常压非平衡等离子体条件下CO2的转化

研究常温常压下,脉冲电晕等离子体对温室气体ＣＯ２的活经与轮,分别考究了纯ＣＯ２气体,ＣＯ２－Ｈ２,ＣＯ２－ＣＨ４体系中ＣＯ２的轮。纯ＣＯ２气体放电,ＣＯ２主要分解为ＣＯ和Ｏ２,ＣＯ的选择性在７０％以上,随着脉冲电压峰值的增加,ＣＯ２转化率,ＣＯ２产率有所提高。     

氟化铵和氨循环法从脱腊脱油废白土中制取白炭黑

利用NH4F与废白土中SiO₂反应生成的（NH4）SiF6溶液和NH₃,进行闭路循环反应,生成NH4F与水合SiO₂（白炭黑）,通过正交优化,得到最佳工艺为：氟化反应,NH₄F∶废白土＝1.28,NH₄F∶水＝0.9,反应温度60℃,反应时间4h;氨化反应,反应温度60℃,反应时间8h,投料比＝2〔25％氨水mL/（NH₄）SiF₆g〕。循环试验结果表明,NH4F转化率可达82％,白炭黑产率达90％以上,只需补充少量NH₄F和氨水,就能在不产生环境污染的情况下从废白土中制取白炭黑。     

Case study on nitrogen and phosphorus emissions from paddy field in Taihu region

The agricultural non-point source pollution by nitrogen (N) and phosphorus (P) loss from typical paddy soil (whitish soil, Bai Tu in Chinese) in the Taihu Lake region was investigated through a case study. Results shown that the net load of nutrients from white soil is 34.1 kg ha(-1) for total nitrogen (TN), distributed as 19.4 kg ha(-1), in the rice season and 14.7 kg ha(-1) in the wheat season, and for total phosphorus (TP) 1.75 kg ha(-1), distributed as 1.16 kg ha(-1) in the rice season and 0.58 kg ha(-1) in the wheat season. The major chemical species of N loss is different in the two seasons. NH4-N is main the form in the rice season (53% of TN). NO3-N is the main form in wheat season (46% of TN). Particle-P is the main form in both seasons, (about 56% of TP). The nutrient loss varied with time of the year. The main loss of nutrients happened in the 10 days after planting, 64% of TN and 42% of TP loss, respectively. Rainfall and fertilizer application are the key factors which influence nitrogen and phosphorus loss from arable land, especially rainfall events shortly after fertilizer application. So it is very important to improve the field management of the nutrients and water during the early days of planting.     

SO2在Co—Mo／AC催化剂上的还原

本文研究了活性焦（ＡＣ）担载Ｃｏ－Ｍｏ催化剂对ＳＯ２还原的催化性能。考查了催化剂不同的预处理方法,Ｈ２／ＳＯ２摩尔比和还原温度对还原过程硫产率的影响,并就硫化后的Ｃｏ－Ｍｏ和活性焦在催化床不同的构成对硫产率的影响进行了研究。结果表明,经硫化后的催化剂在ＳＯ２＋２Ｈ２→Ｓ＋２Ｈ２Ｏ反应有较高的催化活性,在最佳反应温度３００℃,Ｈ／ＳＯ摩尔比为３,空速６０００Ｌ;ｋｇ＾－１．ｈ＾－１条件下,生成硫的产     

环境污染物的分子毒理机制研究进展

以分子生物学技术为基础研究污染物的毒理机制．从分子水平揭示了污染物毒作用的本质。综述了国内外分子毒理机制的研究进展。详细阐述了毒理芯片、单细胞凝胶电泳等分子生物学技术应用与毒理学研究中的特点、应用前景以及存在的问题。提出了分子毒理机制今后的研究方向。     

江苏海岸湿地水质污染特征与海陆一体化调控

2000年江苏海岸湿地人海河流河口淡水监测断面有30％的水质处于劣Ⅴ类,满足Ⅲ类水质的仅占10％;近岸海域海水监测断面有50％的水质处于Ⅳ标准。人类扰动的频率与强度的日益加大是水质污染的主要原因,而河流携带大量污染物是水质污染的主要途径。江苏海岸湿地水质污染防治的关键在于流域海陆水环境系统的一体化调控,侧重点是调控技术路线和水质污染控制层次的设计。环境管理控制区划的方案是：横向上由陆向海划分为上游流域、近岸陆域、海岸湿地和离岸海域4个环境控制带;纵向上自北向南以水系汇流特征、行政区划特征、海域特点划分为Ⅳ类环境功能区及若干亚区。     

树脂吸附法处理邻甲苯胺生产废水的研究

在最佳工艺条件下,采用NDA-804树脂对邻甲苯胺生产废水进行吸附-脱附实验。原废水经吸附处理后,邻甲苯胺去除率和CODcr去除率均大于99％．树脂脱附率接近100％。高浓度脱附液可以回收邻甲苯胺,达到了废水治理与资源化的效果。     

有机生活垃圾微生物处理剂的研究

采用了多种培养基 ,对广泛收集的菌种、相关土样进行分离、筛选 ,得到了 8株有效微生物 ,其产生的蛋白酶、脂肪酶、淀粉酶和纤维素酶等酶系可使大分子物质分解成低分子物质 ,微生物摄取这些低分子物质后 ,将其转变成二氧化碳、水和少量氨气并释放能量 ,剩余的少量固体残渣可作为生物肥料。采用以上 8种微生物制成的有机生活垃圾处理剂 ,如配合一定的处理工艺和设备 ,可对日常有机生活垃圾进行减量化和资源化处理。     

高效生活污水处理装置--高性能合并处理净化槽

详细介绍了从日本引进的一体化生活污水处理装置--高性能合并处理净化槽的特点、运行机理和在日本的应用情况.     

Incorporating sorption/desorption of organic pollutants into river water quality model

Preliminary research was conducted about how to incorporate sorption/desorption of organic pollutants with suspended solids and sediments into single-chemical and one-dimensional water quality model of Jinghang Canal.Sedimentation-resuspension coefficient k3 was deduced; characteristics of organic pollutants, concentrations and components of suspended solids/sediments and hydrological and hydraulic conditions were integrated into k3 and further into river water quality model; impact of sorption/desorption of organic pollutants with suspended solids and sediments on prediction function of the model was discussed. Results demonstrated that this impact is pronounced for organic pollutants with relatively large Koc and Kow, especially when they are also conservative and foc of riversuspended solids/sediments is high, and that incorporation of sorption/ desorption of organic pollutants into river water quality model can improve its prediction accuracy.