全文获取类型
收费全文 | 3854篇 |
免费 | 159篇 |
国内免费 | 1563篇 |
专业分类
安全科学 | 246篇 |
废物处理 | 276篇 |
环保管理 | 270篇 |
综合类 | 2202篇 |
基础理论 | 618篇 |
环境理论 | 1篇 |
污染及防治 | 1534篇 |
评价与监测 | 134篇 |
社会与环境 | 118篇 |
灾害及防治 | 177篇 |
出版年
2024年 | 2篇 |
2023年 | 64篇 |
2022年 | 165篇 |
2021年 | 148篇 |
2020年 | 108篇 |
2019年 | 94篇 |
2018年 | 123篇 |
2017年 | 178篇 |
2016年 | 196篇 |
2015年 | 256篇 |
2014年 | 261篇 |
2013年 | 401篇 |
2012年 | 328篇 |
2011年 | 336篇 |
2010年 | 259篇 |
2009年 | 268篇 |
2008年 | 288篇 |
2007年 | 246篇 |
2006年 | 215篇 |
2005年 | 169篇 |
2004年 | 112篇 |
2003年 | 138篇 |
2002年 | 153篇 |
2001年 | 95篇 |
2000年 | 116篇 |
1999年 | 139篇 |
1998年 | 115篇 |
1997年 | 105篇 |
1996年 | 101篇 |
1995年 | 110篇 |
1994年 | 77篇 |
1993年 | 65篇 |
1992年 | 48篇 |
1991年 | 32篇 |
1990年 | 14篇 |
1989年 | 6篇 |
1988年 | 15篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 9篇 |
1981年 | 3篇 |
排序方式: 共有5576条查询结果,搜索用时 0 毫秒
881.
882.
Siqi Zhang Furui He Xiuqin Fang Xinyu Zhao Yuanyuan Liu Gaobo Yu Yang Zhou Yuhong Feng Jiacheng Li 《环境科学学报(英文版)》2022,34(3):55-63
Soil aggregation plays an important role in agricultural production activities. However, the structure of soil aggregation is destroyed by the natural environment and unreasonable farming management, resulting in the loss of water, fertilizers and pesticides in soil. At present, hydrogels have been widely reported to promote the formation of soil aggregation. In this paper, amphiphilic calcium alginate (ASA/Ca2+) was applied to promote the formation of soil aggregation and enhance pesticide retention. Initially, an ASA was obtained through the one-pot Ugi condensation (a four-component green chemical reaction). Then, ASA/Ca2+ hydrogel is prepared by Ca2+ cross-linking. The formation of soil aggregation was determined through the Turbiscan Lab Expert stability analyzer, Confocal Laser Scanning Microscope (CLSM), and Transmission Electron Microscope (TEM). And the effect of soil aggregation on acetamiprid environmental behavior was investigated by adsorption kinetics, adsorption isotherms, and leaching. The results shown that the three-dimensional network structure of ASA/Ca2+ hydrogel can promote the formation of soil aggregation. Aggregate durability index (ADI) was 0.55 in the presence of ASA/Ca2+ hydrogel, indicating that amphiphilic hydrogel can enhance the stability of soil aggregation. The adsorbing capacity of acetamiprid was 1.58 times higher than pure soil, and the release of acetamiprid only about 20% in the presence of ASA/Ca2+ hydrogel. These results would be helpful for the formation of soil aggregation and pesticides adsorption on soil aggregation. Thus, ASA/Ca2+ hydrogel is likely to improve soil quality, simultaneously it can minimize the mobility of pesticides in the agricultural system. 相似文献
883.
Weiguo Shen Gejin Gan Rui Dong Hu Chen Yu Tan Mingkai Zhou 《Journal of Material Cycles and Waste Management》2012,14(3):228-233
The utilization of the phosphogypsum (PG) as cement retarder is both an economical and an ecological approach to treat this solid waste. Cement using raw PG as retarder has two problems pressing for solution,namely, delaying the setting time and difficulty being fed into the cement mill. The soluble phosphates in PG behave as super-retarder and bring about retarding in the setting process of cement made with PG. Two types of solidified phosphogypsum (SPG) were prepared to solve those two problems. The strength and the water stability of the SPG were good enough to ensure that they may be conveyed easily and fed into the cement mill stably. The cements with SPG had a similar setting time and strength as cement made with natural gypsum (NG). The microstructure of two kinds of SPG were observed with SEM. During factory application of SPG, good techniques and economic benefits were obtained. 相似文献
884.
Aiming to investigate the impacts of n-octanol addition on the oxidation reactivity, morphology and graphitization of diesel exhaust particles, soot samples were collected from a four-cylinder turbocharged diesel engine fueled with D100(neat diesel fuel), DO15(85% diesel and 15% n-octanol, V/V) and DO30(70% diesel and 30% n-octanol, V/V). All tests were conducted at two engine speeds of 1370 and 2150 r/min under a fixed torque of 125 N ·m. The soot properties were characterized by thermogravimet... 相似文献
885.
Cadmium (Cd2+), a known carcinogen, mimics the effects of estrogen in the uterus and mammary gland suggesting its possible involvement in the development and progression of breast cancer. This lab showed through analysis of a small set of archival human diagnostic specimens that the third isoform of the classic Cd2+ binding protein metallothionein (MT-3) is not expressed in normal breast tissue, but is expressed in some breast cancers and that expression tends to correlate with a poor disease outcome. The goals of this study were to verify that overexpression of MT-3 in a large set of archival human diagnostic specimens tends to correlate with poor disease outcome and define the mechanism of MT-3 gene regulation in the normal breast epithelial cell. The results showed that MT-3 was expressed in approximately 90% of all breast cancers and was absent in normal breast epithelium. The lack of MT-3 staining in some cancers correlated with a favorable patient outcome. High frequency of MT-3 staining was also found for in situ breast cancer suggesting that MT-3 might be an early biomarker for breast cancer. The study also demonstrated that the MCF-10A cell line, an immortalized, non-tumorigenic model of human breast epithelial cells, displayed no basal expression of MT-3, nor was it induced by Cd2+. Treatment of the MCF-10A cells with the demethylation agent, 5-aza-2′-deoxycytidine, or the histone deacetylase inhibitor, MS-275, restored MT-3 mRNA expression. It was also shown that the MT-3 metal regulatory elements are potentially active binders of protein factors following treatment with these inhibitors suggesting that MT-3 expression may be subject to epigenetic regulation. 相似文献
886.
887.
洞庭湖湿地Cd富集植物蒌蒿(Artemisia selengensis)的耐性生理机制研究 总被引:1,自引:0,他引:1
采用盆栽植株和外源Cd胁迫的方法,分别对不同生长期蒌蒿植株根、叶组织中的抗氧化酶活性、可溶性蛋白及MDA含量进行测定,以揭示蒌蒿在Cd胁迫下的抗氧化机理和耐受机制。研究结果表明,Cd胁迫对上述生理指标均有显著影响:≤20mg·kg-1的Cd处理可使幼苗期植株器官中的可溶性蛋白含量增加16.5%~19.1%,100mg·kg-1的Cd含量水平则导致其含量减少近30%,可溶性蛋白含量的变化与植株的生物量积累关系密切;3种酶活性在0~10mg·kg-1的Cd处理下未显示出明显变化,幼苗期植株CAT、POD活性在10~80mg·kg-1的Cd胁迫下增加明显,高于此浓度范围则使酶蛋白受到破坏而失活,中等含量水平(≤40mg·kg-1)的Cd处理经过长时间作用可使植株逐渐适应胁迫环境,胁迫强度较大的Cd处理可显著提高SOD酶的活性;Cd胁迫过程中植株MDA积累量不断增加。3种抗氧化酶活性的增强在蒌蒿植株耐受Cd胁迫方面能起到较好的防御作用。 相似文献
888.
Zhenyi Zhang Xuan Zhao Yuting Liang Guanghe Li Jizhong Zhou 《Environmental Chemistry Letters》2013,11(1):11-17
This report shows an increase of PAH-related microbial functional genes with PAH concentration in soils. Adaptation of microbial communities to organic pollutants such as polycyclic aromatic hydrocarbons (PAHs) is a crucial issue. However, there is little knowledge on mechanisms ruling microbial community selection. Here, we studied microbial functional genes in soils contaminated by PAHs. We used GeoChip, an advanced functional gene array for gene analysis. Soil PAH concentrations were measured and microbial functional genes were categorized. PAH-related microbial functional genes, bph, nah, nidA, phd, dfb, and qor, were quantitatively expressed. Total microbial functional genes and PAH-related microbial functional genes were compared with PAH concentration by cluster analysis and curve-fitting analysis. We found that the average abundance of PAH-related microbial functional genes increased from 0.13 to 0.33, whereas that of total microbial functional genes decreased from 0.22 to 0.10 when PAHs concentration increased from 1.01 to 164.28 mg kg?1. It was also found that the classification of microbial community structure characteristics based on PAH-related microbial functional genes was closely similar to the classification based on PAHs concentration. Findings reveal that PAH stress promotes the dominance of PAH-related microbial communities. 相似文献
889.
太湖水体中5种有机磷农药混合物生态风险评价 总被引:2,自引:0,他引:2
有机磷农药是一类广泛分布于我国水环境中的污染物,即使在水体中的污染水平处于规定“安全标准”之下,其联合暴露产生的风险仍有可能威胁水生生态安全。采用基于浓度加和模型与生物敏感度分布曲线的混合物风险商法,评价了太湖水体中敌敌畏、对硫磷、甲基对硫磷、马拉硫磷和乐果5种有机磷农药混合物产生的生态风险。结果表明:2003~2004年期间3个不同时期太湖水体中5种有机磷农药的混合物生态风险商(RQm )均大于1,有机磷农药混合物在2003~2004年期间对太湖水生生物构成了一定威胁。 相似文献
890.
Liqin JI Xue BAI Lincheng ZHOU Hanchang SHI Wei CHEN Zulin HUA 《Frontiers of Environmental Science & Engineering》2013,7(3):442-450
A simple solvothermal method was used to prepare monodisperse magnetite (Fe3O4) nanoparticles attached onto graphene oxide (GO) sheets as adsorbents to remove tetrabromobisphenol A (TBBPA) from an aqueous solution. These Fe3O4/GO (MGO) nanocomposites were characterized by transmission electron microscopy. The adsorption capacity at different initial pH, contact duration, and temperature were evaluated. The kinetics of adsorption was found to fit the pseudo-second-order model perfectly. The adsorption isotherm well fitted the Langmuir model, and the theoretical maximum of adsorption capacity calculated by the Langmuir model was 27.26 mg?g-1. The adsorption thermodynamics of TBBPA on the MGO nanocomposites was determined at 303 K, 313 K, and 323 K, respectively. The results indicated that the adsorption was spontaneous and endothermic. The MGO nanocomposites were conveniently separated from the media by an external magnetic field within several seconds, and then regenerated in 0.2 M NaOH solution. Thus, the MGO nanocomposites are a promising candidate for TBBPA removal from wastewater. 相似文献