the relationship between site primary productivity and plant diversity, due to insufficient ecosystem‐wide data, especially for taxonomically and structurally diverse forest ecosystems. We investigated the effects of site productivity (the site's inherent capacity to grow timber) on tree species richness across 19 types of forest ecosystems in North America and China through 3 ground‐sourced forest inventory data sets (U.S. Forest Inventory and Analysis, Cooperative Alaska Forest Inventory, and Chinese Forest Management Planning Inventory). All forest types conformed to a consistent and highly significant (P < 0.001) hump‐shaped unimodal relationship, of which the generalized coefficients of determination averaged 20.5% over all the forest types. That is, tree species richness first increased as productivity increased at a progressively slower rate, and, after reaching a maximum, richness started to decline. Our consistent findings suggest that forests of high productivity would sustain few species because they consist mostly of flat homogeneous areas lacking an environmental gradient along which a diversity of species with different habitats can coexist. The consistency of the productivity–biodiversity relationship among the 3 data sets we examined makes it possible to quantify the expected tree species richness that a forest stand is capable of sustaining, and a comparison between the actual species richness and the sustainable values can be useful in prioritizing conservation efforts. 相似文献
189.
K. Milenova I. Avramova A. Eliyas V. Blaskov I. Stambolova Nikoleta Kassabova 《Environmental science and pollution research international》2014,21(21):12249-12256
Activated ZnO powder has been prepared by procedures involving first its dissolution in nitric acid, then simultaneous treatment by adding NH4OH and CO2 bubbling leading to precipitation as Zn(OH)CO3 (ZH) and further thermal decomposition of ZH at 400 °C. The gas evolution leads to formation of pores and increase in the specific surface area. Chemically activated M/ZnO powders doped with Mn, Co, Ni, Cu, and Ag have been obtained by the impregnation method. The samples have been characterized by ultraviolet-visible (UV-Vis) spectroscopy, diffuse reflectance (DR) UV-Vis, X-ray diffraction (XRD), single point Brunauer–Emmet–Teller (BET), scanning electron microscope (SEM), and X-ray photoelectron spectroscopy (XPS) methods. The experiments have shown that metal-doped activated ZnO powders possess higher photocatalytic activities in oxidative discoloration of model contaminant textile coloring dye Reactive Black 5 in slurry reactor compared to that of the pure ZnO. The XRD and XPS data have shown the presence of defects, nonstoichiometricity implying the formation of solid solutions. Copper-doped (1.5 wt%) activated ZnO (Cu2+ replaces Zn2+) is outstanding in its photocatalytic performance in discoloration of the dye due to the higher specific surface area and improved charge carrier separation. 相似文献
190.
E. Blondeel M. Chys V. Depuydt K. Folens G. Du laing A. Verliefde S.W.H. Van Hulle 《Waste management (New York, N.Y.)》2014,34(12):2674-2686
Scrap material recovery and recycling companies are confronted with waste water that has a highly fluctuating flow rate and composition. Common pollutants, such as COD, nutrients and suspended solids, potentially toxic metals, polyaromatic hydrocarbons and poly chlorinated biphenyls can exceed the discharge limits. An analysis of the leaching behaviour of different scrap materials and scrap yard sweepings was performed at full-scale, pilot-scale and lab-scale in order to find possible preventive solutions for this waste water problem. The results of these leaching tests (with concentrations that frequently exceeded the Flemish discharge limits) showed the importance of regular sweeping campaigns at the company, leak proof or covered storage of specific scrap materials and oil/water separation on particular leachates. The particulate versus dissolved fraction was also studied for the pollutants. For example, up to 98% of the polyaromatic hydrocarbons, poly chlorinated biphenyls and some metals were in the particulate form. This confirms the (potential) applicability of sedimentation and filtration techniques for the treatment of the majority of the leachates, and as such the rainwater run-off as a whole. 相似文献