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21.
Spatial distribution of 238U and 226Ra activities in sediment columns along the Krka River and estuary, were studied using gamma spectrometry. Markedly different 238U and 226Ra activities between riverine, estuarine and marine sediments were observed. Distribution of these radionuclides, as well as their anthropogenic and natural origin, was evaluated by activity measurements, taking into account sedimentation rates estimated by 137Cs distribution in sediment columns. 相似文献
22.
Long-range atmospheric transport of three toxaphene congeners across Europe. Modeling by chained single-box FATEMOD program 总被引:1,自引:1,他引:0
Jaakko Paasivirta Seija Sinkkonen Vladimir Nikiforov Fedor Kryuchkov Erkki Kolehmainen Katri Laihia Arto Valkonen Manu Lahtinen 《Environmental science and pollution research international》2009,16(2):191-205
Background, aims, and scope Since toxaphene (polychlorocamphene, polychloropinene, or strobane) mixtures were applied for massive insecticide use in the
1960s to replace the use of DDT, some of their congeners have been found at high latitudes far away from the usage areas.
Especially polychlorinated bornanes have demonstrated dominating congeners transported by air up to the Arctic areas. Environmental
fate modeling has been applied to monitor this phenomenon using parallel zones of atmosphere around the globe as interconnected
environments. These zones, shown in many meteorological maps, however, may not be the best way to configure atmospheric transport
in air trajectories. The latter could also be covered by connecting a chain of simple model boxes. We aim to study this alternative
approach by modeling the trajectory chain using catchment boxes of our FATEMOD model. Polychlorobornanes analyzed in biota
of the Barents Sea offered one case to study this modeling alternative, while toxaphene has been and partly still is used
massively at southern East Europe and around rivers flowing to the Aral Sea.
Materials and methods Pure model substances of three polychlorobornanes (toxaphene congeners P26, P50, and P62) were synthesized, their environmentally
important thermal properties measured by differential scanning calorimetry, as evaluated from literature data, and their temperature
dependences estimated by the QSPR programs VPLEST, WATSOLU, and TDLKOW. The evaluated property parameters were used to model
their atmospheric long-range transport from toxaphene heavy usage areas in Ukraine and Aral/SyrDarja/AmuDarja region areas,
through East Europe and Northern Norway (Finnmarken) to the Barents Sea. The time period used for the emission model was June
1997. Usual weather conditions in June were applied in the model, which was constructed by chaining FATEMOD model boxes of
the catchment’s areas along assumed maximal air flow trajectories. Analysis of the three chlorobornanes in toxaphene mixtures
function as a basis for the estimates of emission levels caused by its usage. High estimate (A) was taken from contents in
a Western product chlorocamphene and low estimate (B) from mean contents in Russian polychloroterpene products to achieve
modeled water concentrations. Bioaccumulation to analyzed lipid of aquatic biota at the target region was estimated by using
statistical calculation for persistent organic pollutants in literature.
Results The results from model runs A and B (high and low emission estimate) for levels in sea biota were compared to analysis results
of samples taken in August 1997 at Barents Sea. The model results (ng g−1 lw): 4–95 in lipid of planktovores and 7–150 in lipid of piscivores, were in fair agreement with the analysis results from
August 1997: 21–31 in Themisto libellula (chatka), 26–42 in Boreocadus saida (Polar cod), and 5–27 in Gadus morhua (cod) liver.
Discussion The modeling results indicate that the application of chained simple multimedia catchment boxes on predicted trajectory is
a useful method for estimation of volatile airborne persistent chemical exposures to biota in remote areas. For hazard assessment
of these pollutants, their properties, especially temperature dependences, must be estimated by a reasonable accuracy. That
can be achieved by using measurements in laboratory with pure model compounds and estimation of properties by thermodynamic
QSPR methods. The property parameters can be validated by comparing their values at an environmental temperature range with
measured or QSPR-estimated values derived by independent methods. The chained box method used for long-range air transport
modeling can be more suitable than global parallel zones modeling used earlier, provided that the main airflow trajectories
and properties of transported pollutants are predictable enough.
Conclusions Long-range air transport modeling of persistent, especially photo-resistant organic compounds using a chain of joint simple
boxes of catchment’s environments is a feasible method to predict concentrations of pollutants at the target area. This is
justified from model results compared with analytical measurements in Barents Sea biota in August 1997: three of six modeled
values were high and the other three low compared to the analysis results. The order of magnitude level was similar in both
modeled (planktovore and piscivore) and observed (chatka and polar cod) values of lipid samples. The obtained results were
too limited to firm validation but are sufficient to justify feasibility of the method, which prompts one to perform more
studies on this modeling system.
Recommendations and perspectives For assessment of the risk of environmental damages, chemical fate determination is an essential tool for chemical control,
e.g., for EU following the REACH rules. The present conclusion of applicability of the chained single-box multimedia modeling
can be validated by further studies using analyses of emissions and target biota in various other cases. To achieve useful
results, fate models built with databases having automatic steps for most calculations and outputs accessible to all chemical
control professionals are essential. Our FATEMOD program catchments at environments and compound properties listed in the
database represent a feasible tool for local, regional, and, according our present test results, for global exposure predictions.
As an extended use of model, emission estimates can be achieved by reversed modeling from analysis results of samples corresponding
to the target area.
This article is dedicated to the memory of Professor Alexander B Terentiev (who passed away in November 2006), our true friend.
With his Institute of Organo-Element Compounds, Russian Academy of Science, Moscow, he was an important main organizer of
the six joint Finnish–Russian seminars (every third year since 1989) on the field (‘Chemistry and Ecology of Organo-Element
Compounds’). He prompted us especially to search properties and environmental fates for various polyhalogen compounds. We
remember him for his friendly character and great sense of humor. 相似文献
23.
Vujosević M Andelković S Savić G Blagojević J 《Environmental monitoring and assessment》2008,147(1-3):75-81
Evaluation of the presence of genotoxic substances is especially important in rivers that serve as a source of drinking water. Nine water samples collected along the river Rasina in Serbia were analyzed for potential toxic and genotoxic effects using the Allium anaphase-telophase test. Inhibition of root growth relative to the negative control (synthetic water) was observed in all samples. Analysis of the genotoxic potential, through scoring anaphase and telophase aberrations, showed that in seven of the nine samples the level of aberrations was significantly increased relative to the negative control but was lower than that obtained for the positive control (methyl methanesulfonate). Changes in the relation between spindle and chromosome types of aberrations were found in some samples, indicating differences in the potential genotoxic substances present at the analyzed sites. The data, which were obtained from samples collected at the highest level of river water, warn that during periods of low flow the values could reach genotoxic activity. The Allium anaphase-telophase test can be recommended as an monitoring system, that can serve as the first alert for the presence of genotoxic environmental pollutants. 相似文献
24.
Golobocanin D Zujić A Milenković A Miljević N 《Environmental monitoring and assessment》2008,142(1-3):185-198
Bulk samples collected on a daily basis at three principal meteorological stations in central Serbia were analyzed on chloride (Cl(-)), nitrate [Formula: see text], sulfate [Formula: see text], sodium (Na(+)), ammonium [Formula: see text], potassium (K(+)), calcium (Ca(2+)), and magnesium (Mg(2+)) in addition to precipitation amount, pH and conductivity measurements over the period 1998-2004. The data were subjected to variety of analyses (linear regression, principal component analysis, time series analysis) to characterize precipitation chemistry in the study area. The most abundant ion was [Formula: see text] with annual volume weighted mean concentration of 242 microeq L(-1). Neutralization of precipitation acidity occurs both as a result of the dissolution of alkaline compounds containing Ca(2+), Mg(2+), and K(+) as well as the absorption of ammonia. The ratio of [Formula: see text] was above 5, which indicated that the combustion process of low-grade domestic lignite for electricity generation from coal-fired thermal power plants was the main source of pollution in the investigated area. A considerable mean annual bulk wet deposition of SO(4)-S determined by precipitation amount and concentrations of sulfate in the precipitation was calculated to be 12-35 kg ha(-1). 相似文献
25.
Has-Schön E Bogut I Kralik G Bogut S Horvatić J Cacić M Cacić I 《Environmental monitoring and assessment》2008,144(1-3):15-22
Heavy metals concentration (mercury, lead, cadmium, arsenic, copper, zinc and chromium) in tissues (muscles, liver, kidney and gonads) of Dalmatian barbelgudgeon, the nase, the souffie and brown trout, inhabiting waters of Busko Blato reservoir in Bosnia and Herzegovina, has been determined by atomic absorption spectrophotometry. The meat of the tested fish sorts does not contain elevated concentration of most analyzed heavy metals with exception of lead (higher than MAC in Italy, Germany and Denmark) and mercury (in muscles of brown trout higher than MAC in most countries). The lowest level of all heavy metals is always detected in gonads, with higher values in fry compared to milt for copper, zinc, chromium and arsenic. The highest copper concentration is observed in the liver from the souffie which is suggested as a suitable biomonitor for copper intoxication. In muscles of all fish sorts, lead was always present in much higher concentration than cadmium, while in kidneys of most fish sorts, lead and cadmium concentrations were similar. We showed that bioaccumulation of some heavy metals in the fish sorts analyzed is tissue and sex dependent. Also, we concluded that the small water exchange in reversible shallow reservoir does not induce elevated concentration of heavy metals in fish tissues inhabiting Busko Blato. 相似文献
26.
In order to investigate the distribution pattern of individual organochlorine compounds in soil samples collected from the sites (Canary Island – Spain, China, Germany, India, Romania, Russia, Serbia, Swiss, UK) affected by industrial activities to the more remote areas, principal component analysis was performed on the data taken from literature. Loading plots pointed out the strong correlation among the variables. Score plots revealed similar PCB- and OCP-soil patterns for majority of the investigated sites. Nevertheless, the temporal differences of PCB-soil loads have been identified: the late 1990s and early 2000s concentrations are similar to those of the early 1940s, and they are below the levels existed in 1980. The most pronounced PCB concentrations characterized the soil from 1966. For OCPs the influence of sites location on the detected concentration has been revealed: China and India were characterized by comparably higher loads of DDX (DDT and its metabolites) and of HCH-isomers, respectively. 相似文献
27.
Cabana H Jiwan JL Rozenberg R Elisashvili V Penninckx M Agathos SN Jones JP 《Chemosphere》2007,67(4):770-778
The biocatalytic elimination of the endocrine disrupting chemicals (EDC) nonylphenol (NP) and bisphenol A (BPA) and the personal care product ingredient triclosan (TCS) by the enzyme preparation from the white rot fungus Coriolopsis polyzona was investigated. Analysis of variance methodology showed that the pH and the temperature are statistically significant factors in the removal of NP, BPA and TCS. The elimination of NP and TCS was best at a temperature of 50 degrees C and the disappearance of BPA at 40 degrees C, whereas the most suitable pH for all three micropollutants was 5. After a 4-h treatment of the three target compounds at concentrations of 5 mg l(-1) all of the NP and BPA were eliminated. In the case of TCS, 65% was removed after either a 4 or an 8-h treatment. The utilisation of 2,2'-azino-bis(3-ethylbenzthiazoline-6-sulfonic acid) in the laccase/mediator system significantly increased the efficiency of the enzymatic treatment. The elimination of NP and BPA was directly associated with the disappearance of the estrogenic activity. Mass spectrometry analysis showed that the enzymatic treatment produced high molecular weight metabolites through a radical polymerization mechanism of NP, BPA and TCS. These oligomers were produced through the formation of C-C or C-O bonds. The polymerization of NP produced dimers, trimers, tetramers and pentamers which had molecular weights of 438, 656, 874 and 1092 amu respectively. The polymerization of BPA produced dimers, trimers and tetramers which had molecular weights of 454, 680 and 906 amu. Finally, the polymerization of TCS produced dimers, trimers and tetramers which had molecular weights of 574, 859 and 1146 amu. 相似文献
28.
The study is dealing with the distribution and the origin of heavy metals (Cd, Cr, Cu, Mn, Ni, Pb and Zn) in soils from a priori non-polluted areas. Positive correlations with organic matter and clay content but not with pH have been observed for most of elements analyzed in this study. Correlations of some metals (Cr, Pb and Zn) and radionuclides (238U and 137Cs) observed for analyzed soils could be explained by their common affinity for clay minerals. Enrichment factor (EF) analysis and cluster analysis (CA) highlighted the lithogenic origin of Cr, Cu, Mn, Ni, Pb and Zn and pointed out the primary input of Cd from anthropogenic sources. It also revealed the need for detailed geochemical surveys in the future in order to decrease the uncertainty of discrimination between lithogenic and anthropogenic origin of metals of interest. 相似文献
29.
30.
Ivan Jovanović Predrag Stanimirović Živan Živković 《Environmental Modeling and Assessment》2013,18(1):73-83
Influence of the economic criterion, called Profit, on the ranking of copper concentrates is investigated. Values of the criterion, which correspond to alternatives, are derived as earning values obtained by the exploitation of individual concentrates. Various scenarios with respect to the weight w 14, corresponding to the additional economical criterion, are defined and solved. A discrete set of results is generated, applying DECISION LAB software implementation of the PROMETHEE-GAIA methodology. Interpolating these results, we derived continuous interpolation functions which compute necessary quantities of concentrates for each real value of w 14 within the interval [0, 100]. 相似文献