便携式X射线荧光光谱仪快速测定土壤中多种金属元素

采用粉末压片、X射线荧光光谱分析土壤中的多种金属元素,经标准样品验证,该方法的检出限、准确度、精密度均符合分析要求。与原子吸收光谱法做对比试验,结果表明Ni和Cr相对偏差较大,而Cu、Zn、Mn和Pb相对偏差均〈5％。实验表明x射线荧光光谱分析法样品制备简单、分析速度快,适用于应急监测。     

Optimization analysis of silver extraction from waste monolithic ceramic capacitor using persulfate-ammonia system

Journal of Material Cycles and Waste Management - Monolithic ceramic capacitors (MLCCs) contain a high level of silver. This paper describes a method to recover silver from the waste MLCCs. First,...     

Dynamics of phosphorus fractions and potential bioavailability along soil profiles from seasonal-flooding wetlands in a Chinese estuary

Environmental Science and Pollution Research - Soil phosphorus fractions in wetland ecosystems have received increasing attention due to its high eutrophication risks. Soil samples were collected...     

Short-term effects of real-time individual fine particulate matter exposure on lung function: a panel study in Zhuhai,China

Environmental Science and Pollution Research - Fine particulate matter (PM2.5) is still the primary air pollutant in most Chinese cities and its adverse effects on lung function have been widely...     

The risks of sulfur addition on cadmium accumulation in paddy rice under different water-management conditions

Recently, the application of sulfur (S) has been recommended to control the accumulation of cadmium (Cd) in rice in contaminated paddy soil. However, the effects of exogenous S on Cd transfer in paddy rice systems under different water-management practices have not been systematically investigated. Pot experiments were performed to monitor the composition of soil pore water and the Cd accumulation in iron plaque and rice tissue were compared under different S (0 and 200 mg/kg Na₂SO₄) and water (continuous and discontinuous flooding) treatments. Sulfur application significantly increased Cd concentrations in soil pore water under discontinuous flooding conditions, but slightly reduced them under continuous flooding. Moreover, the oxidation/reduction potential (Eh) was the most critical factor that affected the Cd levels. When the Eh exceeded −42.5 mV, S became the second critical factor, and excessive S application promoted Cd dissolution. In addition, S addition elevated the Cd levels in iron plaque and reduced the Cd transfer from the iron plaque to rice roots. In rice, S addition inhibited Cd transfer from the rice roots to the straw; thus, more Cd was stored in the rice roots. Nevertheless, additional S application increased the Cd content in the rice grains by 72% under discontinuous flooding, although this effect was mitigated by continued flooding. Under simulated practical water management conditions, S addition increased the risk of Cd contamination in rice, suggesting that S application should be reconsidered as a paddy fertilization strategy.     

Emission Inventories of Carbon-containing Greenhouse Gases in and Technological Measures for Their Abatement

The report summarizes surveys on carbon inventories and initiatives on sustainable carbon cycling taken by the Research Center for EcoEnvironmental Sciences, where the authors work/worked. The first part of the report, which appeared in the preceding issue of this journal, deals with the concept of sustainable carbon cycling, the historic evolution of carbon cycling processes in China, carbon pool enhancement, value addition,carbon sequestration and carbon balance. This very paper, as the second part of the report, covers the results of carbon dynamics modeling, emission inventories of various carbon-containing greenhouse gases and their potential abatement measures.     

故障树分析法在安全完整性等级计算中的应用

在介绍故障树分析方法的基础上,重点分析了定量的故障树分析计算方法。以丙烯腈装置中的反应器压力高联锁回路为例,阐述了此方法在具体装置中的应用,结果表明具有很好的工程实用性。     

上海市城乡梯度上土壤重金属空间分布及其影响因素定量分析

提出了两种上海市城乡梯度上土壤重金属空间格局及影响因素的研究方法:缓冲区分析方法和滑动窗口分析方法.缓冲区分析的结果表明,人口变化指数及2~3 km范围内的建设用地比例能显著影响Cd和Cu的空间分布(p0.05),而3 km范围内的道路密度显著影响Pb的浓度.滑动窗口分析的结果表明,Cd和Cu主要受工业活动的影响,而Pb受交通流量,以及反映城市景观扩张过程的景观形状指数的影响.相关分析表明,两种方式揭示了较为相似的土壤重金属空间累积影响因素,即工业活动相关的城市化过程.研究对理解城市化的发生机制及其重金属环境风险的管理有重要意义.     

基于灰色模型GM(1,1)的河南省能源消费预测

本文选取河南省2004-2012年能源消费量作为样本数据,建立了基于灰色模型GM(1,1)的河南省能源消费量预测模型,并预测了河南省2013-2020年能源消费量,2020年预测值41071万吨标煤,比2012年增加73.68%。结合河南省能源消费结构现状,提出了河南省能源消费总量控制及能源结构调整的对策与建议。     

有机化合物动态定量结构—生物降解关系（QSBR）模型研究

本文通过分析影响有机物生物降解的基本因素，指出ＱＳＢＲ模型应综合反映影响有机物生物降解的四个方面：取代化合物的摄入、取代化合物的诱导作用，毒性物质的形成和基础酶的缺乏，在此基础之上给出了动态ＱＳＢＲ的概念模型及方法学基础，并利用其研究了氯代芳香化合物的生物降解性。