Short-term effects of real-time individual fine particulate matter exposure on lung function: a panel study in Zhuhai,China

Environmental Science and Pollution Research - Fine particulate matter (PM2.5) is still the primary air pollutant in most Chinese cities and its adverse effects on lung function have been widely...     

Rising greenhouse gas emissions from the China’s aquaculture industry between 2000 and 2020

Environmental Chemistry Letters - Aquaculture is a major source of greenhouse gas emissions, yet long-term spatiotemporal variations of emissions remain poorly documented. Here, we studied methane...     

Cooperative identification for critical periods and critical source areas of nonpoint source pollution in a typical watershed in China

Environmental Science and Pollution Research - Critical periods (CPs) and critical source areas (CSAs) refer to the high-risk periods and areas of nonpoint source (NPS) pollution in a watershed,...     

Difference between selenite and selenate in selenium transformation and the regulation of cadmium accumulation in Brassica chinensis

Environmental Science and Pollution Research - Se can regulate Cd accumulation and translocation in plants; however, such effects can be controversial because of the differences in plant species...     

铁基双金属催化剂活化过硫酸盐去除水中抗生素研究进展

近年来,抗生素残留物在多种水体中被普遍检出,对水生态环境和人类健康造成严重威胁.基于活化过硫酸盐高级氧化作用去除水中抗生素污染物,以其氧化性强、选择性高和pH适用范围宽等特点成为研究热点.低成本、高稳定性和催化性能优异的铁基双金属材料能有效活化过硫酸盐,它弥补了单一铁元素活化剂易失活、效率低和容易产生二次污染等缺陷.针对尖晶石铁氧体、铁基层状双金属氢氧化物和铁基普鲁士蓝类似物3种典型铁基双金属催化剂,开展其活化过硫酸盐降解抗生素的研究分析,系统讨论了铁基双金属活化过硫酸盐的几种内在驱动机制,并分别对自由基、单线态氧和高价金属的产生,电子转移和过硫酸盐直接氧化过程进行了梳理.最后,总结了活化过硫酸盐技术处理氟喹诺酮类、磺胺类、四环素类与β-内酰胺类抗生素等4种典型抗生素的一般降解途径,为今后研究铁基双金属催化剂及其改性、衍生物和复合物等在活化过硫酸盐技术中的应用提供参考.     

17β3-雌二醇对西伯利亚鲟幼鱼的雌激素效应

为了研究以及评估在利用17β-雌二醇(estradiol-17β,E2)混饲投喂进行人工诱导西伯利亚鲟(Acipenser baerii)性别逆转过程中,外源雌激素处理对西伯利亚鲟幼鱼的雌激素效应以及激素残留风险.实验选取健康的2月龄西伯利亚鲟840尾,设置E2在饲料中的投喂剂量为1 mg·1kg-1(C组)和10 m...     

C60-DOM interactions and effects on C60 apparent solubility: a molecular mechanics and density functional theory study

Dissolved organic matter (DOM) plays a critical role in the transport of carbon nano-particles (e.g. C(60)) in the aquatic environment. However, the mechanism for C(60)-DOM interactions and its environmental implications needs further investigations. In this study, the interaction of C(60) with relevant reference compounds of DOM (DOM(R)) is computationally simulated by molecular mechanics and density functional theory (DFT). All the C(60)-DOM(R) complexes are firstly optimized by classical annealing, and then DFT using the Dmol(3) code. The adsorption energies of C(60) on DOM(R) were computed. The computed electrostatic potential indicates that DOM(R) are electron acceptors in the C(60)-DOM(R) complexes, and the thermodynamic calculations indicate that electrostatic interaction is the dominant driving force for the C(60)-gallic acid complexation process in water. The presence of DOM(R) increases the apparent water solubility of C(60). It is also observed that the C(60) apparent water solubility decrease with the increase of the energy gaps of frontier molecular orbitals (E(LUMO)-E(HOMO)) for each C(60)-DOM(R) complex. These findings indicate that computational simulation is an important tool for predicting the behavior and fate of carbon nano-particles in the aquatic environment.     

沈阳市室内空气中挥发性有机物的污染状态分析

选取装修时间分别为7d、30d、90d的居室各50户,采集室内空气样测定总挥发性有机物（TVOC）浓度,发现超标率随装修时间的延长而下降,且90d后TVOC超标2倍以上的严重污染户已降至2％;装修3个月以上居室室内空气中TVOC组分共检测出59种,其中32种为半数以上居室所共有,经分析绝大多数为室内装修材料所释放且多为有害物质;通过实验发现周期性通风放置比封闭状态放置能够更快地降低室内TVOC浓度．是减轻TVOC污染的最佳方法。     

Characterization of the archaeal community fouling a membrane bioreactor

Biofilmformation, one of the primary causes of biofouling, results in reducedmembrane flux or increased transmembrane pressure and thus represents a major impediment to the wider implementation of membrane bioreactor (MBR) technologies for water purification. Most studies have focused on the role of bacteria in membrane fouling as they are the most dominant and best studied organisms present in the MBR. In contrast, there is limited information on the role of the archaeal community in biofilm formation in MBRs. This study investigated the composition of the archaeal community during the process of biofouling in an MBR. The archaeal community was observed to have lower richness and diversity in the biofilmthan the sludge during the establishment of biofilms at low transmembrane pressure (TMP). Clustering of the communities based on the Bray-Curtis similarity matrix indicated that a subset of the sludge archaeal community formed the initial biofilms. The archaeal community in the biofilm was mainly composed of Thermoprotei, Thermoplasmata, Thermococci, Methanopyri, Methanomicrobia and Halobacteria. Among them, the Thermoprotei and Thermoplasmata were present at higher relative proportions in the biofilms than they were in the sludge. Additionally, the Thermoprotei, Thermoplasmata and Thermococci were the dominant organisms detected in the initial biofilms at low TMP, while as the TMP increased, the Methanopyri, Methanomicrobia, Aciduliprofundum and Halobacteria were present at higher abundances in the biofilms at high TMP.     

空气中总悬浮颗粒物的三种测定方法比较

本文采用大流量采样、β－射线衰减测尘仪与ＴＥＯＭ测尘仪分析测定空气中的总悬浮颗粒物,对比实验结果表明：ＴＥＯＭ法与经典大流量测定方法、β－射线衰减法测量结果均具有可比性。