Current status and historical variations of phthalate ester (PAE) contamination in the sediments from a large Chinese lake (Lake Chaohu)

The residual levels of phthalate esters (PAEs) in the surface and two core sediments from Lake Chaohu were measured with a gas chromatograph–mass spectrometer (GC–MS). The temporal–spatial distributions, compositions of PAEs, and their effecting factors were investigated. The results indicated that di-n-butyl phthalate (DnBP), diisobutyl phthalate (DIBP), and di(2-ethylhexyl) phthalate (DEHP) were three dominant PAE components in both the surface and core sediments. The residual level of total detected PAEs (∑PAEs) in the surface sediments (2.146?±?2.255 μg/g dw) was lower than that in the western core sediments (10.615?±?9.733 μg/g) and in the eastern core sediments (5.109?±?4.741 μg/g). The average content of ∑PAEs in the surface sediments from the inflow rivers (4.128?±?1.738 μg/g dw) was an order of magnitude higher than those from the lake (0.323?±?0.093 μg/g dw), and there were similar PAE compositions between the lake and inflow rivers. This finding means that there were important effects of PAE input from the inflow rivers on the compositions and distributions of PAEs in the surface sediments. An increasing trend was found for the residual levels of ΣPAEs, DnBP, and DIBP from the bottom to the surface in both the western and eastern core sediments. Increasing PAE usage with the population growth, urbanization, and industrial and agricultural development in Lake Chaohu watershed would result in the increasing production of PAEs and their resulting presence in the sediments. The significant positive relationships were also found between the PAE contents and the percentage of sand particles, as well as TOC contents in the sediment cores.     

Research and application of method of oxygen isotope of inorganic phosphate in Beijing agricultural soils

Phosphorus (P) in agricultural ecosystems is an essential and limited element for plants and microorganisms. However, environmental problems caused by P accumulation as well as by P loss have become more and more serious. Oxygen isotopes of phosphate can trace the sources, migration, and transformation of P in agricultural soils. In order to use the isotopes of phosphate oxygen, appropriate extraction and purification methods for inorganic phosphate from soils are necessary. Here, we combined two different methods to analyze the oxygen isotopic composition of inorganic phosphate (δ¹⁸O_P) from chemical fertilizers and different fractions (Milli-Q water, 0.5 mol L^?1 NaHCO₃ (pH = 8.5), 0.1 mol L^?1 NaOH and 1 mol L^?1 HCl) of agricultural soils from the Beijing area. The δ¹⁸O_P results of the water extracts and NaHCO₃ extracts in most samples were close to the calculated equilibrium value. These phenomena can be explained by rapid P cycling in soils and the influence of chemical fertilizers. The δ¹⁸O_P value of the water extracts and NaHCO₃ extracts in some soil samples below the equilibrium value may be caused by the hydrolysis of organic P fractions mediated by extracellular enzymes. The δ¹⁸O_P values of the NaOH extracts were above the calculated equilibrium value reflecting the balance state between microbial uptake of phosphate and the release of intracellular phosphate back to the soil. The HCl extracts with the lowest δ¹⁸O_P values and highest phosphate concentrations indicated that the HCl fraction was affected by microbial activity. Hence, these δ¹⁸O_p values likely reflected the oxygen isotopic values of the parent materials. The results suggested that phosphate oxygen isotope analyses could be an effective tool in order to trace phosphate sources, transformation processes, and its utilization by microorganisms in agricultural soils.     

Efficacy of Si fertilization to modulate the heavy metals absorption by barley (Hordeum vulgare L.) and pea (Pisum sativum L.)

Silicon-based fertilizers and soil amendments can have direct and indirect positive influences on cultivated plants. The solid forms of Si-based substances, the most widespread in use, are efficient only at high application rates due to their low level of solubility. Several types of Si-based substances such as fumed silica, slags from the iron and steel industry, modified slags, and a Si-rich product were tested using barley and pea as silicon accumulative and non-accumulative plants, respectively, at two application rates. The plants were grown under toxic concentrations of heavy metals in a greenhouse. Si-rich materials high in water-soluble Si had a positive effect at both the low and high application rates, and for both plant species. This type of substance can be regarded as Si fertilizer, demonstrating greater efficiency at a low application rate and lessened efficiency at a high application rate for protection of the cultivated plants against accumulation of the heavy metals.

     

环境管理战略转型研究综述

由于经济社会的发展伴随的环境问题越来越复杂,资源相对不足、环境容量有限越来越突出,环境管理转型问题引起越来越多的国内外学者关注。所谓环境管理转型,是指环境管理思维、策略和方式的转变,是以环境质量为目标导向,从被动应对向主动防控的转变。本文通过文献梳理的方法,综述了国内外学术界对于环境管理战略进行的多角度探讨。通过综述发现,国外学者主要注重环境管理理论研究,如环境管理的模型研究和不同环境管理战略的研究,且国外学者在研究不同环境管理战略时,研究对象多为微观层面的企业组织;而我国学者的研究则主要集中在宏观层面,即从国家的角度来探讨环境管理战略如何完成转型,从而促进我国经济社会的良性发展。现有的国内外研究是环境管理战略相关理论发展和实践推行的重要基础,在环境管理战略研究领域,本文认为还有一些问题需要进一步研究:一是环境管理的转型不仅需要宏观层面的统筹、微观方面的变革,也需要从中观层面来推进,所以中观层面的环境管理研究同样具有重要的现实意义。二是环境管理的转型不仅需要法律手段的支撑、经济手段的配置,也需要公民环保意识的觉醒,所以关于公民环保意识层面的研究也需要加强。     

The in vitro effect of selected essential oils on the growth and mycotoxin production of Aspergillus species

The aim of the present study was to assess the antifungal and anti-toxinogenic activity of 15 essential oils (EOs) against three fungi of the genus Aspergillus (A. parasiticus KMi-227-LR, A. parasiticus KMi-220-LR and A. flavus KMi-202-LR). The minimum inhibitory doses (MIDs) of the tested essential oils and their antifungal activity were determined using the micro-atmosphere method. The original commercial essential oil samples of Jasminum officinale L., Thymus vulgaris L., Syzygium aromaticum (L.) Merrill &; Perry, Rosmarinus officinalis L., Ocimum basilicum L., Eucalyptus globulus Labill., Salvia officinalis L., Citrus limon (L.) Burm, Origanum vulgare L., Lavandula angustifolia Mill., Carum carvi L., Citrus sinensis (L.) Osbeck., Zingiber officinalis Rosc., Mentha piperita L. and Cinnamomum zeylanicum Nees. (C. verum J.S.Presl.) were produced in Slovakia (Calendula a.s., Nová ?ubovňa, Slovakia). All essential oils exhibited activity against all tested strains of fungi. After 14 days of incubation, A. flavus (KMi-202-LR) showed the highest susceptibility with a growth inhibition percentage (GIP) of 18.70% to C. limon and 5.92% to C. sinensis, while A. parasiticus (KMi-220-LR) exhibited a GIP of 20.56% to J. officinale. The minimum inhibitory doses (MIDs) of EOs with the most significant activity were recorded. The best antifungal activity, using the micro-atmosphere method was found in S. aromaticum with an MID of 62.5 μL L^?1 air, T. vulgaris (MID of 62.5 μL L^?1 air) and O. vulgare (MID of 31.5 μL L^?1 air) against all tested strains. Mycotoxin production of the tested strains was evaluated by the thin layer chromatography (TLC) method. Mycotoxin production of AFB₁ and AFG₁ was inhibited following all treatments with C. carvi, R. officinale and S. officinale, Eucalyptus globulus L. and O. basilicum L. Essential oils exhibited a potential inhibition activity against toxic fungi, although, these affected only the production of AFB₁.     

Deodorization of pig manure using lignin peroxidase with different electron acceptors

Odor pollution is a big environmental problem caused by large-scale livestock production in China, and developing a practical way to reduce these odors is pressing. In this study, a combination of 0.2–1.0 U/mL lignin peroxidase (LiP) and one of three peroxides (H₂O₂, CaO₂, 2Na₃CO₃·3H₂O₂) was examined for its efficiency in reducing the release of eight chemicals (propionic acid, isobutyric acid, isocaproic acid, isovaleric acid, phenol, p-cresol, indole, and skatole), NH₃, H₂S, and odor intensity from pig manure. The results showed an approximately 90% reduction in p-cresol, 40–60% reduction in odor intensity, 16.5–40% reduction in indolic compounds, and 25–40% reduction in volatile fatty acids. Being the electron acceptors of LiP, 2Na₃CO₃·3H₂O₂ and CaO₂ performed better than H₂O₂ in reducing the concentration of eight chemicals, NH_3, H₂S, and odor intensity from pig manure. The effect of deodorization can last for up to 72 hr.

Implications: In China, one of the major environmental problems caused by confined feeding is odor pollution, which brings a major threat to the sustainability, profitability, and growth of the livestock industry. To couple the LiP with the electron acceptors, a low–cost, simple, and feasible method for odor removal was established in this study. Based on the study results, a practical treatment method was provided for odor pollution and supply the farm operators a more flexible time to dispose treated manure.     

中国虚拟水贸易的测算及影响因素研究

本文测算2005年、2007年与2010年3个年度中国虚拟水进出口贸易量,采用投入产出及IO-SDA等方法分解分析其变化的影响因素。研究结果显示部门间用水系数差距都非常大,直接用水系数最大的农业部门857.9 t/万元(3年平均值,下同),与直接用水系数最小的部门差距达600倍之多。完全用水系数最大的也为农业部门1 078.7 t/万元,与完全用水系数最小的部门亦达113倍。各部门的完全用水系数和直接用水系数也存在较大不同,有些部门完全用水系数和直接用水系数差距很大,如服装皮革羽绒及其制品业部门差距达115倍,食品制造及烟草加工业部门差距达618.5 t/万元;而有些部门差距非常小,如农业部门差距仅仅0.24倍,煤炭开采和洗选业部门差距仅为8.2 t/万元。虚拟水出口量和进口量分别从2005年的1 774.3亿t和1 378.7亿t增加到2010年的2 254.1亿t和1 836.5亿t,且出口量一直大于进口量。影响因素分解显示,在此期间,进出口规模的增加是虚拟水贸易量增加的主要影响因素,其中出口规模合计为103 698.8×10~6t,进口规模合计为80 401.2×10~6t。进出口贸易结构的影响在不同部门间存在较大的差异。真实用水系数和真实中间投入技术是虚拟水贸易变化的主要负向因素,其中真实用水系数对虚拟水出口与进口的影响分别为-36 793.2×10~6t和-34 668.3×10~6t,真实中间投入技术对虚拟水出口与进口的影响分别为-1 719.7×10~6t和-1 660.8×10~6t,表明在此期间用水效率和中间投入效率都得到了改善。另外,直接用水系数和中间投入技术分解出的结构效应都不明显,中间投入进口比率效应也不明显。     

“结构—行为—绩效”框架下农地整理的管护绩效研究

在分析农地整理建后管护基本内涵的基础上开发了农民满意度绩效量表,引入新制度经济学领域"结构—行为—绩效"(SCP)范式,构建农地整理建后管护的"组织结构—管护行为—管护绩效"的分析框架。以湖北省赤壁市黄盖湖农场和嘉鱼县潘家湾镇为研究区域开展实证研究,通过比率标度法和熵权法生成绩效测度的组合权重并得到满意度绩效,运用调查数据检验建后管护的组织结构和管护行为对管护绩效的影响机理,分析组织结构的工作职能、成长机制以及管护行为中的集体行为和个体行为的影响程度。研究结果显示:受访农民对农地整理的管护绩效评价接近于"一般",企业管护模式下黄盖湖农场和集体管护模式下潘家湾镇的管护绩效存在显著的地区差异;表征管护组织持续发展状态、内部结构完善程度的组织结构类变量以及表征管护资金投入、受益农民群体参与程度的管护行为类变量是显著影响管护绩效的解释变量;黄盖湖农场企业化经营的组织结构、潘家湾镇的综合治理改革以及受到县级财政专项支持等外部要素是造成农地整理管护绩效差异的主要原因。研究结论验证了农地整理建后管护SCP分析框架的有效性,为提升农地整理管护绩效提供了理论依据。     

川南山地林分变化对土壤物理性质和抗蚀性的影响

以川南天然林(TRL)及其转变成的毛竹林(MZL)、檫木林(CML)、柳杉林(LSL)、杉木林(SML)和水杉林(SSL)为对象,研究不同林分土壤物理性质和抗蚀性差异,以主成分分析法(ZCFM)和隶属函数法(LSHM)分别计算的土壤抗蚀性综合值Ⅰ(KSX-Ⅰ)和Ⅱ(KSX-Ⅱ)评价林分变化对土壤抗蚀性的影响,探索简便易行的土壤抗蚀性综合评价方法。结果表明,天然林转变为人工林后土壤物理性质和抗蚀性变差,呈现出有机质和0.25 mm水稳性团聚体含量、水稳性团聚体平均重量直径、团聚度、孔隙度及物理稳定性指数降低,而结构体破坏率、不稳定团粒指数、容重、分散率及侵蚀系数增加。各林分土壤KSX-Ⅰ和KSX-Ⅱ均呈现出TRLCMLSSLLSLMZLSML的规律变化。土壤抗蚀性指标间相关性均达到显著(p0.05)水平;土壤KSX-Ⅰ和KSX-Ⅱ之间呈显著相关关系(p0.05),且两者均与各抗蚀性指标间呈显著相关(p0.05)。说明天然林植被变化后会使土壤抗蚀性降低,影响原有植被水土保持功能,应该加强天然林及其生态功能保护;ZCFM和LSHM均可作为计算土壤抗蚀性综合值的有效方法,但考虑到计算过程的难易度,后者更简便易行。结果为土壤抗蚀性综合评价新方法的建立提供了参考。