Atmospheric polycyclic aromatic hydrocarbons in an industrialized city, Kocaeli, Turkey: study of seasonal variations, influence of meteorological parameters and health risk estimation

Ambient gas and particle phase samples were collected during two sampling periods from a residential area of an industrialized city, Kocaeli, Turkey. The sampling occurred during winter months when structures were being heated, and summer months when structures were not being heated. Σ(13)PAH (gas + particle) concentrations ranged between 6.2 ng m(-3) (DahA) and 98.6 ng m(-3) (Phe) in the heating (winter) period and 3.0 ng m(-3) (BaA) and 35.1 ng m(-3) (Phe) in the non-heating (summer) period. Phe, Flt and Pyr were found to be at high concentrations in both sampling periods. Winter time to summer time concentration ratios for individual ambient PAH concentration ratios ranged between 1.2 (DahA) and 17.5 (Flu), indicating the effect of the emissions from residential heating on measured concentrations of PAHs, but great industrial plants and the only incinerator facility of Turkey are other important pollution sources around the city. Temperature dependence of gas phase PAHs was investigated using the Clausius-Clapeyron equation. A high slope obtained (5069.7) indicated the effect of the local sources on measured gas phase PAHs. Correlation of the supercooled vapor pressure (P) with the gas particle partitioning coefficient (K(p)) and particle phase fraction was also evaluated. The relationship between the meteorological parameters and individual PAH (gas + particle) concentrations was investigated further by multiple linear regression analysis. It was found that the temperature had a significant effect on all of the measured PAH concentrations, while the effects of the wind speed and direction were not significant on the individual PAHs. On the other hand, PAH concentrations showed a strong linear relationship with the ventilation coefficient (VC) which showed the influence of local sources on measured PAHs. Benzo[a]pyrene toxic equivalent (BaP(eq.)) concentrations were used for health risk assessment purposes. The winter period risk level (2.92 × 10(-3)) due to the respiratory exposure to PAHs was found to be almost 3 times higher than in the summer period (1.15 × 10(-3)).     

Assessing implications of land use and land cover changes in forest ecosystems of NE Turkey

Monitoring land use and land cover change (LUCC) and understanding forest cover dynamics is extremely important in sustainable development and management of forest ecosystems. This study analyzed the spatial and temporal pattern of LUCC in the Yaln?zçam and U?urlu forest planning units which are located in the northeast corner of Turkey. The investigation also evaluates the temporal changes of the spatial structure of forest conditions through the spatial analysis of forest-cover type maps from 1972 and 2005 using geographical information systems and FRAGSTATS^TM. As an overall change between 1972 and 2005, there was a net increase of 1,823 ha in forested areas, and cumulative forest improvement accounted for 2.06 %. In terms of spatial configuration, the landscape structure in the study area changed substantially over the 33-year study period, resulting in fragmentation of the landscape as indicated by large patch numbers and smaller mean patch sizes, owing to heavy grazing, illegal cutting, and uncontrolled stand treatments.     

Pesticide residues in liquid pekmez (grape molasses)

In this investigation properties of organic semiconductor copper phthalocyanine (CuPc) capacitive humidity and illumination sensors were studied. Organic thin film was deposited by vacuum evaporation on a glass substrate with silver surface-type electrodes to form the Ag/CuPc/Ag sensor. The capacitance of the samples was evaluated at room temperature in the relative humidity range of 35–92%. It was observed that capacitance of the Ag/CuPc/Ag sensor increases with increase in humidity. The ratio of the relative capacitance to relative humidity was about 200. It is assumed that in general the capacitive response of the sensor is associated with polarization due to absorption of water molecules and transfer of charges (electrons and holes). It was observed that under filament lamp illumination of up to 1,000 lx the capacitance of the Ag/CuPc/Ag photo capacitive detectors increased continuously by 20% as compared to dark condition. It is assumed that photo capacitive response of the sensor is associated with polarization due to transfer of photo-generated electrons and holes. An equivalent circuit of the Ag/CuPc/Ag capacitive humidity and illumination sensor was developed. Humidity and illumination dependent capacitance properties of this sensor make it attractive for use in humidity and illumination multi-meters. The sensor may be used in instruments for environmental monitoring of humidity and illumination.     

Assessment of seasonal variations of surface water quality characteristics for Porsuk Stream

In this study, the factor analysis technique is applied to surface water quality data sets obtained from Porsuk stream in Turkey, generated during 10 years (1995-2005) monitoring of 29 parameters at one site (Esenkara) for all four seasons. The varifactors obtained from factor analysis indicate that the parameters responsible for water quality variations are mainly related to mineral and inorganic nutrients, organic pollution, microbiological pollution in winter and spring; mineral and nutrients in summer; microbiological and nutrient pollution in fall. This study presents the necessity and usefulness of multivariate statistical assessment of large and complex databases in order to get better information about the quality of surface water.     

Detecting micronuclei frequency in some aquatic organisms for monitoring pollution of Izmir Bay (Western Turkey)

Micronuclei tests is a system of mutagenicity testing used for determining the pollution and chemicals causing changes in DNA fragments such as micronuclei in the cytoplasm of interphase cells. Damage caused on the DNA by genotoxic pollutants is the first consequence occurring in the aquatic organisms. Thus, it was attempted to determine whether pollution affected the erythrocytes and gills of fish Gobius niger and haemolymph and gills of mussels Mytilus galloprovincialis living in Izmir Bay at the level of DNA by the means of micronuclei (MN) test. Organisms used in the MN test were collected from seven locations (Alsancak, Alaybey Shipyard, Karsiyaka, Bostanli, Göztepe, Konak and Pasaport) which are known as the most polluted part of inner Bay of Izmir (Western Coast of Turkey). According to the results of the present study, frequency of MN was found at high level in Alaybey Shipyard and Pasaport where wastes from existing dockyard contributed to high level of pollution. In conclusion, this study indicates that the micronuclei test gives sensitive results in monitoring the pollution, especially the pollution of harbor, and thus it might be used as standard method in regular monitoring of pollution of coastal ecosystem.     

Metals in tissues of fish from Yelkoma Lagoon, northeastern Mediterranean

This study was performed to investigate the metal concentrations in muscle, liver, gonad, and gill of gilthead seabream (Sparus aurata L., 1758), European seabass (Dicentrarchus labrax L., 1758), and keeled mullet (Liza carinata Valenciennes, 1836) from Yelkoma Lagoon, northeastern Mediterranean region. So, the levels of cadmium, cobalt, chromium, copper, iron, manganese, nickel, lead, and zinc in tissues of specimens from the lagoon were determined by inductively coupled plasma optical emission spectrometer. Concentrations of metals in muscles of the examined species ranged from 0.10 to 0.47 mg kg^???1 for cadmium, 0.10 to 0.43 mg kg^???1 for cobalt, 0.17 to 0.72 mg kg^???1 for chromium, 0.62 to 1.03 mg kg^???1 for copper, 28.9 to 52.3 mg kg^???1 for iron, 0.75 to 0.96 mg kg^???1 for manganese, 0.11 to 0.57 mg kg^???1 for nickel, 0.19 to 0.47 mg kg^???1 for lead, and 6.01 to 13.9 mg kg^???1 for zinc, respectively. Additionally, metal concentrations in muscles of fish were assessed for human uses according to provisional tolerable weekly intake and provisional tolerable daily intake.     

Assessment of groundwater quality of the Tatlicay aquifer and relation to the adjacent evaporitic formations (Cankiri,Turkey)

One of the most important hydrogeologic problems in and adjacent areas of evaporitic formations is severe quality degradation of groundwaters. These kinds of groundwaters contain high content of dissolved solids and generally have some limitations for use. Tatlicay basin (north-central Turkey) is an example to effects of the evaporites on groundwater quality in the adjacent alluvium aquifer. Gypsum and anhydrites in the two evaporite formations (Bayindir and Bozkir) effect of the groundwater quality in the alluvium adversely, by dissolution of the evaporites by surface drainage and infiltration into the alluvium aquifer (widespread effect) and by infiltration of low quality gypsum springs (local effect) into the aquifer. Evaporitic formations significantly increased EC, TDS, Ca and SO₄ parameters in the alluvium aquifer in the central and downstream regions. EC has increased roughly from 500–800 to 1,700–2,000 μS/cm, Ca has roughly increased from 3–4 to 10 meq/l, SO₄ has increased 0.5–1 to 11–12 meq/l. Consequently, three clusters were distinguished in the basin; (1) nonevaporitic waters in low TDS, Na, Ca, Mg, Cl and SO₄, (2) diluted waters in high TDS and relatively high Cl, moderate-relatively high Na, Ca, Mg, SO₄, (3) gypsum springs in highest TDS, Ca, SO₄, but moderate Mg and low Na, Cl.     

Sensitive determination of cadmium using solidified floating organic drop microextraction-slotted quartz tube-flame atomic absorption spectroscopy

In this study, solidified floating organic drop microextraction (SFODME) by 1-undecanol was combined with slotted quartz tube flame atomic absorption spectrometry (SQT-FAAS) for the determination of cadmium at trace levels. Formation of a complex with 4,4′-dimethyl-2,2′-bipyridine facilitated the extraction of cadmium from aqueous solutions. Several chemical variables were optimized in order to obtain high extraction outputs. Parameters such as concentration of the ligand, pH, and amount of buffer solution were optimized to enhance the formation of cadmium complex. The SFODME method was assisted by dispersion of extractor solvent into aqueous solutions using 2-propanol. Under the optimum extraction and instrumental conditions, the limit of detection and limit of quantitation values obtained for cadmium using the combined methods (SFODME-SQT-FAAS) were found to be 0.4 and 1.3 μg L^?1, respectively. Matrix effects on the method were also examined for tap water and wastewater, and spiked recovery results were found to be very satisfactory.

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Graphical Abstract SFODME-SQT-FAAS system for sensitive determination of cadmium

     

Epilithic diatom assemblages and their relationships with environmental variables in the Nilüfer Stream Basin,Bursa, Turkey

Patterns of epilithic diatom species distribution in relation to environmental variables from 12 sampling sites on the main stream and some of its tributaries in the Nilüfer Stream Basin were determined using multivariate statistical techniques. The stream basin has been heavily influenced by anthropogenic effects. The upper part of the basin that is distant from pollution sources mostly has a spring water quality, while the lower part where the stream flows through the urban area and receives domestic and industrial wastewater has a quite low quality. Ordination techniques using both diatom taxa and 21 environmental variables revealed non- to slightly polluted upper basin sites and highly polluted lower basin sites along the stream. The results showed that the stream catchment is polluted gradually from upstream to downstream and that most of the downstream sites have very low water quality especially in summer months. A total of 134 epilithic diatom taxa belonging to 50 genera were recorded for 12 sample sites. Partial CCA results indicated that water temperature (T), discharge (Q), and total phosphorus (TP) were the most important variables affecting the distribution of diatom species. Unpolluted or slightly polluted upper basin sites were dominated by Achnanthidium minutissimum, Cocconeis placentula var. euglypta, Gomphonema olivaceum, and Navicula tripunctata. Highly polluted lower basin sites were characterized by high levels of organic and inorganic matters and low dissolved oxygen (DO) values. Species widespread in the highly polluted lower basin sites such as Nitzschia umbonata, Nitzschia amphibia, Nitzschia capitellata, Nitzschia palea, Nitzschia paleacea, Luticola mutica, and Stephanodiscus niagarae were mostly related to pollution indicator variables such as ammonium nitrogen (NH₄ ⁺–N), sodium (Na⁺), total phosphorus (TP), and total organic matter (TOM).     

Accumulations of total metal in dominant shrimp species (Palaemon adspersus, Palaemon serratus, Parapenaeus longirostris) and bottom surface sediments obtained from the Northern Inner Shelf of the Sea of Marmara

The aim of this study is to determine the total metal (aluminum, copper, manganese, nickel, lead, zinc, cadmium, iron, mercury) contents of dominant shrimp species and sediments present at 1–50 m depths of the Northern Inner Shelf of the Sea of Marmara. Shrimp and sediment samples were collected from four regions (Büyükçekmece, Silivri, Tekirda?, ?arköy) and from different depths (1, 5, 10, 20, 30, 50 m) at each region in September and November of 2003. Three shrimp species [Palaemon adspersus (Rathke, 1937), Palaemon serratus (Pennant, 1777), Parapenaeus longirostris (H. Lucas, 1846)] were identified to be dominant as a result of the examination on the obtained samples. Heavy metal contents of these three species were determined and the results were compared with the acceptable treshold values of the Seafood Standards and also with available literatures. The Cu contents were found to be higher than the treshold limits in all samples except P. longirostris from Silivri, also the Cd contents in all samples except P. adspersus from Büyükçekmece, the Zn contents only in P. adspersus and P. longirostris from Tekirda?, and the Pb contents in all species from all regions. These high values are the indicator of industrial pollution. There is not any data in the Seafood Standards about Mn, Ni, Fe and Al contents in shrimp species. The values of these metal contents were given in the present study. The examination of total metal distributions in bottom surface sediment samples in the Northern Inner Shelf of the Sea of Marmara showed that the determined values were higher than the shale average at some depths of examined stations.