Cadomian terranes, wrench faulting and thrusting in the central Europe Variscides: geophysical and geological evidence

Sixty five per cent of the Paleozoic basement of western and central Europe is hidden by a sedimentary cover and/or sea. This work aims to remove that blanket to detect new structures which could used to build a more comprehensive model of the Variscan orogeny. It is based on the interpretation of various forms of data: (a) published gravity maps corrected for the effects of the crust–mantle boundary topography and light sedimentary basins; (b) aeromagnetic maps; (c) measurements of densities; and (d) induced and remanent magnetizations on rocks from Paleozoic outcrops of the upper Rhenish area. From the northern Bohemian Massif to the eastern Paris Basin, the Saxothuringian is characterized by a 500?km long belt of gravity highs, the most important being the Kraichgau high. Most of the corresponding heavy bodies are buried under a post-early Viséan cover. They are interpreted as relics of Late Proterozoic terranes overlain by an Early to Middle Paleozoic sequence, equivalent to the Bohemian terrane in the Bohemian Massif. The most probable continuation of these dense Bohemian terranes toward the west is the Southern Channel–Northern Brittany Cadomian terrane. The gravity lows are correlated with Variscan granites and pre- and early Variscan metagranites. Gravity and magnetic maps demonstrate large-scale displacement in Devonian–Early Carboniferous times along the parallel and equidistant, NW–SE striking, Vistula, Elbe, Bavarian, Bray and South Armorican dextral wrench faults. In the Vosges–Schwarzwald and Central Massif the faults continue with the east–west striking Lalaye-Lubine–Baden-Baden and Marche faults and with south vergent thrusts. The Bavarian faults shift the Kraichgau terrane by 150?km relative to the Bohemian terrane, whereas the offset of the Northern Brittany Cadomian relative to the Northern Vosges–Kraichgau terranes is estimated at 400?km along the Bray fault. Sinistral wrench faults are the NE–SW striking Sillon Houiller, Rheingraben, Rodl, Vitis and Diendorf faults. The southern Vosges–Schwarzwald Devonian–Dinantian basin is interpreted as a pull-apart basin at the south-easterly extremity of the Bray fault. The Bohemian and Kraichgau body form allochthonous terranes which were thrust over the Saxothuringian crust. Thrusting to the north-west was accompanied by back-thrusting and led to the formation of pop-up structures. Contemporaneous dextral and sinistral wrench faulting resulted in transpressive strain during collision. The zonal structure of the Variscides in the sense of Kossmat (1927) is relevant only to the Rhenohercynian Foreland Belt. Kossmat (1927) already spoke of a Moldanubian Region because it displays no real zonal structure. The Saxothuringian Zone was formed by terrane accretion. Their apparent zonal structure is not a pre-collisional feature, but only the result of accretion and collision.     

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Issues in natural resources management in developing countries

Recognizing the steady depletion of natural resources in developing countries, this study analyses its causes by focusing on the ownership of such resources. Resource degradation was found associated with an array of individual, socioeconomic, politicoeconomic and institutional factors. In the pursuit of sustainable regional resources management and conservation, it is necessary to analyse and incorporate these multifarious factors into the design of a comprehensive strategy. While local government should be responsible for devising management strategies, their implementation requires the interfacing of field agencies with local communities that are to be assisted in the short term and instructed in depth; their performance should be closely monitored over the long term.     

Principles and application of an in vivo swine assay for the determination of arsenic bioavailability in contaminated matrices

The assessment of arsenic (As) bioavailability from contaminated matrices is a crucial parameter for reducing the uncertainty when estimating exposure for human health risk assessment. In vivo assessment of As utilising swine is considered an appropriate model for human health risk assessment applications as swine are remarkably similar to humans in terms of physiology and As metabolism. While limited in vivo As bioavailability data is available in the literature, few details have been provided regarding technical considerations for performing in vivo assays. This paper describes, with examples, surgical, experimental design and analytical issues associated with performing chronic and acute in vivo swine assays to determine As bioavailability in contaminated soil and food.     

Ethyl carbamate in foods and beverages: a review

Food and beverages contain many toxic chemicals that raise health concerns. Ethyl carbamate (EC) or urethane is the ethyl ester of carbamic acid. It occurs at low level, from ng/L to mg/L, in many fermented foods and beverages. Ethyl carbamate is genotoxic and carcinogenic for a number of species such as mice, rats, hamsters and monkeys. It has been classified as a group 2A carcinogen, “probably carcinogenic to humans”, by the World Health Organization’s International Agency for Research on Cancer (IARC) in 2007. The benchmark dose lower limit of ethyl carbamate is 0.3 mg/kg bw per day and the mean intake of ethyl carbamate from food is approximately 15 ng/kg bw per day. Those levels were calculated for relevant foods including bread, fermented milk products and soy sauce. Alcoholic beverages were not included in this calculation. However, high levels of ethyl carbamate can be found in distillated spirits at concentrations ranging from 0.01 to 12 mg/L depending on to the origin of spirit. Alcoholic drinks should thus be considered as a source of ethyl carbamate. Ethyl carbamate is produced by several chemical mechanisms: first, from urea and various proteins like citrulline produced during the fermentation step and second from cyanide, and hydrocyanic acid, via ethyl carbamate precursors such as cyanate. A large panel of ethyl carbamate formation mechanisms is described from simple ethanolysis of urea in homogeneous liquid phase to photochemical oxidation of cyanide ion or complex heterogeneous gas/solid catalytic reactions. Determination of ethyl carbamate in foods and beverages involves various strategies according to the material, food or beverage, solid or liquid, and according to the concentration, from ng/L to mg/L. Usually, adapted extractive techniques and pre-concentration step are followed by analysis by gas chromatography coupled to mass spectrometry (GC–MS of GC–MS–MS). High performance liquid chromatography (HPLC) and semi-quantitative spectroscopic methods (infra-red) are also proposed as valuable alternatives to the classical but time-consuming GC–MS. Various preventing methods are developed and used in some cases at industrial scale to lower ethyl carbamate levels in food. Two types of preventing methods are described. First, adapted and optimised practices in all step of the chain of foods’ (or beverages) production lead in general to low ethyl carbamate level. Second, the abatement of ethyl carbamate precursors can be done by adapted enzymatic, physical chemical or chemical methods according to the natures of raw materials and conditions of their production processes.     

Characterization of dioxin-like contamination in soil and sediments from the ��hot spot�� area of petrochemical plant in Pancevo (Serbia)

Purpose

Combinatorial bio/chemical approach was applied to investigate dioxin-like contamination of soil and sediment at the petrochemical and organochlorine plant in Pancevo, Serbia, after the destruction of manufacturing facilities that occurred in the spring of 1999 and subsequent remediation actions.

Materials and methods

Soil samples were analyzed for indicator polychlorinated biphenyls (PCBs) by gas chromatography/electron capture detection (GC/ECD). Prioritized soil sample and sediment samples from the waste water channel were analyzed for polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) by high-resolution gas chromatography/high-resolution mass spectrometry (HRGC/HRMS). Microethoxyresorufin o-deethylase (Micro-EROD) and H4IIE?Cluciferase bioassays were used for monitoring of dioxin-like compounds (DLC) and for better characterization of dioxin-like activity of soil samples.

Results

Bioanalytical results indicated high dioxin-like activity in one localized soil sample, while the chemical analysis confirmed the presence of large quantities of DLC: 3.0?×?10⁵ ng/g d.w. of seven-key PCBs, 8.2 ng/g d.w. of PCDD/Fs, and 3.0?×?10⁵ ng/g d.w. of planar and mono-ortho PCBs. In the sediment, contaminant concentrations were in the range 2?C8 ng/g d.w. of PCDD/Fs and 9?C20 ng/g d.w. of PCBs.

Conclusions

This study demonstrates the utility of combined application of bioassays and instrumental analysis, especially for developing and transition country which do not have capacity of the expensive instrumental analysis. The results indicate the high contamination of soil in the area of petrochemical plant, and PCDD/Fs contamination of the sediment from the waste water channel originating from the ethylene dichloride production.